Hostname: page-component-586b7cd67f-r5fsc Total loading time: 0 Render date: 2024-11-24T08:43:21.095Z Has data issue: false hasContentIssue false
  • English
  • Français

Synergic effect of nanostructuring and excess Mn3+ content in the electrochemical performance of Li4Ti5O12–LiNi0.5Mn1.5O4 Li-ion full-cells

Published online by Cambridge University Press:  11 October 2019

Anulekha K. Haridas Open the ORCID record for Anulekha K. Haridas [Opens in a new window] ,
Adduru Jyothirmayi ,
Chandra S. Sharma Open the ORCID record for Chandra S. Sharma [Opens in a new window]  and
Tata N. Rao
Anulekha K. Haridas
Affiliation:
International Advanced Research Centre for Powder Metallurgy and New Materials (ARCI), Hyderabad, Telangana, 500005, India; and Creative & Advanced Research Based on Nanomaterials (CARBON) Laboratory, Department of Chemical Engineering, Indian Institute of Technology Hyderabad, Sangareddy, Telangana 502285, India
Adduru Jyothirmayi
Affiliation:
International Advanced Research Centre for Powder Metallurgy and New Materials (ARCI), Hyderabad, Telangana, 500005, India
Chandra S. Sharma*
Affiliation:
Creative & Advanced Research Based on Nanomaterials (CARBON) Laboratory, Department of Chemical Engineering, Indian Institute of Technology Hyderabad, Sangareddy, Telangana 502285, India
Tata N. Rao*
Affiliation:
International Advanced Research Centre for Powder Metallurgy and New Materials (ARCI), Hyderabad, Telangana, 500005, India
*
a)Address all correspondence to these authors. e-mail: [email protected]
b)e-mail: [email protected]
Get access

Abstract

The design of high energy Li-ion batteries (LIBs) by coupling high voltage LiNi0.5Mn1.5O4 (LNMO) cathode and Li4Ti5O12 (LTO) anode ensures effective and safe energy-storage. LTO–LNMO full-cells (FCs) with difference in electrode grain sizes and presence of excess Mn3+ in cathode were studied using micron-sized commercial LTO, nanostructured LTO donuts (LTOd), P4332 LNMO nanopowders, and nanostructured Fd3m LNMO caterpillars (LNMOcplr). Among the studied FCs, LTOd–LNMOcplr was detected with a stable capacity of 69 mA h/g (1C rate), 99% coulombic efficiency, and 87% capacity retention under 200 cycles of continuous charge–discharge studies. The superior electrochemical performance observed in LTOd–LNMOcplr FC was due to the low charge transfer resistance, which is corroborated to the effect of grain sizes and the longer retention of Mn3+ in the electrodes. An effective and simple FC design incorporating both nanostructuring and in situ conductivity in electrode materials would aid in developing future high-performance LIBs.

Keywords

Linanostructureenergy storage
Type
Article
Information
Journal of Materials Research , Volume 35 , Issue 1: Focus Section: Advances in Battery Technology: Material Innovations in Design and Fabrication , 14 January 2020 , pp. 42 - 50
Copyright
Copyright © Materials Research Society 2019 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

c)

Present Address: Department of Chemical and Bio-molecular Engineering, Rice University, Houston, Texas, USA.

