Hostname: page-component-78c5997874-v9fdk Total loading time: 0 Render date: 2024-11-02T21:26:01.644Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis of multi-branched gold nanostructures and their surface-enhanced Raman scattering properties of 4-aminothiophenol

Published online by Cambridge University Press:  07 February 2019

Min He ,
Beibei Cao ,
Xiangxiang Gao ,
Bin Liu  and
Jianhui Yang
Min He
Affiliation:
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi’an 710127, People’s Republic of China
Beibei Cao
Affiliation:
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi’an 710127, People’s Republic of China
Xiangxiang Gao
Affiliation:
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi’an 710127, People’s Republic of China
Bin Liu
Affiliation:
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi’an 710127, People’s Republic of China
Jianhui Yang*
Affiliation:
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi’an 710127, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

A facile one-pot and environmentally friendly method was developed to synthesize multi-branched flowerlike gold (Au) nanostructures by reducing chlorate gold (HAuCl4) with hydrogen peroxide (H2O2) in the presence of sodium citrate. The multibranched Au nanostructures were characterized by transmission electron microscopy and Ultraviolet-visible (UV-vis) absorption spectroscopy. The molar ratio of sodium citrate to HAuCl4 and the concentrations of the reacted reagents play important roles in the formation of multibranched Au nanostructures. The multibranched Au nanostructures with sharp tips exhibit excellent surface-enhanced Raman scattering (SERS) ability of 4-aminothiophenol (PATP). The experimental and simulated results both confirm that the photoinduced catalytic coupling reaction of PATP transformation to 4,4′-dimercaptoazobenzene occurs on the surface of multibranched Au nanostructures at a high power during the SERS measurement. It is believed that these multibranched Au nanostructures may find potential applications in SERS, biosensors, and the photoinduced surface catalytic application fields.

