Hostname: page-component-586b7cd67f-2plfb Total loading time: 0 Render date: 2024-11-28T00:32:29.216Z Has data issue: false hasContentIssue false
  • English
  • Français

Structural stability of layered n-LaFeO3–Bi4Ti3O12, BiFeO3–Bi4Ti3O12, and SrTiO3–Bi4Ti3O12 thin films

Published online by Cambridge University Press:  29 October 2012

Jian Zhou ,
Fei-Xiang Wu ,
Y.B. Chen ,
Shan-Tao Zhang  and
Yan-Feng Chen
Jian Zhou
Affiliation:
Department of Materials Science and Engineering and National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093, China
Fei-Xiang Wu
Affiliation:
Department of Materials Science and Engineering and National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093, China
Y.B. Chen*
Affiliation:
Department of Physics and National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093, China
Shan-Tao Zhang
Affiliation:
Department of Materials Science and Engineering and National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093, China
Yan-Feng Chen
Affiliation:
Department of Materials Science and Engineering and National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093, China
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

A series of layered n-ABO3-doped Aurivillius structures Bi4Ti3O12 (BTO) thin films are synthesized on (001) SrTiO3 (STO) substrates by pulsed laser deposition, where n represents the number of ABO3 perovskite. X-ray diffraction substantiates that these films have expected layered Aurivillius structures. Furthermore, the microstructure of these samples is “systematically” characterized by transmission electron microscopy. It is found that the structure of n-STO-doped BTO becomes unstable when n is equal to 3, as revealed by the occurrence of intergrowth. Similar phenomenon is observed in n-LaFeO3-doped BTO; the layered Aurivillius structure is totally collapsed in the case of n as high as 2.5. In contrast, 3-BiFeO3-doped BTO still keeps perfect Aurivillius structure. The above-observed structural stabilities of these materials are explained by the theoretical formation enthalpy calculated by the density functional theory. This work provides the necessary information to explore the multifunctionality based on Aurivillius n-ABO3–BTO oxides.

Type
Articles
Information
Journal of Materials Research , Volume 27 , Issue 23 , 14 December 2012 , pp. 2956 - 2964
Copyright
Copyright © Materials Research Society 2012

