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Photocurrent generation of heterostructured films composed of donor–acceptor and donor–insulator networks on indium-tin-oxide electrodes

Published online by Cambridge University Press:  19 January 2011

Katsuhiko Kanaizuka ,
Shinji Kato ,
Hiroshi Moriyama  and
Chyongjin Pac
Katsuhiko Kanaizuka
Affiliation:
Department of Chemistry, Faculty of Science, Toho University, Funabashi 274-8510, Japan; and Kawamura Institute of Chemical Research, Sakura 285-0078, Japan
Shinji Kato*
Affiliation:
Kawamura Institute of Chemical Research, Sakura 285-0078, Japan
Hiroshi Moriyama*
Affiliation:
Department of Chemistry, Faculty of Science, Toho University, Funabashi 274-8510, Japan
Chyongjin Pac
Affiliation:
Department of Chemistry, Faculty of Science, Toho University, Funabashi 274-8510, Japan
*
b)Address all correspondence to these authors. e-mail: [email protected]
c)e-mail: [email protected]
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Abstract

The heterocomponent films of polypyridine ruthenium(II) complexes and methyl viologen derivatives, and polypyridine ruthenium(II) complexes and alkyl chain derivatives have been successfully obtained using a layer-by-layer fabrication method. We determined their photocurrent generation properties and noted that the photocurrent generation strongly depended on the inner layer. A higher photocurrent generation in the donor–acceptor film was obtained than in a single-component film of the chromophore.

Keywords

Self-AssemblyOrganicSurface Chemistry
Type
Reviews
Information
Journal of Materials Research , Volume 26 , Issue 2: Focus Issue: Self-Assembly and Directed Assembly of Advanced Materials , 28 January 2011 , pp. 236 - 239
Copyright
Copyright © Materials Research Society 2011

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References

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