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Synthesis of metastable tetragonal (t′) zirconia-calcia solid solution by pyrolysis of organic precursors and coprecipitation route

Published online by Cambridge University Press:  31 January 2011

Masatomo Yashima ,
Masato Kakihana ,
Koutaroh Ishii ,
Yasuro Ikuma  and
Masahiro Yoshimura
Masatomo Yashima
Affiliation:
Research Laboratory of Engineering Materials, Tokyo Institute of Technology, Nagatsuta 4259, Midori-ku, Yokohama, 226, Japan
Masato Kakihana
Affiliation:
Research Laboratory of Engineering Materials, Tokyo Institute of Technology, Nagatsuta 4259, Midori-ku, Yokohama, 226, Japan
Koutaroh Ishii
Affiliation:
Department of Industrial Chemistry, Faculty of Technology, Kanagawa Institute of Technology, Shimo-Ogino 1030, Atsugi, Kanagawa, 243–02, Japan
Yasuro Ikuma
Affiliation:
Department of Industrial Chemistry, Faculty of Technology, Kanagawa Institute of Technology, Shimo-Ogino 1030, Atsugi, Kanagawa, 243–02, Japan
Masahiro Yoshimura
Affiliation:
Research Laboratory of Engineering Materials, Tokyo Institute of Technology, Nagatsuta 4259, Midori-ku, Yokohama, 226, Japan
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Abstract

Three kinds of chemical processes, citrate gel process, acetate gel process, and coprecipitation route, have been applied to the synthesis of homogeneous metastable tetragonal (t′) and cubic solid solutions of ZrO2−X mol% CaO (X = 4–20). From a Raman scattering study, the citrate gel process based on the gelation of the aqueous solution of citric acid containing Zr and Ca ions was found to produce compositionally homogeneous samples in comparison with the other two methods. The axial ratio c/a decreases with increasing concentration of CaO and becomes unity around 8–10 mol% CaO composition.

Type
Articles
Information
Journal of Materials Research , Volume 11 , Issue 6 , June 1996 , pp. 1410 - 1420
Copyright
Copyright © Materials Research Society 1996

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