Hostname: page-component-586b7cd67f-gb8f7 Total loading time: 0 Render date: 2024-11-24T18:59:07.402Z Has data issue: false hasContentIssue false
  • English
  • Français

Pronounced enhancement of glass-forming ability of Fe–Si–B–P bulk metallic glass in oxygen atmosphere

Published online by Cambridge University Press:  13 May 2014

Chuntao Chang ,
Jianhua Zhang ,
Baolong Shen ,
Weihua Wang  and
Akihisa Inoue
Chuntao Chang*
Affiliation:
Zhejiang Province Key Laboratory of Magnetic Materials and Application Technology, Key Laboratory of Magnetic Materials and Devices, Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, Zhenhai District, Ningbo, Zhejiang 315201, China
Jianhua Zhang*
Affiliation:
College of Electrical and Power Engineering, Shanxi Key Laboratory of Coal Mining Equipment and Safety Control, Taiyuan University of Technology, Wanbolin District, Taiyuan, Shanxi 030024, China
Baolong Shen
Affiliation:
School of Materials Science and Engineering, Southeast University, Jiangning District, Nanjing 211189, China
Weihua Wang
Affiliation:
Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
Akihisa Inoue
Affiliation:
Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, Zhenhai District, Ningbo, Zhejiang 315201, China
*
a)Address all correspondence to these authors. e-mail: [email protected]
b)e-mail: [email protected]
Get access

Abstract

It is widely accepted that oxygen will severely deteriorate the glass-forming ability (GFA) of an alloy. In this work, we report that the GFA of a Fe76Si9B10P5 glassy alloy can be significantly improved (the critical diameter for fully glass formation is increased from 1 to 3 mm) under oxygen casting atmosphere. Furthermore, the pressure of oxygen atmosphere gives an obvious enhancement in the critical diameter of Fe76Si9B10P5 glassy alloy. A dependence of GFA on casting atmosphere species (argon, nitrogen, air, and oxygen) is also observed for this glassy alloy, and its critical diameter is 1, 1.5, 2.5, and 3 mm, respectively. In addition, the Fe-based glassy alloy exhibits excellent soft magnetic properties regardless of the applied casting atmosphere. The mechanism for such an unusual oxygen effect on the GFA of Fe76Si9B10P5 glassy alloy is attributed to the reduced nucleation rate caused by the enhancement of surface tension of the alloy melt.

