Hostname: page-component-586b7cd67f-l7hp2 Total loading time: 0 Render date: 2024-11-24T10:25:45.113Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis and catalysis properties of NiO flower-like spheres and nanosheets: Water-induced phase transformation of nickel hydroxides

Published online by Cambridge University Press:  16 November 2011

Xin Liang ,
Junjia Xiao ,
Ye Gou  and
Biaohua Chen
Xin Liang
Affiliation:
The State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China; and Faculty of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Junjia Xiao
Affiliation:
Faculty of Chemical Engineering, Beijing University of Chemical Technology, Beijing, 100029, China
Ye Gou
Affiliation:
Faculty of Chemical Engineering, Beijing University of Chemical Technology, Beijing, 100029, China
Biaohua Chen*
Affiliation:
Faculty of Chemical Engineering, Beijing University of Chemical Technology, Beijing, 100029, China
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

An oleylamine-assisted solvothermal approach has been developed for the synthesis of nickel hydroxide nanomaterials. α-Ni(OH)2 flower-like spheres and β-Ni(OH)2 hexagonal sheets were obtained by tuning the water volume in the synthesis system. The water-induced phase and morphology evolution from α-Ni(OH)2 spheres to β-Ni(OH)2 sheets were investigated in detail by controlled experiments based on their crystal structures. Moreover, NiO spheres and sheets were obtained by direct thermal decomposition of corresponding nickel hydroxides. N2 adsorption/desorption, temperature-programmed reduction with H2, and catalytic activity tests reveal that NiO spheres exhibit higher surface area, larger pore volume, higher reducibility, and better catalysis activities for CO oxidation than NiO sheets.

Keywords

WaterCrystallineCatalytic
Type
Articles
Information
Journal of Materials Research , Volume 26 , Issue 24 , 28 December 2011 , pp. 3091 - 3097
Copyright
Copyright © Materials Research Society 2011

