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A simple strategy for fabricating honeycomb patterns on commercially available polymer film under a wide humidity range

Published online by Cambridge University Press:  16 November 2020

Kai Huang ,
Qi Cheng ,
Honglei Zhang ,
Ligang Lin  and
Qiying Wang
Kai Huang
Affiliation:
State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Polytechnic University, Tianjin300387, P.R. China
Qi Cheng
Affiliation:
State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Polytechnic University, Tianjin300387, P.R. China
Honglei Zhang
Affiliation:
State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Polytechnic University, Tianjin300387, P.R. China
Ligang Lin*
Affiliation:
State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Polytechnic University, Tianjin300387, P.R. China
Qiying Wang
Affiliation:
State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Polytechnic University, Tianjin300387, P.R. China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

A simple and effective strategy is proposed for fabricating honeycomb-patterned ethyl cellulose (EC) films via a combination of the dip-coating and breath figure methods under a wide humidity range (40–90%). A mixture of toluene and methanol as a volatile solvent/nonsolvent pair was used to effectively control the surface morphology. Additionally, honeycomb patterns were successfully formed via dip-coating under a low humidity (relative humidity less than 40%), when water was directly added into the mixed solution. The important factors that influenced the morphology of EC honeycomb-patterned films were investigated, such as the humidity, solution concentration, and the withdrawal speed during dip-coating. The pore sizes could be controlled by changing the film-formation conditions. Water contact angle enables a transition from hydrophilic to hydrophobic. The possible mechanisms of honeycomb pattern formation are discussed. The fabrication of an ordered honeycomb-patterned film in a cost-effective and convenient manner will have broad application potential in the future.

Keywords

dip-coatingfilmhoneycomb patternethyl cellulosehumidity
Type
Article
Information
Journal of Materials Research , Volume 35 , Issue 23-24 , 14 December 2020 , pp. 3210 - 3221
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Copyright
Copyright © The Author(s), 2020, published on behalf of Materials Research Society by Cambridge University Press

