Hostname: page-component-78c5997874-fbnjt Total loading time: 0 Render date: 2024-11-08T06:31:09.706Z Has data issue: false hasContentIssue false
  • English
  • Français

Reaction-assisted shock consolidation of RSR Ti–Al alloys

Published online by Cambridge University Press:  31 January 2011

L. H. Yu ,
M. A. Meyers  and
N. N. Thadhani
L. H. Yu
Affiliation:
Department of Materials and Metallurgical Engineering and Center for Explosives Technology Research, New Mexico Institute of Mining and Technology, Socorro, New Mexico 87801
M. A. Meyers
Affiliation:
Center of Excellence for Advanced Materials, University of California at San Diego, La Jolia, California 92053
N. N. Thadhani
Affiliation:
Center for Explosives Technology Research, New Mexico Institute of Mining and Technology, Socorro, New Mexico 87801
Get access

Abstract

A new method for the shock consolidation of hard metallic powders has been successfully tested. This method extends the process developed by Sawaoka and Akashi for the processing of ceramics (U.S. Patent 4,655,830) to metallic powders. Shock-activated reactions between elemental mixtures of niobium and aluminum powders were used to chemically induce bonding between difficult-to-consolidate intermetallic TiAl compound powder particles. The highly exothermic reactions activated by the passage of shock waves form an intermetallic binder phase which assists in the consolidation of the very hard TiAl alloy powders. Shock impact experiments were carried out utilizing a twelve-capsule shock recovery system in which a plane wave generating lens is used for accelerating a flyer plate to velocities of 1.7 and 2.3 km/s. With these impact velocities, sufficient shock pressures are generated in the powders, contained in capsules, to result in shock-induced reactions between the elemental powders of the mix. Fully dense compacts were successfully recovered and were subsequently characterized by optical, transmission, and scanning electron microscopy, x-ray diffraction, and microhardness testing. Transmission electron microscopy revealed both microcrystalline and amorphous regions in the reaction zone. In one instance, the amorphous material crystallized under the heating effect of the electron beam. Shock induced reaction between elemental powders and with the TiAl powders, producing ternary compounds, was also observed.

Type
Articles
Information
Journal of Materials Research , Volume 5 , Issue 2 , February 1990 , pp. 302 - 312
Copyright
Copyright © Materials Research Society 1990

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Lipsitt, H.A., Shechtman, D., and Schafrik, R. E., Metall. Trans. A 6A, 1991(1975).CrossRefGoogle Scholar
2Shechtman, D., Blackburn, M. J., and Lipsitt, H. A., Metall. Trans. 5, 1373 (1974).Google Scholar
3Graham, R. A., in Shock Waves in Condensed Matter, edited by Gupta, Y. M. (Plenum, New York, 1986).Google Scholar
4Larocca, E.W. and Pearson, J., Rev. Sci. Instrum. 29, 848 (1985).Google Scholar
5DeCarli, P. S. and Jamieson, J. C., Science, 821 (1961).Google Scholar
6DeCarli, P.S., “Method of Making Diamond,” U.S. Patent 3,238,019 (1966).Google Scholar
7Sawaoka, A.B. and Akashi, T., “High Density Compacts,” U.S. Patent 4,655,830 (1987).Google Scholar
8Murr, L.E. and Grace, F.I., Expl. Mech. 5, 145 (1969).Google Scholar
9DeCarli, P. S. and Meyers, M. A., in Shock Waves and High-Strain-Rate Phenomena in Metals, edited by Meyers, M. A. and Murr, L. E. (Plenum, New York, 1981), p. 341.CrossRefGoogle Scholar
10Akashi, T. and Sawaoka, A., Mater. Lett. 3, 11 (1984).Google Scholar
11Norwood, F. R., Graham, R. A., and Sawaoka, A., in Shock Waves in Condensed Matter, edited by Gupta, Y. M. (Plenum, New York, 1986), p. 837.CrossRefGoogle Scholar
12Bull. Alloy Phase Diagrams, Elliot, R. P. and Shunk, F.A., contributing editors, 2 (1), (June 1981).Google Scholar
13Vreeland, T., Kasiraj, P., Mutz, A. H., and Thadhani, N. N., in Metallurgical Applications of Shock-Wave and High-Strain-Rate Phenomena, edited by Murr, L. E., Staudhammer, K. P., and Meyers, M. A. (Dekker, M., 1986), p. 231.Google Scholar
14Thadhani, N. N., Vreeland, T., and Ahrens, T. J., J. of Mater. Sci. 22, 4446 (1987).Google Scholar
15Meyers, M. A., Gupta, B. B., and Murr, L. E., J. of Metals, No. 22, 21 (1981).Google Scholar
16Wang, S. L. and Meyers, M. A., J. Mater. Sci. (1988) (in press).Google Scholar
17Gourdin, W. H., Prog. Mater. Sci. 30, 39 (1986).CrossRefGoogle Scholar
18Schwarz, R. B., Kasiraj, P., Vreeland, T., and Ahrens, T. J., Acta Metall. 32, 1243 (1984).CrossRefGoogle Scholar