Keywords

Feamorphousalloy
Type
Articles
Information
Journal of Materials Research , Volume 29 , Issue 10 , 28 May 2014 , pp. 1217 - 1222
Copyright
Copyright © Materials Research Society 2014 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Wang, W.H., Dong, C., and Shek, C.H.: Bulk metallic glasses. Mater. Sci. Eng., R 44(2–3), 45 (2004).CrossRefGoogle Scholar
Axinte, E.: Metallic glasses from “alchemy” to pure science: Present and future of design, processing and applications of glassy metals. Mater. Des. 35, 518 (2012).CrossRefGoogle Scholar
Inoue, A. and Takeuchi, A.: Recent development and application products of bulk glassy alloys. Acta Mater. 59(6), 2243 (2011).CrossRefGoogle Scholar
Shen, T.D. and Schwarz, R.B.: Bulk ferromagnetic glasses prepared by flux melting and water quenching. Appl. Phys. Lett. 75(1), 49 (1999).CrossRefGoogle Scholar
Lu, Z.P., Liu, C.T., and Porter, W.D.: Role of yttrium in glass formation of Fe-based bulk metallic glasses. Appl. Phys. Lett. 83(13), 2581 (2003).CrossRefGoogle Scholar
Lu, Z.P., Liu, C.T., Thompson, J.R., and Porter, W.D.: Structural amorphous steels. Phys. Rev. Lett. 92(24), 245503 (2004).CrossRefGoogle ScholarPubMed
Ponnambalam, V., Poon, S.J., and Shiflet, G.J.: Fe-based bulk metallic glasses with diameter thickness larger than one centimeter. J. Mater. Res. 19(05), 1320 (2004).CrossRefGoogle Scholar
Ponnambalam, V., Poon, S.J., and Shiflet, G.J.: Fe-Mn-Cr-Mo-(Y, Ln)-CB (Ln = Lanthanides) bulk metallic glasses as formable amorphous steel alloys. J. Mater. Res. 19(10), 3046 (2004).CrossRefGoogle Scholar
Wang, W.H., Pan, M., Zhao, D., Hu, Y., and Bai, H.: Enhancement of the soft magnetic properties of FeCoZrMoWB bulk metallic glass by microalloying. J. Phys. Condens. Matter 16(21), 3719 (2004).CrossRefGoogle Scholar
Bitoh, T., Makino, A., Inoue, A., and Greer, A.L.: Large bulk soft magnetic [(Fe0.5Co0.5)0.75]B0.20Si0.05]96Nb4 glassy alloy prepared by B2O3 flux melting and water quenching. Appl. Phys. Lett. 88(18), 182510 (2006).CrossRefGoogle Scholar
Wang, W.H.: Roles of minor additions in formation and properties of bulk metallic glasses. Prog. Mater. Sci. 52(4), 540 (2007).CrossRefGoogle Scholar
Jian, H., Luo, W., Tao, S., and Yan, M.: Mechanical and magnetic properties of (Fe72Mo4B24)100−x Tb x (x = 4, 5, 6, 7 at.%) bulk glassy alloys. J. Alloys Compd. 505(1), 315 (2010).CrossRefGoogle Scholar
Lin, S.L., Chen, S.F., Chen, J.K., and Lin, Y.L.: Formation and magnetic properties of Fe–Si–B–Dy amorphous alloy. Intermetallics 18(10), 1826 (2010).CrossRefGoogle Scholar
Chrobak, A., Nosenko, V., Haneczok, G., Boichyshyn, L., Kotur, B., Bajorek, A., Zivotsky, O., and Hendrych, A.: Effect of rare earth additions on magnetic properties of Fe82Nb2B14RE2 (RE = Y, Gd, Tb and Dy) amorphous alloys. Mater. Chem. Phys. 130(1–2), 603 (2011).CrossRefGoogle Scholar
Stoica, M., Roth, S., Eckert, J., Schultz, L., and Baro, M.: Bulk amorphous FeCrMoGaPCB: Preparation and magnetic properties. J. Magn. Magn. Mater. 290, 1480 (2005).CrossRefGoogle Scholar
Park, J., Wang, G., Li, R., Mattern, N., Eckert, J., and Kim, D.: Enhancement of plastic deformability in Fe–Ni–Nb–B bulk glassy alloys by controlling the Ni-to-Fe concentration ratio. Appl. Phys. Lett. 96(3), 031905 (2010).CrossRefGoogle Scholar
Qiu, K., Pang, J., Ren, Y., Zhang, H., Ma, C., and Zhang, T.: Fe-based bulk metallic glasses with a larger supercooled liquid region and high ductility. Mater. Sci. Eng., A 498(1), 464 (2008).CrossRefGoogle Scholar
Yoon, S., Kim, J., Bae, G., Kim, B., and Lee, C.: Formation of coating and tribological behavior of kinetic sprayed Fe-based bulk metallic glass. J. Alloys Compd. 509(2), 347 (2011).CrossRefGoogle Scholar
