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Phenol red dyed bis thiourea cadmium acetate monocrystal growth and characterization for optoelectronic applications

Published online by Cambridge University Press:  20 July 2018

Vanga Ganesh ,
Mohd. Shkir Open the ORCID record for Mohd. Shkir [Opens in a new window] ,
Kamlesh Kumar Maurya ,
I.S. Yahia  and
Salem AlFaify
Vanga Ganesh
Affiliation:
Advanced Functional Materials and Optoelectronics Laboratory (AFMOL), Department of Physics, College of Science, King Khalid University, Abha 61413, Saudi Arabia; and Research Center for Advanced Materials Science (RCAMS), King Khalid University, Abha 61413, Saudi Arabia
Mohd. Shkir*
Affiliation:
Advanced Functional Materials and Optoelectronics Laboratory (AFMOL), Department of Physics, College of Science, King Khalid University, Abha 61413, Saudi Arabia; and Research Center for Advanced Materials Science (RCAMS), King Khalid University, Abha 61413, Saudi Arabia
Kamlesh Kumar Maurya
Affiliation:
National Physical Laboratory, Council of Scientific and Industrial Research, New Delhi 110012, India
I.S. Yahia
Affiliation:
Advanced Functional Materials and Optoelectronics Laboratory (AFMOL), Department of Physics, College of Science, King Khalid University, Abha 61413, Saudi Arabia
Salem AlFaify*
Affiliation:
Advanced Functional Materials and Optoelectronics Laboratory (AFMOL), Department of Physics, College of Science, King Khalid University, Abha 61413, Saudi Arabia
*
a)Address all correspondence to these authors. e-mail: [email protected]
b)e-mail: [email protected]
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Abstract

Phenol red dyed bis thiourea cadmium acetate (BTCA) crystals of ∼30 × 10 × 6 mm dimension have been grown for the first time using the slow evaporation solution technique. Diffuse reflectance measurements show absorption bands at 363 and 563 nm in the doped crystal. Optical energy gap was calculated to be 4–5 eV. Photoluminescence spectra were recorded using 320 nm excitation source. The chemical etching study was done and etch pit density was found to be reduced from 4.5 × 103/cm2 (pure) to 3.0 × 102/cm2 (dyed). Mechanical strength is increased from 74.1 kg/mm2 for pure to 94.7 kg/mm2 for dyed crystals. The enriched properties of BTCA in the presence of dye suggest that the dyed crystals will be more applicable compared to pure crystals.

Keywords

growth of crystalsdyed crystalsHRXRDoptical studiesDSCmechanical parameters
Type
Article
Information
Journal of Materials Research , Volume 33 , Issue 16 , 28 August 2018 , pp. 2364 - 2375
Copyright
Copyright © Materials Research Society 2018 

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References

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