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Role of hierarchical morphology of helical carbon nanotube bundles on thermal expansion of polymer nanocomposites

Published online by Cambridge University Press:  19 June 2017

Oleksandr G. Kravchenko Open the ORCID record for Oleksandr G. Kravchenko [Opens in a new window] ,
Xin Qian ,
Sergii G. Kravchenko ,
Rocio Misiego ,
R. Byron Pipes  and
Ica Manas-Zloczower
Oleksandr G. Kravchenko*
Affiliation:
Department of Macromolecular Science and Engineering, Case School of Engineering, Case Western Reserve University, Cleveland, Ohio 44106-7202, USA
Xin Qian
Affiliation:
Department of Macromolecular Science and Engineering, Case School of Engineering, Case Western Reserve University, Cleveland, Ohio 44106-7202, USA
Sergii G. Kravchenko
Affiliation:
School of Aeronautics and Astronautics, Purdue University, Indiana Manufacturing Institute, West Lafayette, Indiana 47906-1168, USA
Rocio Misiego
Affiliation:
SABIC, Murcia 30390, Spain
R. Byron Pipes
Affiliation:
School of Aeronautics and Astronautics, Materials Engineering and Chemical Engineering, Purdue University, Indiana Manufacturing Institute, West Lafayette, Indiana 47906-1168, USA
Ica Manas-Zloczower
Affiliation:
Department of Macromolecular Science and Engineering, Case School of Engineering, Case Western Reserve University, Cleveland, Ohio 44106-7202, USA
*
a) Address all correspondence to this author. e-mail: [email protected]
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Abstract

The thermal expansion behavior of polymer carbon nanotube (CNT) nanocomposites was investigated, and a micromechanical model was proposed to explain the highly nonlinear dependence of the coefficient of thermal expansion of the nanocomposite with CNT content for the CNT/polyimide nanocomposite. The microscopic analysis of CNT/polyimide matrix showed homogeneous dispersion of bundles composed of CNTs. Therefore, the proposed model to predict the thermal expansion behavior of the nanocomposite considered a random, homogeneous distribution of CNT bundles with a hierarchical arrangement of helical CNTs within the polymeric matrix. The CNT bundle morphology influenced the thermal expansion response of the nanocomposite through (i) bundle volume fraction and (ii) degree of helicity, affecting thermo-mechanical properties of the bundle. The effective, homogenized, properties of CNT bundles were determined by the elasticity based solution of the layered cylinder model. Bundle effective properties were used in the micromechanical model implementing the homogenized strain rule of the mixture expression to predict the thermal expansion behavior of nanocomposite in a wide range of CNT volume contents. The proposed micromechanical analytical model was found to correlate closely with the experimental results for polyimide/CNT nanocomposite films as measured using a digital image correlation method.

Keywords

polymercompositemicrostructure
Type
Articles
Information
Journal of Materials Research , Volume 32 , Issue 14 , 28 July 2017 , pp. 2738 - 2746
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Copyright
Copyright © Materials Research Society 2017 