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References

Shebi, A. and Lisa, S.: Pectin mediated synthesis of nano hydroxyapatite-decorated poly(lactic acid) honeycomb membranes for tissue engineering. Carbohydr. Polym. 201, 39–47 (2018).10.1016/j.carbpol.2018.08.012CrossRefGoogle ScholarPubMed
Li, B., Kan, L., Zhang, X.Y., Li, J., Li, R.T., Gui, Q.Y., Qiu, D.L., He, F., Ma, N., Wang, Y.P., and Wei, H.: Biomimetic bone-like hydroxyapatite by mineralization on supramolecular porous fiber networks. Langmuir 33, 8493–8502 (2017).10.1021/acs.langmuir.7b02394CrossRefGoogle ScholarPubMed
Zhou, W.D., Chen, Y., Roh, T., Lin, Y.N., Ling, S.J., Zhao, S.W., Lin, J.D., Khalil, N., Cairns, D.M., Manousiouthakis, E., Tse, M., and Kaplan, D.L.: Multifunctional bioreactor system for human intestine tissues. ACS Biomater. Sci. Eng. 4, 231–239 (2018).10.1021/acsbiomaterials.7b00794CrossRefGoogle ScholarPubMed
Zhang, L., Chen, L., Liu, S.X., Gong, J., Tang, Q., and Su, Z.M.: Honeycomb-patterned hybrid films of surfactant-encapsulated polyoxometalates by a breath figure method and its electrocatalysis for BrO3. Dalton Trans. 47, 105–111 (2017).10.1039/C7DT03201CCrossRefGoogle ScholarPubMed
Chen, H.Y., Liu, J.L., Xu, W.C., Wang, Z.F., Wang, C.Y., and Zhang, M.: Selective assembly of silver nanoparticles on honeycomb films and their surface-enhanced Raman scattering. Colloids Surf. A 506, 782–788 (2016).10.1016/j.colsurfa.2016.07.043CrossRefGoogle Scholar
Shin, B.K., Male, U., and Huh, D.S.: In-situ pore filling of TiO2 nanoparticles in honeycomb patterned porous films: A modified breath figure method. Polymer 135, 1–8 (2018).10.1016/j.polymer.2017.12.011CrossRefGoogle Scholar
Xu, C., Feng, R., Song, F., Wu, J-M., Luo, Y.Q., Wang, X.L., and Wang, Y.Z.: Continuous and controlled directional water transportation on a hydrophobic/superhydrophobic patterned surface. Chem. Eng. J. 352, 722–729 (2018).10.1016/j.cej.2018.07.073CrossRefGoogle Scholar
Wan, L.S., Li, J.W., Ke, B.B., and Xu, Z.K.: Ordered microporous membranes templated by breath figures for size-selective separation. J. Am. Chem. Soc. 134, 95–98 (2012).10.1021/ja2092745CrossRefGoogle ScholarPubMed
Dong, C. and Hao, J.: Honeycomb films with ordered patterns and structures .In Comprehensive Supramolecular Chemistry II, Atwood, Jerry L., ed. (Elsevier Ltd., Netherlands, 2017), pp. 207–229.10.1016/B978-0-12-409547-2.12641-1CrossRefGoogle Scholar
Bormashenko, E.: Breath-figure self-assembly, a versatile method of manufacturing membranes and porous structures: Physical, chemical and technological aspects. Membranes 7, 45 (2017).10.3390/membranes7030045CrossRefGoogle ScholarPubMed
Zhang, A.J., Bai, H., and Li, L.: Breath figure: A nature-inspired preparation method for ordered porous films. Chem. Rev. 115, 9801–9868 (2015).10.1021/acs.chemrev.5b00069CrossRefGoogle ScholarPubMed
Aynard, A., Pessoni, L., and Billon, L.: Directed self-assembly in “breath figure” templating of block copolymers followed by soft hydrolysis-condensation: One step towards synthetic bio-inspired silica diatoms exoskeleton. Polymer 210, 123047 (2020).10.1016/j.polymer.2020.123047CrossRefGoogle Scholar
Liu, Q., Wu, Y., and Li, Z.X.: Facile preparation of super-hydrophobic fabrics composed of fibres with microporous or microspherical coatings using the static breath figure method. Prog. Org. Coat. 149, 105938 (2020).10.1016/j.porgcoat.2020.105938CrossRefGoogle Scholar