Lu, Y., Huang, Y., Zheng, W., and Shen, J.: Free volume and viscosity of Fe–Co–Cr–Mo–C–B–Y bulk metallic glasses and their correlation with glass-forming ability. J. Non-Cryst. Solids 358(10), 1274 (2012).CrossRefGoogle Scholar
Huang, X., Chang, C., Chang, Z., Inoue, A., and Jiang, J.: Glass forming ability, mechanical and magnetic properties in Fe–W–Y–B alloys. Mater. Sci. Eng., A 527(7), 1952 (2010).CrossRefGoogle Scholar
Harimkar, S.P., Paital, S.R., Singh, A., Aalund, R., and Dahotre, N.B.: Microstructure and properties of spark plasma sintered Fe–Cr–Mo–Y–B–C bulk metallic glass. J. Non-Cryst. Solids 355(43), 2179 (2009).CrossRefGoogle Scholar
Guo, S., Wu, Z., and Liu, L.: Preparation and magnetic properties of FeCoHfMoBY bulk metallic glasses. J. Alloys Compd. 468(1), 54 (2009).CrossRefGoogle Scholar
Li, J.W., Men, H., and Shen, B.L.: Soft-ferromagnetic bulk glassy alloys with large magnetostriction and high glass-forming ability. AIP Adv. 1(4), 042110 (2011).CrossRefGoogle Scholar
Inoue, A., Shen, B., and Chang, C.: Super-high strength of over 4000 MPa for Fe-based bulk glassy alloys in [(Fe1–x Co x )0.75B0. 2Si0. 05]96Nb4 system. Acta Mater. 52(14), 4093 (2004).CrossRefGoogle Scholar
Setyawan, A.D., Kato, H., Saida, J., and Inoue, A.: Origin of the effect of the gas atmosphere during mold-casting Zr65Al7.5Ni10Pd17.5 bulk glassy or nano-quasicrystal-forming alloy. Mater. Trans. 48(6), 1266 (2007).CrossRefGoogle Scholar
Setyawan, A.D., Kato, H., Saida, J., and Inoue, A.: Glass formation dependence on casting-atmosphere pressure in Zr65Al7.5Ni10Cu17.5–x Pd x (x = 0–17.5) alloy system: A resultant effect of quasicrystalline phase transformation and cooling mechanism during mold-casting process. J. Appl. Phys. 103(4), 044907 (2008).CrossRefGoogle Scholar
Ito, Y., Ueki, O., and Nakamura, S.: Determination of colloidal iron in water by laser-induced breakdown spectroscopy. Anal. Chim. Acta 299(3), 401 (1995).CrossRefGoogle Scholar
Lu, Z.P. and Liu, C.T.: Role of minor alloying additions in formation of bulk metallic glasses: A review. J. Mater. Sci. 39(12), 3965 (2004).CrossRefGoogle Scholar
Wang, Y.X., Yang, H., Lim, G., and Li, Y.: Glass formation enhanced by oxygen in binary Zr-Cu system. Scr. Mater. 62(9), 682 (2010).CrossRefGoogle Scholar
Li, H.X., Gao, J.E., Jiao, Z.B., Wu, Y., and Lu, Z.P.: Glass-forming ability enhanced by proper additions of oxygen in a Fe-based bulk metallic glass. Appl. Phys. Lett. 95(16), 014202 (2009).Google Scholar
Meng, L.L., Li, X.Y., Pang, J., Wang, L., An, B., Yin, L.J., Song, K.K., and Wang, W.M.: Casting atmosphere effects on the precipitates, magnetism, and corrosion resistance of Fe78Si9B13 glassy alloys. Metall. Mater. Trans. A 44A(11), 5122 (2013).CrossRefGoogle Scholar
Wang, W.M., Zhang, J.T., Gebert, A., Roth, S., and Schultz, L.: Casting vacuum effects on the precipitates and magnetic properties of Fe-based glassy alloys. J. Non-Cryst. Solids 357(7), 1657 (2011).CrossRefGoogle Scholar
Tumbull, D. and Fisher, J.C.: Rate of nucleation in condensed systems. J. Chem. Phys. 17, 71 (1949).CrossRefGoogle Scholar
Turnbull, D.: Formation of crystal nuclei in liquid metal. J. Appl. Phys. 21, 1022 (1950).CrossRefGoogle Scholar
Nastar, M. and Clouet, E.: Mean field theories for the description of diffusion and phase transformations controlled by diffusion. Phys. Chem. Chem. Phys. 6(13), 3611 (2004).CrossRefGoogle Scholar
Xue, X.M., Jiang, H.G., Sui, Z.T., Ding, B.Z., and Hu, Z.Q.: Influence of phosphorus addition on the surface tension of liquid iron and segregation of phosphorus on the surface of Fe-P alloy. Metall. Mater. Trans. B 27(1), 71 (1996).CrossRefGoogle Scholar
Lavorato, G.C., Fiore, G., Tiberto, P., Baricco, M., Sirkin, H., and Moya, J.A.: Structural and magnetic properties of Fe76P5(Si0.3B0.5C0.2)19 amorphous alloy. J. Alloys Compd. 536, S319 (2012).CrossRefGoogle Scholar