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Footnotes

Contributing Editor: Linda S. Schadler

References

REFERENCES

Qian, H., Greenhalgh, E.S., Shaffer, M.S.P., and Bismarck, A.: Carbon nanotube-based hierarchical composites: A review. J. Mater. Chem. 20, 4751–4762 (2010).Google Scholar
Kravchenko, O.G., Misiego, R., Qian, X., Kravchenko, S.G., Pips, R.B., and Manas-Zloczower, I.: Relation between morphology and thermo-elastic properties of carbon nanotube polymer/carbon fiber hybrid composites. In Proc. Am. Soc. Compos. Tech. Conf., 31st (American Society for Composites, Williamsburg, 2016).Google Scholar
Wang, S., Liang, Z., Gonnet, P., Liao, Y-H., Wang, B., and Zhang, C.: Effect of nanotube functionalization on the coefficient of thermal expansion of nanocomposites. Adv. Funct. Mater. 17, 87–92 (2007).CrossRefGoogle Scholar
Jiang, X., Bin, Y., and Matsuo, M.: Electrical and mechanical properties of polyimide–carbon nanotubes composites fabricated by in situ polymerization. Polymer 46, 7418–7424 (2005).CrossRefGoogle Scholar
Hou, T.H., Johnston, N.J., and Clair, T.L.S.: IM7/LARCTM-IA polyimide composites. High Perform. Polym. 7, 105–124 (1995).Google Scholar
Misiego, C.R. and Pipes, R.B.: Dispersion and its relation to carbon nanotube concentration in polyimide nanocomposites. Compos. Sci. Technol. 85, 43–49 (2013).CrossRefGoogle Scholar
Ogasawara, T., Ishida, Y., Ishikawa, T., and Yokota, R.: Characterization of multi-walled carbon nanotube/phenylethynyl terminated polyimide composites. Composites, Part A 35, 67–74 (2004).CrossRefGoogle Scholar
Paiva, M.C., Zhou, B., Fernando, K.A.S., Lin, Y., Kennedy, J.M., and Sun, Y-P.: Mechanical and morphological characterization of polymer–carbon nanocomposites from functionalized carbon nanotubes. Carbon 42, 2849–2854 (2004).CrossRefGoogle Scholar
Guo, H., Sreekumar, T.V., Liu, T., Minus, M., and Kumar, S.: Structure and properties of polyacrylonitrile/single wall carbon nanotube composite films. Polymer 46, 3001–3005 (2005).CrossRefGoogle Scholar
Fisher, F.T., Bradshaw, R.D., and Brinson, L.C.: Effects of nanotube waviness on the modulus of nanotube-reinforced polymers. Appl. Phys. Lett. 80, 4647–4649 (2002).Google Scholar
Pipes, R.B. and Hubert, P.: Helical carbon nanotube arrays: Mechanical properties. Compos. Sci. Technol. 62, 419–428 (2002).CrossRefGoogle Scholar
Shi, D-L., Feng, X-Q., Huang, Y.Y., Hwang, K-C., and Gao, H.: The effect of nanotube waviness and agglomeration on the elastic property of carbon nanotube-reinforced composites. J. Eng. Mater. Technol. 126, 250–257 (2004).CrossRefGoogle Scholar
Misiego Arpa, C.R.: Carbon nanotube dispersion and characteristics: Thermomechanical properties and conductivity of polyimide nanocomposites. PhD dissertation, Purdue University, West Lafeyette (2012).Google Scholar
Kravchenko, O.G., Misiego, C.R., Kravchenko, S.G., Pipes, R.B., and Manas-Zloczower, I.: Modeling of hierarchical morphology of carbon nanotube bundles in polymer composites. Macromol. Theory Simul. 26, 524–532 (2016).CrossRefGoogle Scholar
Kravchenko, O.G., Kravchenko, S.G., Casares, A., and Pipes, R.B.: Digital image correlation measurement of resin chemical and thermal shrinkage after gelation. J. Mater. Sci. 50, 5244–5252 (2015).CrossRefGoogle Scholar
Park, C., Ounaies, Z., Watson, K.A., Crooks, R.E., Smith, J. Jr., Lowther, S.E., Connell, J.W., Siochi, E.J., Harrison, J.S., and Clair, T.L.S.: Dispersion of single wall carbon nanotubes by in situ polymerization under sonication. Chem. Phys. Lett. 364, 303–308 (2002).Google Scholar
Eberl, C., Gianola, D., and Bundschuh, S.: Digital image correlation and tracking. http://www.mathworks.com/matlabcentral/fileexchange/12413-digital-imagecorrelation-and-tracking (2010).Google Scholar
Kravchenko, O.G., Li, C., Strachan, A., Kravchenko, S.G., and Pipes, R.B.: Prediction of the chemical and thermal shrinkage in a thermoset polymer. Composites, Part A 66, 35–43 (2014).CrossRefGoogle Scholar
Agius, S.L., Joosten, M., Trippit, B., Wang, C.H., and Hilditch, T.: Rapidly cured epoxy/anhydride composites: Effect of residual stress on laminate shear strength. Composites, Part A 90, 125–136 (2016).Google Scholar
Zhao, L.G., Warrior, N.A., and Long, A.C.: A micromechanical study of residual stress and its effect on transverse failure in polymer–matrix composites. Int. J. Solids Struct. 43, 5449–5467 (2006).Google Scholar
Mo, T-C., Wang, H-W., Chen, S-Y., and Yeh, Y-C.: Synthesis and characterization of polyimide/multi-walled carbon nanotube nanocomposites. Polym. Compos. 29, 451–457 (2008).Google Scholar
Siochi, E.J., Working, D.C., Park, C., Lillehei, P.T., Rouse, J.H., Topping, C.C., Bhattacharyya, A.R., and Kumar, S.: Melt processing of SWCNT-polyimide nanocomposite fibers. Composites, Part B 35, 439–446 (2004).Google Scholar
Yuen, S-M., Ma, C-C.M., Chiang, C-L., Lin, Y-Y., and Teng, C-C.: Preparation and morphological, electrical, and mechanical properties of polyimide-grafted MWCNT/polyimide composite. J. Polym. Sci., Part A: Polym. Chem. 45, 3349–3358 (2007).Google Scholar
E37 Committee: Test method for assignment of the glass transition temperatures by differential scanning calorimetry. J. ASTM Int. ASTM E1356-08, 2014 (1900).Google Scholar
Schapery, R.A.: Thermal expansion coefficients of composite materials based on energy principles. J. Compos. Mater. 2, 380–404 (1968).CrossRefGoogle Scholar
Yosida, Y.: High-temperature shrinkage of single-walled carbon nanotube bundles up to 1600 K. J. Appl. Phys. 87, 3338–3341 (2000).CrossRefGoogle Scholar
Ruoff, R.S. and Lorents, D.C.: Mechanical and thermal properties of carbon nanotubes. Carbon 33, 925–930 (1995).Google Scholar
Nan, C-W., Shen, Y., and Ma, J.: Physical properties of composites near percolation. Annu. Rev. Mater. Res. 40, 131–151 (2010).Google Scholar
Pipes, R.B. and Hubert, P.: Helical carbon nanotube arrays: Thermal expansion. Compos. Sci. Technol. 63, 1571–1579 (2003).Google Scholar
Tsai, S.W., Halpin, J.C., and Pagano, N.J.: Composite Materials Workshop (1968).Google Scholar
Hashin, Z.: Analysis of composite materials—A survey. J. Appl. Mech. 50, 481–505 (1983).CrossRefGoogle Scholar