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Poizot, P., Laruelle, S., Grugeon, S., Dupont, L., and Tarascon, J.M.: Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries. Nature 407, 496 (2000).CrossRefGoogle ScholarPubMed
2.Park, J., Kang, E., Son, S.U., Park, H.M., Lee, M.K., Kim, J., Kim, K.W., Noh, H.J., Park, J.H., Bae, C.J., Park, J.G., and Hyeon, T.: Monodisperse nanoparticles of Ni and NiO: Synthesis, characterization, self-assembled superlattices, and catalytic applications in the Suzuki coupling reaction. Adv. Mater. 17, 429 (2005).CrossRefGoogle Scholar
3.Li, Y., Zhang, B.C., Xie, X.W., Liu, J.L., Xu, Y.D., and Shen, W.J.: Novel Ni catalysts for methane decomposition to hydrogen and carbon nanofibers. J. Catal. 238, 412 (2006).CrossRefGoogle Scholar
4.Liu, K. and Anderson, M.: Porous nickel oxide/nickel films for electrochemical capacitors. J. Electrochem. Soc. 143, 124 (1996).CrossRefGoogle Scholar
5.Zhang, X.J., Shi, W.H., Zhu, J.X., Zhao, W.Y., Ma, J., Mhaisalkar, S., Maria, T.L., Yang, Y.H., Zhang, H., Hng, H.H., and Yan, Q.Y.: Synthesis of porous NiO nanocrystals with controllable surface area and their application as supercapacitor electrodes. Nano Res. 3, 643 (2010).CrossRefGoogle Scholar
6.Felici, A.C., Lama, F., Piacentini, M., Papa, T., Debowska, D., Kisiel, A., and Rodzik, A.: Photoacoustic spectroscopy of diluted magnetic semiconductors. J. Appl. Phys. 80, 6925 (1996).CrossRefGoogle Scholar
7.Mattei, G., Mazzoldi, P., Post, M.L., Buso, D., Guglielmi, M., and Martucci, A.: Cookie-like Au/NiO nanoparticles with optical gas-sensing properties. Adv. Mater. 19, 561 (2007).CrossRefGoogle Scholar
8.Wu, Z.Y., Liu, C.M., Guo, L., Hu, R., Abbas, M.I., Hu, T.D., and Xu, H.B.: Structural characterization of nickel oxide nanowires by X-ray absorption near-edge structure spectroscopy. J. Phys. Chem. B 109, 2512 (2005).CrossRefGoogle ScholarPubMed
9.Ni, X.M., Zhao, Q.B., Zhou, F., Zheng, H.G., Cheng, J., and Li, B.B.: Synthesis and characterization of NiO strips from a single source. J. Cryst. Growth 289, 299 (2006).CrossRefGoogle Scholar
10.Zhao, B., Ke, X.K., Bao, J.H., Wang, C.L., Dong, L., and Chen, H.L.: Synthesis of flower-like NiO and effects of morphology on its catalytic properties. J. Phys. Chem. C 113, 14440 (2009).CrossRefGoogle Scholar
11.Malandrino, G., Perdicaro, L.M.S., Fragalà, I.L., Nigro, R.L., Losurdo, M., and Bruno, G.: MOCVD template approach to the fabrication of free-standing nickel(II) oxide nanotube arrays: Structural, morphological, and optical properties characterization. J. Phys. Chem. C 111, 3211 (2007).CrossRefGoogle Scholar
12.Liang, J. and Li, Y.D.: Synthesis and characterization of Ni(OH)2 single-crystal nanorods. Chem. Lett. 32, 1126 (2003).CrossRefGoogle Scholar
13.Wang, D.S., Xu, R., Wang, X., and Li, Y.D.: NiO nanorings and their unexpected catalytic property for CO oxidation. Nanotechnology 17, 979 (2006).CrossRefGoogle ScholarPubMed
14.Hu, J.C., Zhu, K.K., Chen, L.F., Yang, H.J., Li, Z., Suchopar, A., and Richards, R.: Preparation and surface activity of single-crystalline NiO(111) nanosheets with hexagonal holes: A semiconductor nanospanner. Adv. Mater. 20, 267 (2008).CrossRefGoogle Scholar
15.Liang, Z.H., Zhu, Y.J., and Hu, X.L.: β-Nickel hydroxide nanosheets and their thermal decomposition to nickel oxide nanosheets. J. Phys. Chem. B 108, 3488 (2004).CrossRefGoogle Scholar
16.Yang, L.X., Zhu, Y.J., Tong, H., Liang, Z.H., and Wang, W.W.: Hierarchical β-Ni(OH)2 and NiO carnations assembled from nanosheet building blocks. Cryst. Growth Des. 7, 2716 (2007).CrossRefGoogle Scholar
17.Yang, Q., Sha, J., Ma, X.Y., and Yang, D.R.: Synthesis of NiO nanowires by a sol-gel process. Mater. Lett. 59, 1967 (2005).CrossRefGoogle Scholar
18.Sun, X.M., Liu, J.F., and Li, Y.D.: Use of carbonaceous polysaccharide microspheres as templates for fabricating metal oxide hollow spheres. Chemistry 12, 2039 (2006).CrossRefGoogle ScholarPubMed
19.Ni, X.M., Zhang, Y.F., Tian, D.Y., Zheng, H.G., and Wang, X.W.: Synthesis and characterization of hierarchical NiO nanoflowers with porous structure. J. Cryst. Growth 306, 418 (2007).CrossRefGoogle Scholar
20.Olivaa, P., Leonardia, J., Laurenta, J. F., Delmasb, C., Braconnierb, J. J., Figlarzc, M., Fievetc, F., and De Guibert, A.: Review of the structure and the electrochemistry of nickel hydroxides and oxy-hydroxides. J. Power Sources 8, 229 (1982).CrossRefGoogle Scholar
21.Wang, H.L., Casalongue, H.S., Liang, Y.Y., and Dai, H.J.: Ni(OH)2 nanoplates grown on graphene as advanced electrochemical pseudocapacitor materials. J. Am. Chem. Soc. 132, 7472 (2010).CrossRefGoogle ScholarPubMed
22.Qi, Y.J., Qi, H.Y., Li, J.H., and Lu, C.J.: Synthesis, microstructures and UV-vis absorption properties of β-Ni(OH)2 nanoplates and NiO nanostructures. J. Cryst. Growth 310, 4221 (2008).CrossRefGoogle Scholar
23.Rajamathi, M., Kamatha, P.V., and Seshadri, R.: Polymorphism in nickel hydroxide: Role of interstratifications. J. Mater. Chem. 10, 503 (2000).CrossRefGoogle Scholar
24.Corringan, D.A. and Knight, S.L.: Electrochemical and spectroscopic evidence on the participation of quadrivalent nickel in the nickel hydroxide redox reaction. J. Electrochem. Soc. 136, 613 (1989).CrossRefGoogle Scholar
25.Barnard, R., Randell, C.F., and Tye, F.F.: Studies concerning charged nickel hydroxide electrodes I. Measurement of reversible potentials. J. Appl. Electrochem. 10, 109 (1980).CrossRefGoogle Scholar
26.Xu, L.P., Ding, Y.S., Chen, C.H., Zhao, L.L., Rimkus, C., Joesten, R., and Suib, S.L.: 3D flowerlike α-Nickel hydroxide with enhanced electrochemical activity synthesized by microwave-assisted hydrothermal method. Chem. Mater. 20, 308 (2008).CrossRefGoogle Scholar
27.Zhao, Y.L., Wang, J.M., Chen, H., Pana, T., Zhang, J.Q., and Cao, C.N.: Al-substituted alpha-nickel hydroxide prepared by homogeneous precipitation method with urea. Int. J. Hydrogen Energy 29, 889 (2004).CrossRefGoogle Scholar
28.Kuang, D.B., Lei, B.X., Pan, Y.P., Yu, X.Y., and Su, C.Y.: Fabrication of novel hierarchical β-Ni(OH)2 and NiO microspheres via an easy hydrothermal process. J. Phys. Chem. C 113, 5508 (2009).CrossRefGoogle Scholar
Supplementary material: File

Liang Supplementary Material

Liang Supplementary Material

Download Liang Supplementary Material(File)
File 2.4 MB