References

Wakihara, M.: Recent developments in lithium ion batteries. Mater. Sci. Eng., R 33, 109 (2001).CrossRefGoogle Scholar
Nitta, N., Wu, F., Lee, J.T., and Yushin, G.: Li-ion battery materials: Present and future. Mater. Today 18, 252 (2015).CrossRefGoogle Scholar
Bruce, P.G., Scrosati, B., and Tarascon, J-M.: Nanomaterials for rechargeable lithium batteries. Angew. Chem., Int. Ed. 47, 2930 (2008).CrossRefGoogle ScholarPubMed
Yin, S.Y., Song, L., Wang, X.Y., Zhang, M.F., Zhang, K.L., and Zhang, Y.X.: Synthesis of spinel Li4Ti5O12 anode material by a modified rheological phase reaction. Electrochim. Acta 54, 5629 (2009).CrossRefGoogle Scholar
Tikekar, N.M., Lannutti, J.J., Rao Revur, R., and Sengupta, S.: High surface area lithium titanate electrode for Li-ion batteries. J. New Mater. Electrochem. Syst. 15, 265 (2012).CrossRefGoogle Scholar
Li, Y., Pan, G.L., Liu, J.W., and Gao, X.P.: Preparation of Li4Ti5O12 nanorods as anode materials for lithium-ion batteries. J. Electrochem. Soc. 156, A495 (2009).CrossRefGoogle Scholar
Zhang, W-J.: A review of the electrochemical performance of alloy anodes for lithium-ion batteries. J. Power Sources 196, 13 (2011).CrossRefGoogle Scholar
Ohzuku, T.: Zero-strain insertion material of Li [Li1/3Ti5/3]O4 for rechargeable lithium cells. J. Electrochem. Soc. 142, 1431 (1995).CrossRefGoogle Scholar
Choi, Z., Kramer, D., and Monig, R.: Correlation of stress and structural evolution in Li4Ti5O12-based electrodes for lithium ion batteries. J. Power Sources 240, 245 (2013).CrossRefGoogle Scholar
Zhang, A., Zheng, Z., Cheng, F., Tao, Z., and Chen, J.: Preparation of Li4Ti5O12 submicrospheres and their application as anode materials of rechargeable lithium-ion batteries. Sci. China Chem. 54, 936 (2011).CrossRefGoogle Scholar
Tang, Y., Huang, F., Zhao, W., Liu, Z., and Wan, D.: Synthesis of graphene supported Li4Ti5O12 nanosheets for high rate battery application. J. Mater. Chem. 22, 11257 (2012).CrossRefGoogle Scholar
Wang, J., Liu, X., and Yang, H.: Synthesis and electrochemical properties of highly dispersed Li4Ti5O12 nanocrystalline for lithium secondary batteries. Trans. Nonferrous Met. Soc. China 22, 613 (2012).CrossRefGoogle Scholar
Yi, T-F., Jiang, L-J., Shu, J., Yue, C-B., Zhu, R-S., and Qiao, H-B.: Recent development and application of Li4Ti5O12 as anode material of lithium ion battery. J. Phys. Chem. Solids 71, 1236 (2010).CrossRefGoogle Scholar
Guerfi, A., Sévigny, S., Lagacé, M., Hovington, P., Kinoshita, K., and Zaghib, K.: Nanoparticle Li4Ti5O12 spinel as electrode for electrochemical generators. J. Power Sources 119–121, 88 (2003).CrossRefGoogle Scholar
Mizushima, K., Jones, P.C., Wiseman, P.J., and Goodenough, J.B.: LixCoO2 (0 < x ≤ 1): A new cathode material for batteries of high energy density. Solid State Ionics 3–4, 171 (1981).CrossRefGoogle Scholar
Xiao, J., Chen, X., Sushko, P.V., Sushko, M.L., Kovarik, L., Feng, J., Deng, Z., Zheng, J., Graff, G.L., Nie, Z., Choi, D., Liu, J., Zhang, J.G., and Whittingham, M.S.: High-performance LiNi0.5Mn1.5O4 Spinel controlled by Mn3+ concentration and site disorder. Adv. Mater. 24, 2109 (2012).CrossRefGoogle ScholarPubMed
Kim, J., Myung, S., Yoon, C.S., Kang, S.G., and Sun, Y.: Comparative study of cathodes having two crystallographic structures: Fd3m and P4332. Chem. Mater. 10, 906 (2004).CrossRefGoogle Scholar
Wang, L., Li, H., Huang, X., and Baudrin, E.: A comparative study of $Fd\bar{3}m$ and P4332 “LiNi0.5Mn1.5O4”. Solid State Ionics 193, 32 (2011).CrossRefGoogle Scholar
Yang, J., Han, X., Zhang, X., Cheng, F., and Chen, J.: Spinel LiNi0.5Mn1.5O4 cathode for rechargeable lithium ion batteries: Nano vs micro, ordered phase (P4332) vs disordered phase $Fd\bar{3}m$. Nano Res. 6, 679 (2013).CrossRefGoogle Scholar
Song, J., Shin, D.W., Lu, Y., Amos, C.D., Manthiram, A., and Goodenough, J.B.: Role of oxygen vacancies on the performance of Li[Ni0.5−xMn1.5+x]O4 (x = 0, 0.05, and 0.08) spinel cathodes for lithium-ion batteries. Chem. Mater. 24, 3101 (2012).CrossRefGoogle Scholar
Zheng, J., Xiao, J., Yu, X., Kovarik, L., Gu, M., Omenya, F., Chen, X., Yang, X.Q., Liu, J., Graff, G.L., Whittingham, M.S., and Zhang, J.G.: Enhanced Li+-ion transport in LiNi0.5Mn1.5O4 through control of site disorder. Phys. Chem. Chem. Phys. 14, 13515 (2012).CrossRefGoogle ScholarPubMed
Haridas, A.K., Sharma, C.S., and Rao, T.N.: Donut-shaped Li4Ti5O12 structures as a high-performance anode material for lithium ion batteries. Small 11, 290 (2015).CrossRefGoogle ScholarPubMed
Haridas, A.K., Sharma, C.S., and Rao, T.N.: Caterpillar-like sub-micron LiNi0.5Mn1.5O4 structures with site disorder and excess Mn3+ as high-performance cathode material for lithium ion batteries. Electrochim. Acta 212, 500 (2016).CrossRefGoogle Scholar
Kunduraci, M. and Amatucci, G.G.: Synthesis and characterization of nanostructured 4.7 V LixMn1.5Ni0.5O4 spinels for high-power lithium-ion batteries. J. Electrochem. Soc. 153, A1345 (2006).CrossRefGoogle Scholar
Liu, G., Li, Y., Ma, B., and Li, Y.: Study of the intrinsic electrochemical properties of spinel LiNi0.5Mn1.5O4. Electrochim. Acta 112, 557 (2013).CrossRefGoogle Scholar
Amdouni, N., Zaghib, K., Gendron, F., Mauger, A., and Julien, C.M.: Structure and insertion properties of disordered and ordered LiNi0.5Mn1.5O4 spinels prepared by wet chemistry. Ionics 12, 117 (2006).CrossRefGoogle Scholar
Xiang, H.F., Zhang, X., Jin, Q.Y., Zhang, C.P., Chen, C.H., and Ge, X.W.: Effect of capacity matchup in the LiNi0.5Mn1.5O4/Li4Ti5O12 cells. J. Power Sources 183, 355 (2008).CrossRefGoogle Scholar
Zheng, J., Xiao, J., Nie, Z., and Zhang, J-G.: Lattice Mn3+ behaviours in Li4Ti5O12/LiNi0.5Mn1.5O4 full cells. J. Electrochem. Soc. 160, A1264 (2013).CrossRefGoogle Scholar
Supplementary material: File

Haridas et al. supplementary material

Haridas et al. supplementary material

Download Haridas et al. supplementary material(File)
File 505.3 KB