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Self-formed pencil-like bulk composite materials consisting of copper alloy and stainless steel

Published online by Cambridge University Press:  31 January 2011

C.P. Wang ,
X.J. Liu ,
I. Ohnuma ,
R. Kainuma  and
K. Ishida
C.P. Wang
Affiliation:
Department of Materials Science and Engineering, College of Materials, and Research Center for Materials Design and Applications, Xiamen University, Xiamen 361005, People’s Republic of China
X.J. Liu*
Affiliation:
Department of Materials Science and Engineering, College of Materials, and Research Center for Materials Design and Applications, Xiamen University, Xiamen 361005, People’s Republic of China
I. Ohnuma
Affiliation:
Department of Materials Science, Graduate School of Engineering, Tohoku University, Sendai, 980-8579, Japan
R. Kainuma
Affiliation:
Department of Materials Science, Graduate School of Engineering, Tohoku University, Sendai, 980-8579, Japan
K. Ishida
Affiliation:
Department of Materials Science, Graduate School of Engineering, Tohoku University, Sendai, 980-8579, Japan
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

On the basis of the CALPHAD (Calculation of Phase Diagrams) method, the compositional range of stable miscibility gap and volume fractions of the two liquid phases in the Cu–Fe–Cr–Ni system were predicted, which can provide the guidance for design of self-formed composite materials. Based on such information, the self-formed pencil-like bulk composite materials consisting of copper alloy and two kinds of stainless steels were prepared by controlling the compositions of Cu-rich and Fe-rich phases in immiscible liquid system by the conventional casting process. The experimental results are in good agreement with the ones predicted by calculation. This study indicates that it is possible to develop the pencil-like bulk composite materials consisting of copper alloy and stainless steels by the conventional casting process.

Keywords

CompositeMetalPhase equilibria
Type
Articles
Information
Journal of Materials Research , Volume 23 , Issue 4 , April 2008 , pp. 933 - 940
Copyright
Copyright © Materials Research Society 2008

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References

REFERENCES

1Livne, Z.Munitz, A.: Characterization of explosively bonded iron and copper plates. J. Mater. Sci. 22, 1495 1987CrossRefGoogle Scholar
2Hermas, A.A., Ogura, K.Adachi, T.: Accumulation of copper layer on a surface in the anodic polarization of stainless-steel containing Cu at different temperatures. Electrochim. Acta 40(7), 837 1995CrossRefGoogle Scholar
3Van Cleemput, M., Jones, H., Van Der Burgt, M., Barrau, J-R., Lee, J.A., Eyssa, Y.Schneider-Muntau, H-J.: Copper/stainless steel conductor for high field pulsed magnets. Phys. B (Amsterdam) 216, 226 1996CrossRefGoogle Scholar
4Grünberger, W., Heilmaier, M.Schultz, L.: High-strength, high-nitrogen stainless steel—copper composite wires for conductors in pulsed high-field magnets. Mater. Lett. 52, 154 2002CrossRefGoogle Scholar
5Santella, M.L.Patterson, A.B.: Wetting of iron aluminide alloys by Ag, Au, and Cu. Mater. Sci. Eng., A 258, 270 1998CrossRefGoogle Scholar
6Wang, C.P., Liu, X.J., Ohnuma, I., Kainuma, R.Ishida, K.: Formation of immiscible alloy powders with egg-type microstructure. Science 297, 990 2002CrossRefGoogle ScholarPubMed
7Wang, C.P., Liu, X.J., Ohnuma, I., Kainuma, R.Ishida, K.: Formation of core-type macroscopic morphology in Cu–Fe base alloy with liquid miscibility gap. Metall. Mater. Trans. A 35, 1243 2004CrossRefGoogle Scholar
8Marangoni, C.: Study on surface tension of fluid. Ann. Phys. Chem. 143, 337 1871CrossRefGoogle Scholar
9Lukas, H., Fries, S.G.Sundman, B.: Computational Thermodynamics Cambridge University Press Cambridge, UK 2007CrossRefGoogle Scholar
10Liu, X.J., Ohnuma, I., Wang, C.P., Jiang, M., Kainuma, R.Ishida, K.: Thermodynamic database on microsolders and copper-based alloy systems. J. Electron. Mater. 32, 1265 2003CrossRefGoogle Scholar
11Wang, C.P., Liu, X.J., Jiang, M., Ohnuma, I., Kainuma, R.Ishida, K.: Thermodynamic database of the phase diagram in copper base alloy system. J. Phys. Chem. Solids 66, 256 2005CrossRefGoogle Scholar
12Redlich, O.Kister, A.T.: Algebraic representation of thermodynamic properties and the classification of solutions. Ind. Eng. Chem. 40, 354 1948CrossRefGoogle Scholar
13Dinsdale, A.T.: SGTE data for pure elements. Calphad 15, 317 1991CrossRefGoogle Scholar
14Hillert, M.Jarl, M.: A model for alloying effects in ferromagnetic metals. Calphad 2, 227 1978CrossRefGoogle Scholar
15Smithells, C.J.Brandes, E.A.Metals Reference Book, 5th ed.Butterworths London & Boston 1976 940–950Google Scholar
16Young, N.O., Goldstein, J.S.Block, M.J.: The motion of bubbles in a vertical temperature gradient. J. Fluid Mech. 6, 350 1959CrossRefGoogle Scholar
17Prinz, B., Romero, A.Ratke, L.: Casting process for hypermonotectic alloys under terrestrial conditions. J. Mater. Sci. 30, 4715 1995CrossRefGoogle Scholar
18Mills, K.C., Monaghan, B.J.Keene, B.J.: Thermal conductivities of molten metals. Int. Mater. Rev. 41(6), 209 1996CrossRefGoogle Scholar
19Cverna, F.: Thermal Properties of Metals ASM International Materials Park, OH 2002 337–342Google Scholar
20Ratke, L.Voorhees, P.W.: Growth and Coarsening Springer-Verlag New York 2002 239–249CrossRefGoogle Scholar
21Becker, R.: The germ formation with the elimination in metallic mixed crystals. Ann. Phys. (Leipzig) 32, 128 1938CrossRefGoogle Scholar
22Nishizawa, T., Ohnuma, I.Ishida, K.: Correlation between interfacial energy and phase diagram in ceramic system. J. Phase Equilib. 22, 269 2001CrossRefGoogle Scholar
23Iida, T.Guthrie, R.I.L.: Physical Properties of Liquid Metals Clarendon Press Oxford 1988Google Scholar
24Howe, J.M.: Interfaces in Materials John Wiley & Sons Inc. 1997 47–60Google Scholar
25Seetharaman, S.Du, S.: Estimation of viscosities of binary metallic melts using Gibbs energy of mixing. Metall. Mater. Trans. B 25, 589 1994CrossRefGoogle Scholar