Keywords

AunanostructureRaman spectroscopy
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 17: Focus Issue: Building Advanced Materials via Particle Aggregation and Molecular Self-Assembly , 16 September 2019 , pp. 2928 - 2934
Copyright
Copyright © Materials Research Society 2019 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Sau, T.K. and Rogach, A.L.: Nonspherical noble metal nanoparticles: Colloid-chemical synthesis and morphology control. Adv. Mater. 22, 1781 (2010).CrossRefGoogle ScholarPubMed
Sau, T.K., Rogach, A.L., Jäckel, F., Klar, T.A., and Feldmann, J.: Properties and applications of colloidal nonspherical noble metal nanoparticles. Adv. Mater. 22, 1805 (2010).CrossRefGoogle ScholarPubMed
Daniel, M.C. and Astruc, D.: Gold nanoparticles: Assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology. Chem. Rev. 104, 293 (2004).CrossRefGoogle ScholarPubMed
Eustis, S. and El-Sayed, M.A.: Why gold nanoparticles are more precious than pretty gold: Noble metal surface plasmon resonance and its enhancement of the radiative and nonradiative properties of nanocrystals of different shapes. Chem. Soc. Rev. 35, 209 (2006).CrossRefGoogle ScholarPubMed
Sepulveda, B., Angelome, P.C., Lechuga, L.M., and Liz-Marzan, L.M.: LSPR-based nanobiosensors. Nano Today 4, 244 (2009).CrossRefGoogle Scholar
Nehl, C.L. and Hafner, J.H.: Shape-dependent plasmon resonances of gold nanoparticles. J. Mater. Chem. 18, 2415 (2008).CrossRefGoogle Scholar
Mayer, K.M. and Hafner, J.H.: Localized surface plasmon resonance sensors. Chem. Rev. 111, 3828 (2011).CrossRefGoogle ScholarPubMed
Li, M., Kang, J.W., Dasari, R.R., and Barman, I.: Shedding light on the extinction-enhancement duality in gold nanostar-enhanced Raman spectroscopy. Angew. Chem., Int. Ed. 53, 14115 (2014).CrossRefGoogle ScholarPubMed
Hao, F., Nehl, C.L., Hafner, J.H., and Nordlander, P.: Plasmon resonances of a gold nanostar. Nano Lett. 7, 729 (2007).CrossRefGoogle ScholarPubMed
Li, M., Cushing, S.K., Zhang, J., Lankford, J., Aguilar, Z.P., Ma, D., and Wu, N.: Shape-dependent surface-enhanced Raman scattering in gold-Raman-probe-silica sandwiched nanoparticles for biocompatible applications. Nanotechnology 23, 115501 (2012).CrossRefGoogle ScholarPubMed
Jana, N.R. and Pal, T.: Anisotropic metal nanoparticles for use as surface-enhanced Raman substrates. Adv. Mater. 19, 1761 (2007).CrossRefGoogle Scholar
Grzelczak, M., Perez-Juste, J., Mulvaney, P., and Liz-Marzan, L.M.: Shape control in gold nanoparticle synthesis. Chem. Soc. Rev. 37, 1783 (2008).CrossRefGoogle ScholarPubMed
Guerrero-Martinez, A., Barbosa, S., Pastoriza-Santos, I., and Liz-Marzan, L.M.: Nanostars shine bright for you. Curr. Opin. Colloid Interface Sci. 16, 118 (2011).CrossRefGoogle Scholar
Senthil, K.P., Pastoriza-Santos, I., Rodriguez-González, B., Javier, G.d.A.F., and Liz-Marzan, L.M.: High-yield synthesis and optical response of gold nanostars. Nanotechnology 19, 015606 (2008).CrossRefGoogle Scholar
Xia, T., Luo, H., Wang, S., Liu, J., Yu, G., and Wang, R.: Large scale synthesis of gold dendritic nanostructures for surface enhanced Raman scattering. CrystEngComm 17, 4200 (2015).CrossRefGoogle Scholar
Jena, B.K. and Raj, C.R.: Seedless, surfactantless room temperature synthesis of single crystalline fluorescent gold nanoflowers with pronounced SERS and electrocatalytic activity. Chem. Mater. 20, 3546 (2008).CrossRefGoogle Scholar
Wang, L., Imura, M., and Yamauchi, Y.: Tailored synthesis of various Au nanoarchitectures with branched shapes. CrystEngComm 14, 7594 (2012).CrossRefGoogle Scholar
Milligan, W.O. and Morriss, R.H.: Morphology of colloidal gold—A comparative study. J. Am. Chem. Soc. 86, 3461 (1964).CrossRefGoogle Scholar
Paclawski, K. and Fitzner, K.: Kinetics of reduction of gold(III) complexes using H2O2. Metall. Mater. Trans. B 37, 703 (2006).CrossRefGoogle Scholar
