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Tension and stress relaxation behavior of a La-based bulk metallic glass

Published online by Cambridge University Press:  31 January 2011

G.Q. Zhang
Affiliation:
International Center for New-Structured Materials (ICNSM) and Laboratory of New-Structured Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China; and Key Laboratory of Advanced Textile Materials and Manufacturing Technology (Zhejiang Sci-Tech University), Ministry of Education, Hangzhou 310018, People’s Republic of China
Q.K. Jiang
Affiliation:
International Center for New-Structured Materials (ICNSM) and Laboratory of New-Structured Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
X.P. Nie
Affiliation:
International Center for New-Structured Materials (ICNSM) and Laboratory of New-Structured Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
L.Y. Chen
Affiliation:
International Center for New-Structured Materials (ICNSM) and Laboratory of New-Structured Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
L.N. Wang
Affiliation:
Key Laboratory of Advanced Textile Materials and Manufacturing Technology (Zhejiang Sci-Tech University), Ministry of Education, Hangzhou 310018, People’s Republic of China
M. Shao
Affiliation:
Key Laboratory of Advanced Textile Materials and Manufacturing Technology (Zhejiang Sci-Tech University), Ministry of Education, Hangzhou 310018, People’s Republic of China
X.D. Wang
Affiliation:
International Center for New-Structured Materials (ICNSM) and Laboratory of New-Structured Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
Y.G. Liu
Affiliation:
Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, People’s Republic of China
H.S. Xie
Affiliation:
Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, People’s Republic of China
C.L. Qin
Affiliation:
Japan Science and Technology Agency, Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, Japan
A. Inoue
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan
Y.W. Wang
Affiliation:
International Center for New-Structured Materials (ICNSM) and Laboratory of New-Structured Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
J.Z. Jiang*
Affiliation:
International Center for New-Structured Materials (ICNSM) and Laboratory of New-Structured Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

Tension and stress-relaxation behaviors of a La62Al14Cu11.7Ag2.3Ni5Co5 bulk metallic glass (BMG) as a function of isothermal annealing time have been investigated. It is found that annealing at 373 K below the glass-transition temperature (423 K) of the BMG alloy causes an increase of special heat difference at the glass transition and density of the alloy, indicating a reduction of free volume in the BMG alloy with annealing time. Compared with the as-cast sample, the fracture strength, Vickers hardness, viscosity, Young’s modulus, and stress-relaxation stability of the annealed BMGs increase with annealing time, which is caused by the reduction of free volume in the annealed samples. Furthermore, a change of fracture morphology from a mixture of smooth and furrow zones in the as-cast sample to a mainly furrow zone in the sample annealed for 8 h was also observed. All samples exhibit brittle behavior during tension tests.

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Articles
Copyright
Copyright © Materials Research Society 2007

