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Shaping different carbon nano- and submicro-structures by alcohol chemical vapor deposition

Published online by Cambridge University Press:  03 March 2011

Z.G. Zhao ,
S. Bai ,
Z. Ying ,
Jin-Bo Bai  and
H.M. Cheng
Z.G. Zhao
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, People’s Republic China; and Laboratory of Mechanics of Soils, Structures and Materials, Centre National de la Recherche Scientifique UMR 8579, Ecole Central Paris, 92295 Chatenay-Malabry, France
S. Bai
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, People’s Republic China
Z. Ying
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, People’s Republic China
Jin-Bo Bai
Affiliation:
Laboratory of Mechanics of Soils, Structures and Materials, Centre National de la Recherche Scientifique UMR 8579, Ecole Central Paris, 92295 Chatenay-Malabry, France
H.M. Cheng*
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, People’s Republic of China
*
a) Address all correspondence to this author. e-mail: [email protected]
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Abstract

A variety of carbon nano- and submicro-structures with spectacular morphologies such as spaghetti-like, dendritic, and segmented carbon fibers; carbon pillars; and single-walled carbon nanotubes (SWNTs) was selectively synthesized by the alcohol chemical vapor deposition (CVD) method. The phase structure and morphologies were investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM), selected-area electron diffraction (SAED), and Raman spectroscopy. The carbon structures could be controlled by adjusting the deposition position and the growth temperature. The formation mechanism of these carbon structures was discussed on the basis of the experimental results. The various CVD products obviously imply that the growth mechanism for our alcohol CVD process evolves from catalytic growth mode to pyrolytic carbon deposition mode. The obtained various carbon nano- and submicro-structures may be promising for applications in functional nanodevices.

Keywords

Chemical vapor deposition (CVD)Morphology
Type
Articles
Information
Journal of Materials Research , Volume 21 , Issue 10 , October 2006 , pp. 2504 - 2509
Copyright
Copyright © Materials Research Society 2006

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References

REFERENCES

1.Kroto, H.W., Heath, J.R., Brien, S.C.O., Curl, R.F., Smalley, R.E.: C60-buckminsterfullerene. Nature 318, 162 (1985).CrossRefGoogle Scholar
2.Iijima, S.: Helical microtubules of graphitic carbon. Nature 354, 56 (1991).CrossRefGoogle Scholar
3.Iijima, S., Lchihashi, T.: Single-shell carbon nanotubes of 1-nm diameter. Nature 363, 603 (1993).CrossRefGoogle Scholar
4.Ugarte, D.: Curling and closure of graphitic networks under electronbeam irradiation. Nature 359, 707 (1992).CrossRefGoogle ScholarPubMed
5.Krishnan, A., Dujardin, E., Treacy, M.M.J., Hugdahl, J., Lynum, S., Ebbesen, T.W.: Graphitic cones and the nucleation of curved carbon surfaces. Nature 388, 451 (1997).CrossRefGoogle Scholar
6.Iijima, S., Yudasaka, M., Yamada, R., Bandow, S., Suenaga, K., Kokai, F., Takahashi, K.: Nano-aggregates of single-walled graphitic carbon nano-horns. Chem. Phys. Lett. 309, 165 (1999).CrossRefGoogle Scholar
7.Shimizu, Y., Sasaki, T., Kodaira, T., Kawaguchi, K., Tersaima, K., Koshizaki, N.: Fabrication of carbon nanotubes assemblies on Ni-Mo substrates mimics law of natural forest growth. Chem. Phys. Lett. 370, 774 (2003).CrossRefGoogle Scholar
8.Ajayan, P.M.: Nanotechnology—How does a nanofibre grow. Nature 427, 402 (2004).CrossRefGoogle ScholarPubMed
9.Maruyama, S., Kojima, R., Miyauchi, S., Chiashi, S., Kohno, M.: Low-temperature synthesis of high-purity single-walled carbon nanotubes from alcohol. Chem. Phys. Lett. 360, 229 (2002).CrossRefGoogle Scholar
10.Zhao, Z.G., Ci, L.J., Cheng, H.M., Bai, J.B.: The growth of multi-walled carbon nanotubes with different morphologies on carbon fibers. Carbon 43, 651 (2005).CrossRefGoogle Scholar
11.Ci, L.J., Zhao, Z.G., Bai, J.B.: Direct growth of carbon nanotubes on the surface of ceramic fibers. Carbon 43, 883 (2005).CrossRefGoogle Scholar
12.Singh, C., Shaffer, M.S.P., Windle, A.H.: Production of controlled architectures of aligned carbon nanotubes by an injection chemical vapour deposition method. Carbon 41, 359 (2003).CrossRefGoogle Scholar
13.May, S.J., Zheng, J.G.P., Wessels, B.W., Lauhon, L.J.: Dendritic nanowire growth mediated by a self-assembled catalyst. Adv. Mater. 17, 598 (2005).CrossRefGoogle Scholar
14.Ye, C.H., Zhang, L., Fang, X.S., Wang, Y.H., Yan, P., Zhao, J.W.: Hierarchical structure: Silicon nanowires standing on silica microwires. Adv. Mater. 16, 1019 (2004).CrossRefGoogle Scholar
15.Allouche, H., Monthioux, M.: Chemical vapor deposition of pyrolytic carbon on carbon nanotubes. Part 2. Texture and structure. Carbon 43, 1265 (2005).CrossRefGoogle Scholar
16.Heer, W.A., Poncharal, P., Berger, C., Gezo, J., Song, Z.M., Bettini, J., Ugarte, D.: Liquid carbon, carbon-glass beads, and the crystallization of carbon nanotubes. Science 307, 907 (2005).CrossRefGoogle ScholarPubMed
17.Ren, Z.F., Huang, Z.P., Xu, J.W., Wang, J.H., Bush, P., Siegal, M.P., Provencio, P.N.: Synthesis of large arrays of well-aligned carbon nanotubes on glass. Science 282, 1105 (1998).CrossRefGoogle Scholar
18.Singh, C., Quested, T., Boothroyd, C.B., Thomas, P., Kinloch, I.A., Kandil, A.I.A., Windle, A.H.: Synthesis and characterization of carbon nanofibers produced by the floating catalyst method. J. Phys. Chem. B 106, 10915 (2002).CrossRefGoogle Scholar