Hostname: page-component-586b7cd67f-rdxmf Total loading time: 0 Render date: 2024-11-28T12:05:25.789Z Has data issue: false hasContentIssue false

Production of customized hybrid porous structures by powder metallurgy of Ni59Zr20Ti16Si2Sn3 glassy powders

Published online by Cambridge University Press:  19 August 2013

Sergio Scudino*
Affiliation:
IFW Dresden, Institut für Komplexe Materialien, D-01171 Dresden, Germany
Jin Young Kim
Affiliation:
IFW Dresden, Institut für Komplexe Materialien, D-01171 Dresden, Germany
Konda Gokuldoss Prashanth
Affiliation:
IFW Dresden, Institut für Komplexe Materialien, D-01171 Dresden, Germany
Min Ha Lee
Affiliation:
Korea Institute for Rare Metals, Korea Institute of Industrial Technology, Incheon 406-840, Korea
Bum Sung Kim
Affiliation:
Korea Institute for Rare Metals, Korea Institute of Industrial Technology, Incheon 406-840, Korea
Uta Kühn
Affiliation:
IFW Dresden, Institut für Komplexe Materialien, D-01171 Dresden, Germany
Jürgen Eckert
Affiliation:
IFW Dresden, Institut für Komplexe Materialien, D-01171 Dresden, Germany; and TU Dresden, InstitutfürWerkstoffwissenschaft, D-01062 Dresden, Germany
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

Among the different porous materials, bulk metallic glass (BMG) foams are of special interest due to their high strength combined with large elastic limit. Large surface areas and, therefore, high reactivity in chemical applications can be achieved by properly adjusting the pore characteristics. Pore size and pore size distribution are the key factors for determining the overall performance of open-cell porous materials used for functional applications, such as filtration or catalysis. As a result, the control of these factors is a necessary requirement for material design and application. In this work, BMG foams are produced by powder metallurgy through the selective dissolution of a fugitive phase. The work is focused on the manufacturing processes needed to properly control pore size and pore size distribution. The results reveal that customized hybrid BMG porous structures can be produced through the controlled milling of the BMG-composite powders.