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Kimura, T. and Tokura, Y.: Layered magnetic manganites. Annu. Rev. Mater. Sci. 30, 451 (2000).CrossRefGoogle Scholar
Lee, J.S., Lee, Y.S., Noh, T.W., Nakatsuji, S., Fukazawa, H., Perry, R.S., Maeno, Y., Yoshida, Y., Ikeda, S.I., Yu, J., and Eom, C.B.: Bond-length dependence of charge-transfer excitations and stretch phonon modes in perovskite ruthenates: Evidence of strong p-d hybridization effects. Phys. Rev. B 70, 085103 (2004).CrossRefGoogle Scholar
Marechal, C., Defourneau, R.M., Rosenman, I., Perriere, J., and Simon, Ch.: Phase intergrowth effects on the magnetic and transport properties of Bi2Sr2CaCu2Oy thin films grown in situ by laser ablation. Phys. Rev. B 57, 13811 (1998).CrossRefGoogle Scholar
Rao, C.N.R. and Raveau, B.: Transition Metal Oxides: Structure, Properties, and Synthesis Of Ceramic Oxides, 2nd ed. (John Wiley & Sons, New York, NY, 1998); pp. 52, 74.Google Scholar
Tian, W., Pan, X.Q., Haeni, J., and Schlom, D.G.: Transmission-electron-microscopy study of n = 1-5 Srn+1TinO3n+1 epitaxial thin films. J. Mater. Res. 16, 2013 (2001).CrossRefGoogle Scholar
Zurbuchen, M.A., Tian, W., Pan, X.Q., Fong, D., Streiffer, S.K., Hawley, M.E., Lettieri, J., Jia, Y., Asayama, G., Fulk, S.J., Comstock, D.J., Knapp, S., Carim, A.H., and Schlom, D.G.: Morphology, structure, and nucleation of out-of-phase boundaries (OPBs) in epitaxial films of layered oxides. J. Mater. Res. 22, 1439 (2007).CrossRefGoogle Scholar
Parinov, I.A.: Microstructure and Properties of High-Temperature Superconductors (Springer-Verlag, Berlin Heidelberg, Germany, 2007); pp. 337–404.CrossRefGoogle Scholar
Subbanna, G.N., Guru Row, T.N., and Rao, C.N.R.: Structure and dielectric properties of recurrent intergrowth structures formed by the Aurivillius family of bismuth oxides of the formula Bi2An-1BnO3n+3. J. Solid State Chem. 86, 206 (1990).CrossRefGoogle Scholar
Van Tendeloo, G., Lebedev, O.I., Hervieu, M., and Raveau, B.: Structure and microstructure of colossal magnetoresistant materials. Rep. Prog. Phys. 67, 1315 (2004).CrossRefGoogle Scholar
Wen, J.G., Yang, C.Y., Yan, Y.F., and Fung, K.K.: Modulated structures and intergrowth in Pb-doped Bi-Sr-Ca-Cu-O superconducting oxides. Phys. Rev. B 42, 4117 (1990).CrossRefGoogle ScholarPubMed
Jardiel, T., Caballero, A.C., and Villegas, M.: Aurivillius ceramics: Bi4Ti3O12-based piezoelectrics. J. Ceram. Soc. Jpn. 116, 511 (2008).CrossRefGoogle Scholar
Kobayashi, T., Noguchi, Y., and Miyayama, M.: Enhanced spontaneous polarization in superlattice-structured Bi4Ti3O12-BaBi4Ti4O15 single crystals. Appl. Phys. Lett. 86, 012907 (2005).CrossRefGoogle Scholar
Mao, X.Y., Wang, W., Chen, X.B., and Lu, Y.L.: Multiferroic properties of layer-structured Bi5Fe0.5Co0.5Ti3O15 ceramics. Appl. Phys. Lett. 95, 082901 (2009).CrossRefGoogle Scholar
Suzuki, T., Nishi, Y., Fujimoto, M., Ishikawa, K., and Funakubo, H.: Interface and domain structures of (116)-oriented SrBi2Ta2O9 thin film epitaxially grown on (110) SrTiO3 single crystal. Jpn. J. Appl. Phys. 38, L1265 (1999).CrossRefGoogle Scholar
Gopalakrishnan, J., Ramanan, A., Rao, C.N.R., Jefferson, D.A., and Smith, D.J.: A homologous series of recurrent intergrowth structures of the type Bi4Am+n-2Bm+nO3(m+n)+6 formed by oxides of the Aurivillius family. J. Solid State Chem. 55, 101 (1984).CrossRefGoogle Scholar
Zurbuchen, M.A., Sherman, V.O., Tagantsev, A.K., Schubert, J., Hawley, M.E., Feng, D.D., Streiffer, S.K., Jia, Y., Tian, W., and Schlom, D.G.: Synthesis, structure and electrical behavior of Sr4Bi4Ti7O24. J. Appl. Phys. 107, 024106 (2010).CrossRefGoogle Scholar
Kresse, G. and Hafner, J.: Ab-initio molecular dynamics for open shell transition metals. Phys. Rev. B 48, 13115 (1993)CrossRefGoogle ScholarPubMed
Blöchl, P.E.: Projector augmented-wave method. Phys. Rev. B 50, 17953 (1994).CrossRefGoogle ScholarPubMed
Perdew, J.P., Burke, K., and Ernzerhof, M.: Generalized gradient approximation made simple. Phys. Rev. Lett. 77, 3865 (1996).CrossRefGoogle ScholarPubMed
Hervoches, C.H., Snedden, A., Riggs, R., Kilcoyne, S.H., Manuel, P., and Lightfoot, P.: Structural behavior of the four-layer Aurivillius-phase ferroelectrics SrBi4Ti4O15 and Bi5Ti3FeO15. J. Solid State Chem. 164, 280 (2002).CrossRefGoogle Scholar
Nakashima, S., Fujisawa, H., Ichikawa, S., Park, J.M., Kanashima, T., Okuyama, M., and Shimizu, M.: Structural and ferroelectric properties of epitaxial Bi5Ti3FeO15 and natural-superlattice-structured Bi4Ti3O12-Bi5Ti3FeO15 thin films. J. Appl. Phys. 108, 074106 (2010).CrossRefGoogle Scholar
Krzhizhanovskaya, M., Filatov, S., Gusarov, V., Paufler, P., Bubnova, R., Morozov, M., and Meyer, D.C.: Aurivillius phases in the Bi4Ti3O12/BiFeO3 system: Thermal behaviour and crystal structure. Z. Anorg. Allg. Chem. 631, 1603 (2005).CrossRefGoogle Scholar
Wu, F.X., Chen, Z., Chen, Y.B., Zhang, S.T., Zhou, J., Zhu, Y.Y., and Chen, Y.F.: Significant ferrimagnetism observed in Aurivillius Bi4Ti3O12 doped by antiferromagentic LaFeO3. Appl. Phys. Lett. 98, 212501 (2011).CrossRefGoogle Scholar
Zhou, J., Luo, Z.L., Chen, Y.B., Zhang, S.T., Gu, Z.B., Yao, S.H., and Chen, Y.F.: Microstructure and magnetic properties of a novel 10-H hexagonal perovskite nanosheet in a Bi-Fe-Cr-O system. RSC Adv. 2, 5683 (2012).CrossRefGoogle Scholar
Porter, D.A. and Easterling, K.E.: Phase Transitions in Metals and Alloys (Nelson Thornes Ltd., Cheltenham, UK, 2001); pp. 1–57.Google Scholar
Pirovano, C., Saiful Islam, M., Vannier, R., Nowogrocki, G., and Mairesse, G.: Modeling the crystal structures of Aurivillius phases. Solid State Ionics 140, 115 (2001).CrossRefGoogle Scholar