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References

REFERENCES

1Peker, A.Johnson, W.L.: A highly processing metallic glass: Zr41.5Ti13.8Cu12.5Ni10Be22.5. Appl. Phys. Lett. 63, 2342 1993CrossRefGoogle Scholar
2Inoue, A., Yokoyama, Y., Shinohara, Y.Masumoto, T.: Preparation of bulky Zr-based amorphous alloys by a zone melting method. Mater. Trans., JIM 35(12), 923 1994CrossRefGoogle Scholar
3Jin, K.F.Löffler, F. Jörg: Bulk metallic glass formation in Zr–Cu–Fe–Al alloys. Appl. Phys. Lett. 86, 241909 2005CrossRefGoogle Scholar
4Zhang, G.Q., Jiang, Q.K., Chen, L.Y., Shao, M., Liu, J.F.Jiang, J.Z.: Synthesis of centimeter-size Ag-doped Zr–Cu–Al metallic glasses with large plasticity. J. Alloys Compd. 424, 176 2006CrossRefGoogle Scholar
5He, Y., Schwarz, R.B.Archuleta, J.I.: Bulk glass formation in the Pd–Ni–P system. Appl. Phys. Lett. 69, 1861 1996CrossRefGoogle Scholar
6Inoue, A., Zhang, T., Nishiyama, N., Ohba, K.Masumoto, T.: Preparation of 16 mm diameter rod of amorphous Zr65Al7.5Ni10Cu17.5 alloy. Mater. Trans., JIM 34, 1234 1993CrossRefGoogle Scholar
7Ma, H., Shi, L.L., Xu, J., Li, Y.Ma, E.: Discovering inch-diameter metallic glasses in three-dimensional composition space. Appl. Phys. Lett. 87, 181915 2005Google Scholar
8Xu, D.H., Duan, G.Johnson, W.L.: Unusual glass-forming ability of bulk amorphous alloys based on ordinary metal copper. Phys. Rev. Lett. 92, 245504 2004CrossRefGoogle ScholarPubMed
9Dai, C.L., Hua, G., Yong, S., Li, Y., Ma, E.Xu, J.: A new centimeter-diameter Cu-based bulk metallic glass. Scripta Mater. 54, 1403 2006CrossRefGoogle Scholar
10Ponnambalam, V., Poon, S.J.Shiflet, G.J.: Fe-based bulk metallic glasses with diameter thickness larger than one centimeter. J. Mater. Res. 19, 1320 2004Google Scholar
11Shen, J., Chen, Q.J., Sun, J.F., Fan, H.B.Wang, G.: Exceptionally high glass-forming ability of an FeCoCrMoCBY alloy. Appl. Phys. Lett. 86, 151907 2005CrossRefGoogle Scholar
12Lu, Z.P., Liu, C.T., Thompson, J.R.Porter, W.D.: Structural amorphous steels. Phys. Rev. Lett. 92, 245503 2004CrossRefGoogle ScholarPubMed
13Park, E.S.Kim, D.H.: Rapid lateral solidification of pure Cu and Au thin films encapsulated in SiO2. Appl. Phys. Lett. 86, 201912 2005CrossRefGoogle Scholar
14Guo, F.Q., Poon, S.J.Shiflet, G.J.: Metallic glass ingots based on yttrium. Appl. Phys. Lett. 83, 2575 2005CrossRefGoogle Scholar
15Zhang, Y., Tan, H.Li, Y.: Bulk glass formation of 12 mm rod in La–Cu–Ni–Al alloys. Mater. Sci. Eng., A 375, 436 2004CrossRefGoogle Scholar
16Li, R., Pang, S.J., Men, H., Ma, C.L.Zhang, T.: Formation and mechanical properties of (Ce–La–Pr–Nd)–Co–Al bulk glassy alloys with superior glass-forming ability. Scripta Mater. 54, 1123 2006CrossRefGoogle Scholar
17Zhang, B., Wang, R.J., Zhao, D.Q., Pan, M.X.Wang, W.H.: Superior glass-forming ability through microalloying in cerium-based alloys. Phys. Rev. B: Solid State 73, 092201 2006CrossRefGoogle Scholar
18Jiang, Q.K., Zhang, G.Q., Chen, L.Y., Wu, J.Z., Zhang, H.G.Jiang, J.Z.: Glass formability, thermal stability and mechanical properties of La-based bulk metallic glasses. J. Alloys Compd. 424, 183 2006CrossRefGoogle Scholar
19Lowhaphandu, P., Ludrosky, L.A., Montgomery, S.L.Lewandowski, J.J.: Deformation and fracture toughness of a bulk amorphous Zr-Ti-Ni-Cu-Be alloy. Intermetallics 8, 487 2000CrossRefGoogle Scholar
20Alpas, A.T., Edwards, L.Reid, C.N.: Fracture and fatigue-crack propagation in a nickel-base metallic glass. Metall. Trans. A 20, 1395 1989CrossRefGoogle Scholar
21He, G., Lu, J., Bian, Z., Chen, D.J., Chen, G.L., Tu, G.H.Chen, G.J.: Fracture morphology and quenched-in precipitates induced embrittlement in a Zr-base bulk glass. Mater. Trans. 42, 356 2001CrossRefGoogle Scholar
22Inoue, A., Kimura, H.M.Zhang, T.: High-strength aluminum- and zirconium-based alloys containing nanoquasicrystalline particles. Mater. Sci. Eng., A 294, 727 2000CrossRefGoogle Scholar
23Inoue, A., Zhang, W., Zhang, T.Kurosaka, K.: High-strength Cu-based bulk glassy alloys in Cu-Zr-Ti and Cu-Hf-Ti ternary systems. Acta Mater. 49, 2645 2001CrossRefGoogle Scholar