Type
Articles
Copyright
Copyright © Materials Research Society 2013 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Ashby, M.F., Evans, A.G., Fleck, N.A., Gibson, L.J., Hutchinson, J.W., and Wadley, H.N.G.: Metal Foams: A Design Guide (Butterworth-Heinemann, Boston, 2000).Google Scholar
Banhart, J.: Manufacture, characterisation and application of cellular metals and metal foams. Prog. Mater. Sci. 46, 559 (2001).CrossRefGoogle Scholar
Schroers, J., Veazey, C., Demetriou, M.D., and Johnson, W.L.: Synthesis method for amorphous metallic foam. J. Appl. Phys. 96, 7723 (2004).CrossRefGoogle Scholar
Cahn, R.W. and Greer, A.L.: Metastable states of alloys, in Physical Metallurgy, edited by Cahn, R.W. and Haasen, P. (Elsevier, Amsterdam, 1996), p. 1723, Ch. 19.CrossRefGoogle Scholar
Johnson, W.L.: Bulk glass-forming metallic alloys: Science and technology. MRS Bull. 24, 42 (1999).CrossRefGoogle Scholar
He, G., Löser, W., Eckert, J., and Schultz, L.: Microstructure, mechanical properties and fracture mechanism of as-cast (Ti0.5Cu0.25Ni0.15Sn0.05Zr0.05)(100-x)Mox composites. Metall. Mater. Trans. A 35, 1591 (2004).CrossRefGoogle Scholar
Gebert, A., Subba Rao, R.V., Wolff, U., Baunack, S., Eckert, J., and Schultz, L.: Corrosion behaviour of the Mg65Y10Cu15Ag10 bulk metallic glass. Mater. Sci. Eng., A 375377, 280 (2004).CrossRefGoogle Scholar
Inoue, A.: Stabilization of metallic supercooled liquid and bulk amorphous alloys. Acta Mater. 48, 279 (2000).CrossRefGoogle Scholar
Peker, A. and Johnson, W.L.: A highly processable metallic glass: Zr41.2Ti13.8Cu12.5Ni10.0Be22.5. Appl. Phys. Lett. 63, 2342 (1993).CrossRefGoogle Scholar
Schroers, J., Veazey, C., and Johnson, W.L.: Amorphous metallic foam. Appl. Phys. Lett. 82, 370 (2003).CrossRefGoogle Scholar
Brothers, A.H. and Dunand, D.C.: Syntactic bulk metallic glass foam. Appl. Phys. Lett. 84, 1108 (2004).CrossRefGoogle Scholar
Huett, V.T., Zander, D., Jastrow, L., Majzoub, E.H., Kelton, K.F., and Köster, U.: Gaseous hydrogen charging of Zr–Cu–Ni–Al glasses and quasicrystals. J. Alloys Compd. 379, 16 (2004).CrossRefGoogle Scholar
Yang, S.Y., Ryu, I., Kim, H.Y., Kim, J.K., Jang, S.K., and Russell, T.P.: Nanoporous membranes with ultrahigh selectivity and flux for the filtration of viruses. Adv. Mater. 18, 709 (2006).CrossRefGoogle Scholar
Wada, T. and Inoue, A.: Formation of porous Pd-based bulk glassy alloys by a high hydrogen pressure melting-water quenching method and their mechanical properties. Mater. Trans. 45, 2761 (2004).CrossRefGoogle Scholar
Wada, T., Inoue, A., and Greer, A.L.: Enhancement of room-temperature plasticity in a bulk metallic glass by finely dispersed porosity. Appl. Phys. Lett. 86, 251907 (2005).CrossRefGoogle Scholar
Lee, M.H. and Sordelet, D.J.: Nanoporous metallic glass with high surface area. Scr. Mater. 55, 947 (2006).CrossRefGoogle Scholar
Schroers, J.: Processing of bulk metallic glass. Adv. Mater. 22, 1566 (2010).CrossRefGoogle ScholarPubMed
Lee, M.H. and Sordelet, D.J.: Synthesis of bulk metallic glass foam by powder extrusion with a fugitive second phase. Appl. Phys. Lett. 89, 021921 (2006).CrossRefGoogle Scholar
Kim, J.Y., Scudino, S., Kühn, U., Kim, B.S., Lee, M.H., and Eckert, J.: Production and characterization of brass-matrix composites reinforced with Ni59Zr20Ti16Si2Sn3 glassy particles. Metals 2, 79 (2012).CrossRefGoogle Scholar
Brauner, S.: Pore structure of solids. Pure Appl. Chem. 48, 401 (1976).CrossRefGoogle Scholar
Suryanarayana, C.: Mechanical Alloying and Milling (Marcel Dekker, New York, 2004).CrossRefGoogle Scholar
Scudino, S., Eckert, J., Yang, X.Y., Sordelet, D., and Schultz, L.: Conditions for quasicrystal formation from mechanically alloyed Zr-based glassy powders. Intermetallics 15, 571 (2007).CrossRefGoogle Scholar
Busch, R., Bakke, E., and Johnson, W.L.: Viscosity of the supercooled liquid and relaxation at the glass transition of the Zr46.75Ti8.25Cu7.5Ni10Be27.5 bulk metallic glass forming alloy. Acta Mater. 46, 4725 (1998).CrossRefGoogle Scholar
Scudino, S., Bartusch, B., and Eckert, J.: Viscosity of the supercooled liquid in multi-component Zr-based metallic glasses. J. Phys. Conf. Ser. 144, 012097 (2009).CrossRefGoogle Scholar
Kawamura, Y., Kato, H., Inoue, A., and Masumoto, T.: Full strength compacts by extrusion of glassy metal powder at the supercooled liquid state. Appl. Phys. Lett. 67, 2008 (1995).CrossRefGoogle Scholar
El-Eskandarany, M.S. and Inoue, A.: Hot pressing and characterizations of mechanically alloyed Zr52Al6Ni8Cu14W20 glassy powders. J. Mater. Res. 21, 976 (2006).CrossRefGoogle Scholar
Scudino, S., Venkataraman, S., Stoica, M., Surreddi, K.B., Pauly, S., Das, J., and Eckert, J.: Consolidation and mechanical properties of ball milled Zr50Cu50 glassy ribbons. J. Alloys Compd. 483, 227 (2009).CrossRefGoogle Scholar
Eckert, J.: Mechanical alloying of highly processable glassy alloys. Mater. Sci. Eng., A 226228, 364 (1997).CrossRefGoogle Scholar