Huang, C.X., Shen, X.T., Liu, X.J., Chen, Z.L., Shu, B.L., Wan, L.B., Liu, H.J., and He, J.: Hybrid breath figure method: A new insight in Petri dishes for cell culture. J. Colloid Interface Sci. 541, 114–122 (2019).10.1016/j.jcis.2019.01.074CrossRefGoogle ScholarPubMed
Hernández-Guerrero, M. and Stenzel, M.H.: Honeycomb structured polymer films via breath figures. Polym. Chem. 3, 563–577 (2012).10.1039/C1PY00219HCrossRefGoogle Scholar
Bai, H., Du, C., Zhang, A.J., and Li, L.: Breath figure arrays: Unconventional fabrications, functionalizations, and applications. Angew. Chem. Int. Ed. 52, 12240–12255 (2013).10.1002/anie.201303594CrossRefGoogle ScholarPubMed
Wan, L.S., Zhu, L.W., Ou, Y., and Xu, Z.K.: Multiple interfaces in self-assembled breath figures. Chem. Commun. 50, 4024–4039 (2014).10.1039/C3CC49826CCrossRefGoogle ScholarPubMed
Wu, W., Wang, X., Han, X., Yang, Z., Gao, G., Zhang, Y., Hu, J., Tan, Y., Pan, A., and Pan, C.: Flexible photodetector arrays based on patterned CH3NH3PbI3-xClx perovskite film for real-time photosensing and imaging. Adv. Mater. 31, 1805913 (2019).10.1002/adma.201805913CrossRefGoogle Scholar
Zhang, L., Chen, L., Liu, S-x., Gong, J., Tang, Q., and Su, Z-m.: Honeycomb-patterned hybrid films of surfactant-encapsulated polyoxometalates by a breath figure method and its electrocatalysis for BrO3. Dalton Trans. 47, 105–111 (2018).10.1039/C7DT03201CCrossRefGoogle Scholar
Kamei, J., Abe, H., and Yabu, H.: Biomimetic bubble-repellent tubes: Microdimple arrays enhance repellency of bubbles inside of tubes. Langmuir 33, 585–590 (2017).10.1021/acs.langmuir.6b04155CrossRefGoogle ScholarPubMed
Marcasuzaa, P., Save, M., Gérard, P., and Billon, L.: When a pH-triggered nanopatterned shape transition drives the wettability of a hierarchically self-organized film: A bio-inspired effect of “sea Anemone”. J. Colloid Interface. Sci. 581, 96–101 (2021).10.1016/j.jcis.2020.07.130CrossRefGoogle ScholarPubMed
Heng, L.P., Wang, B., Li, M.C., Zhang, Y.Q., and Jiang, L.: Advances in fabrication materials of honeycomb structure films by the breath-figure method. Materials 6, 460–482 (2013).10.3390/ma6020460CrossRefGoogle ScholarPubMed
Yin, S.Y., Goldovsky, Y.L., Herzberg, M., Liu, L., Sun, H., Zhang, Y.Y., Meng, F.B., Cao, X.B., Sun, D.D., Chen, H.Y., Kushmaro, A., and Chen, X.D.: Functional free-standing graphene honeycomb films. Adv. Funct. Mater. 23, 2972–2978 (2013).10.1002/adfm.201203491CrossRefGoogle Scholar
Ma, H.M., Cui, J.W., Song, A.X., and Hao, J.C.: Fabrication of freestanding honeycomb films with through-pore structures via air/water interfacial self-assembly. Chem. Commun. 47, 1154–1156 (2011).10.1039/C0CC02680HCrossRefGoogle ScholarPubMed
Park, M.S., Joo, W., and Kim, J.K.: Porous structures of polymer films prepared by spin coating with mixed solvents under humid condition. Langmuir 22, 4594–4598 (2006).10.1021/la053009tCrossRefGoogle ScholarPubMed
Bui, V.T., Thuy, L.T., Tran, Q.C., Nguyen, V.T., Dao, V.D., Choi, J.S., and Choi, H.S.: Ordered honeycomb biocompatible polymer films via a one-step solution-immersion phase separation used as a scaffold for cell cultures. Chem. Eng. J. 320, 561–569 (2017).10.1016/j.cej.2017.03.086CrossRefGoogle Scholar
Park, M.S. and Kim, J.K.: Breath figure patterns prepared by spin coating in a dry environment. Langmuir 20, 5347–5352 (2004).10.1021/la035915gCrossRefGoogle Scholar
Bormashenko, E., Malkin, A., Musin, A., Bormashenko, Y., Whyman, G., Litvak, N., Barkay, Z., and Machavariani, V.: Mesoscopic patterning in evaporated polymer solutions: Poly(ethylene glycol) and room-temperature-vulcanized polyorganosilanes/-siloxanes promote formation of honeycomb structures. Macromol. Chem. Phys. 209, 873–873 (2008).10.1002/macp.200800134CrossRefGoogle Scholar