24Liu, C.T., Heatherly, L., Easton, D.S., Carmichael, C.A., Schneibel, J.H., Chen, C.H., Wright, J.L., Yoo, M.H., Horton, J.A.Inoue, A.: Test environments and mechanical Properties of Zr-base bulk amorphous alloys. Metall. Mater. Trans. A 29, 1811 1998CrossRefGoogle Scholar
25Zhang, Z.F., He, G., Eckert, J.Schultz, L.: Fracture mechanisms in bulk metallic glassy materials. Phys. Rev. Lett. 91, 045505 2003Google Scholar
26Lee, M.L., Li, Y.Schuh, C.A.: Effect of a controlled volume fraction of dendritic phases on tensile and compressive ductility in La-based metallic glass. Acta Mater. 52, 4121 2004CrossRefGoogle Scholar
27Bobrov, O.P., Laptev, S.N., Neuhauser, H., Khonik, V.A.Csach, K.: Stress relaxation and viscosity of a bulk Pd40Cu30Ni10P20 metallic glass under isochronous heating conditions. Phys. Sol. State (St. Petersburg). 46, 1801 2004Google Scholar
28Bobrov, O.P., Khonik, V.A.Laptev, S.N.: Isochronal tensile stress relaxation of a bulk metallic glass. Scripta Mater. 50, 337 2004CrossRefGoogle Scholar
29Bobrov, O.P., Laptev, S.N.Khonik, V.A.: Stress relaxation in an Zr52.5Ti5Cu17.9Ni14.6Al10 bulk metallic glass. Phys. Sol. State (St. Petersburg) 46, 471 2004Google Scholar
30Bobrov, O.P., Khonik, V.A., Kitagawa, K.Laptev, S.N.: Isothermal stress relaxation of bulk and ribbon Zr-based metallic glass. J. Non-Cryst. Solids 342, 152 2004CrossRefGoogle Scholar
31Bobrov, O.P., Csach, K., Khonik, V.A., Kitagawa, K., Laptev, S.N.Yazvitsky, M.Yu.: Stress relaxation of bulk and ribbon glassy Pd40Cu30Ni10P20. Scripta Mater. 54, 369 2006CrossRefGoogle Scholar
32Cohen, M.H.Turnbull, D.: Relation between dispersion and intensity measurements in pure liquids. J. Chem. Phys. 31, 1146 1959Google Scholar
33Turnbull, D.Cohen, M.H.: Free-volume model of the amorphous phase: Glass transition. J. Chem. Phys. 34, 120 1961CrossRefGoogle Scholar
34Hey, P.D., Sietsma, J.van den Beukel, A.: Structural disordering in amorphous Pd40Ni40P20 induced by high temperature deformation. Acta Mater. 46, 5873 1998CrossRefGoogle Scholar
35van den Beukel, A.Sietsman, J.: The glass transition as a free volume related kinetic phenomenon. Acta Metall. Mater. 38, 383 1990Google Scholar
36Daniel, B.S.S., Reger-Leonhard, A., Heilmaier, M., Eckert, J.Schultz, L.: Thermal relaxation and high temperature creep of. Zr55Cu30Al10Ni5 bulk metallic glass. Mech. Time-Depend. Mater. 6, 193 2002CrossRefGoogle Scholar
37Slipenyuk, A.Eckert, J.: Correlation between enthalpy change and free volume reduction during structural relaxation of Zr55Cu30Al10Ni5 metallic glass. Scripta Mater. 50, 39 2004CrossRefGoogle Scholar
38Martin, S.W., Walleser, J., Karthikeyan, A.Sordelet, D.J.: Enthalpy relaxation studies of the glass transition in a metallic glass. J. Non-Cryst. Solids 349, 347 2004CrossRefGoogle Scholar
39Harms, U., Jin, O.Schwarz, R.B.: Effects of plastic deformation on the elastic modulus and density of bulk amorphous Pd40Ni10Cu30P20. J. Non-Cryst. Solids 317, 200 2003CrossRefGoogle Scholar
40Fan, C., Liaw, P.K., Wilson, T.W., Dmowski, W., Choo, H., Liu, C.T., Richardson, J.W.Proffen, Th.: Structural model for bulk amorphous alloys. Appl. Phys. Lett. 89, 111905 2006CrossRefGoogle Scholar
41Fan, C., Liaw, P.K., Haas, V., Wall, J.J., Choo, H., Inoue, A.Liu, C.T.: Structures and mechanical behaviors of Zr55Cu35Al10 bulk amorphous alloys at ambient and cryogenic temperatures. Phys. Rev. B 74, 014205 2006CrossRefGoogle Scholar
42Fan, C., Liaw, P.K., Wilson, T., Choo, H., Gao, Y.F.Liu, C.T.: Pair distribution function study and mechanical behavior of as-cast and structurally relaxed Zr-based bulk metallic glasses. Appl. Phys. Lett. 89, 231920 2006CrossRefGoogle Scholar
43Spaepen, F.: Microscopic mechanism for steady state inhomogeneous flow in metallic glasses. Acta Metall. 25, 407 1977CrossRefGoogle Scholar
44Argon, A.S.: Plastic deformation in metallic glasses. Acta Metall. 27, 47 1979CrossRefGoogle Scholar
45Kimura, H.Masumoto, T.: Fracture toughness of amorphous metals. Scripta Metall. 9, 211 1975CrossRefGoogle Scholar