Panda, B.R. and Chattopadhyay, A.: Synthesis of Au nanoparticles at “all” pH by H2O2 reduction of HAuCl4. J. Nanosci. Nanotechnol. 7, 1911 (2007).CrossRefGoogle Scholar
Hao, E., Bailey, R.C., Schatz, G.C., Hupp, J.T., and Li, S.: Synthesis and optical properties of “branched” gold nanocrystals. Nano Lett. 4, 327 (2004).CrossRefGoogle Scholar
Bakr, O.S., Wunsch, B.H., and Stellacci, F.: High-yield synthesis of multi-branched urchin-like gold nanoparticles. Chem. Mater. 18, 3297 (2006).CrossRefGoogle Scholar
Turkevich, J., Stevenson, P.C., and Hillier, J.: A study of the nucleation and growth processes in the synthesis of colloidal gold. Discuss. Faraday Soc. 11, 55 (1951).CrossRefGoogle Scholar
Frens, G.: Controlled nucleation for the regulation of the particle size in monodisperse gold suspensions. Nat. Phys. Sci. 241, 20 (1973).CrossRefGoogle Scholar
Pei, L., Mori, K., and Adachi, M.: Formation process of two-dimensional networked gold nanowires by citrate reduction of AuCl4− and the shape stabilization. Langmuir 20, 7837 (2004).CrossRefGoogle ScholarPubMed
Zou, X., Ying, E., and Dong, S.: Seed-mediated synthesis of branched gold nanoparticles with the assistance of citrate and their surface-enhanced Raman scattering properties. Nanotechnology 17, 4758 (2006).CrossRefGoogle ScholarPubMed
Park, J-W. and Shumaker-Parry, J.S.: Structural study of citrate layers on gold nanoparticles: Role of intermolecular interactions in stabilizing nanoparticles. J. Am. Chem. Soc. 136, 1907 (2014).CrossRefGoogle Scholar
Zou, H., Ren, G., Shang, M., and Wang, W.: One-step, seedless, fabrication of three-dimensional gold meso-flowers (3D-AuMFs) with high activities in catalysis and surface-enhanced Raman scattering. Mater. Chem. Phys. 176, 115 (2016).CrossRefGoogle Scholar
Link, S. and El-Sayed, M.A.: Size and temperature dependence of the plasmon absorption of colloidal gold nanoparticles. J. Phys. Chem. B 103, 4212 (1999).CrossRefGoogle Scholar
Jain, P.K., Lee, K.S., El-Sayed, I.H., and El-Sayed, M.A.: Calculated absorption and scattering properties of gold nanoparticles of different size, shape, and composition: applications in biological imaging and biomedicine. J. Phys. Chem. B 110, 7238 (2006).CrossRefGoogle ScholarPubMed
Sun, L., Hu, H., Zhan, D., Yan, J., Liu, L., Teguh, J.S., Yeow, E.K.L., Lee, P.S., and Shen, Z.: Plasma modified MoS2 nanoflakes for surface enhanced Raman scattering. Small 10, 1090 (2014).CrossRefGoogle ScholarPubMed
Yan, D., Qiu, W., Chen, X., Liu, L., Lai, Y., Meng, Z., Song, J., Liu, Y., Liu, X., and Zhan, D.: Achieving high-performance surface-enhanced Raman scattering through one-step thermal treatment of bulk MoS2. J. Phys. Chem. C 122, 14467 (2018).CrossRefGoogle Scholar
Huang, Y., Wu, D., Zhu, H., Zhao, L., Liu, G., Ren, B., and Tian, Z.: Surface-enhanced Raman spectroscopic study of p-aminothiophenol. Phys. Chem. Chem. Phys. 14, 8485 (2012).CrossRefGoogle ScholarPubMed
Cao, B., Liu, B., and Yang, J.: Facile synthesis of single crystalline gold nanoplates and SERS investigations of 4-aminothiophenol. CrystEngComm 15, 5735 (2013).CrossRefGoogle Scholar
Xu, P., Kang, L., Mack, N.H., Schanze, K.S., Han, X., and Wang, H.L.: Mechanistic understanding of surface plasmon assisted catalysis on a single particle: Cyclic redox of 4-aminothiophenol. Sci. Rep. 3, 2997 (2013).CrossRefGoogle ScholarPubMed
Kim, H., Kosuda, K.M., Van Duyne, R.P., and Stair, P.C.: Resonance Raman and surface- and tip-enhanced Raman spectroscopy methods to study solid catalysts and heterogeneous catalytic reactions. Chem. Soc. Rev. 39, 4820 (2010).CrossRefGoogle ScholarPubMed
Wu, D., Zhao, L., Liu, X., Huang, R., Huang, Y., Ren, B., and Tian, Z.: Photon-driven charge transfer and photocatalysis of p-aminothiophenol in metal nanogaps: A DFT study of SERS. Chem. Commun. 47, 2520 (2011).CrossRefGoogle ScholarPubMed