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A study of temperature and pressure induced structural and electronic changes in SbCl5 intercalated graphite: Part IV. The basal plane resistivity

Published online by Cambridge University Press:  03 March 2011

O.E. Andersson ,
B. Sundqvist ,
E. McRae ,
M. Lelaurain  and
J.F. Marêché
O.E. Andersson
Affiliation:
Department of Experimental Physics, University of Umeå. S-901 87 Umeå, Sweden
B. Sundqvist
Affiliation:
Department of Experimental Physics, University of Umeå. S-901 87 Umeå, Sweden
E. McRae
Affiliation:
Université de Nancy I, Laboratoire de Chimie du Solide Minéral, U.R.A. C.N.R.S. 158, Service de Chimie Minérale Appliquée, B.P. 239, 54506 Vandoeuvre-lès-Nancy Cédex. France
M. Lelaurain
Affiliation:
Université de Nancy I, Laboratoire de Chimie du Solide Minéral, U.R.A. C.N.R.S. 158, Service de Chimie Minérale Appliquée, B.P. 239, 54506 Vandoeuvre-lès-Nancy Cédex. France
J.F. Marêché
Affiliation:
Université de Nancy I, Laboratoire de Chimie du Solide Minéral, U.R.A. C.N.R.S. 158, Service de Chimie Minérale Appliquée, B.P. 239, 54506 Vandoeuvre-lès-Nancy Cédex. France
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Abstract

Using an inductive technique, we have measured the in-plane resistivity ρa of stages 2, 4, 5, and 8 SbCl5-GIC's versus temperature T and pressure p in the ranges 130–300 K and 0–0.85 GPa. The room temperature values of ρa range from 4.0 μΩcm for the stages 5 sample to 7.7 μΩcm for the stage 8 sample. At all pressures, ρa shows a metallic temperature dependence ρa ∼ Tα, with 1 ≤ a ≤ 2, but in contrast to the c-axis resistivity ρc, it depends only very weakly on pressure and/or intercalate structural order. We show that the behavior observed is consistent with a band conduction model.

Type
Articles
Information
Journal of Materials Research , Volume 10 , Issue 7 , July 1995 , pp. 1653 - 1660
Copyright
Copyright © Materials Research Society 1995

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References

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