Bormashenko, E., Balter, S., Pogreb, R., and Aurbach, D.: Single-step technique allowing formation of microscaled thermally stable polymer honeycomb reliefs demonstrating reversible wettability. Polym. Adv. Technol. 22, 94–98 (2011).10.1002/pat.1698CrossRefGoogle Scholar
Mansouri, J., Yapit, E., and Chen, V.: Polysulfone filtration membranes with isoporous structures prepared by a combination of dip-coating and breath figure approach. J. Membr. Sci. 444, 237–251 (2013).10.1016/j.memsci.2013.05.022CrossRefGoogle Scholar
Srinivasarao, M., Collings, D., Philips, A., and Patel, S.: Three-dimensionally ordered array of air bubbles in a polymer film. Science 292, 79–83 (2001).10.1126/science.1057887CrossRefGoogle Scholar
Peng, J., Han, Y.C., Yang, Y.M., and Li, B.Y.: The influencing factors on the macroporous formation in polymer films by water droplet templating. Polymer 45, 447–452 (2004).10.1016/j.polymer.2003.11.019CrossRefGoogle Scholar
Brinker, C.J., Frye, G.C., Hurd, A.J., and Ashley, C.S.: Fundamentals of sol-gel film dip-coating. Thin Solid Films 201, 97–108 (1991).10.1016/0040-6090(91)90158-TCrossRefGoogle Scholar
Yang, C.C., Josefowicz, J.Y., and Alexandru, L.: Deposition of ultrathin films by a withdrawal method. Thin Solid Films 74, 117–127 (1980).10.1016/0040-6090(80)90446-0CrossRefGoogle Scholar
Cassie, A.B.D. and Baxter, S.: Wettability of porous surfaces. Trans. Faraday Soc. 40, 546–551 (1944).10.1039/tf9444000546CrossRefGoogle Scholar
Dong, R.H., Yan, J.L., Ma, H.M., Fang, Y., and Hao, J.C.: Dimensional architecture of ferrocenyl-based oligomer honeycomb-patterned films: From monolayer to multilayer. Langmuir 27, 9052–9056 (2011).10.1021/la201264uCrossRefGoogle ScholarPubMed
Girard, F., Antoni, M., Faure, S., and Steinchen, A.: Evaporation and Marangoni driven convection in small heated water droplets. Langmuir 22, 11085–11091 (2006).10.1021/la061572lCrossRefGoogle ScholarPubMed
Tsoumpas, Y., Dehaeck, S., Rednikov, A., and Colinet, P.: Effect of Marangoni flows on the shape of thin sessile droplets evaporating into air. Langmuir 31, 13334–13340 (2015).10.1021/acs.langmuir.5b02673CrossRefGoogle ScholarPubMed
De Dier, R., Sempels, W., Hofkens, J., and Vermant, J.: Thermocapillary fingering in surfactant-laden water droplets. Langmuir 30, 13338–13344 (2014).CrossRefGoogle ScholarPubMed
Jiang, L.W., Wang, R., Yang, B.X., Li, T.J., Tryk, D.A., Fujishima, A., Hashimoto, K., and Zhu, D.B.: Binary cooperative complementary nanoscale interfacial materials. Pure Appl. Chem. 72, 73–81 (2000).10.1351/pac200072010073CrossRefGoogle Scholar
Fang, R.C., Liu, M.J., Liu, H.L., and Jiang, L.: Bioinspired interfacial materials: From binary cooperative complementary interfaces to superwettability systems. Adv. Mater. Interfaces 5, 1701176 (2018).10.1002/admi.201701176CrossRefGoogle Scholar
Feng, L., Li, S., Li, Y., Li, H., Zhang, L., Zhai, J., Song, Y., Liu, B., Jiang, L., and Zhu, D.: Super-hydrophobic surfaces: From natural to artificial. Adv. Mater. 14, 1857–1860 (2002).10.1002/adma.200290020CrossRefGoogle Scholar
Wang, D.M. and Lai, J.Y.: Recent advances in preparation and morphology control of polymeric membranes formed by nonsolvent induced phase separation. Curr. Opin. Chem. Eng. 2, 229–237 (2013).CrossRefGoogle Scholar
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