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Phase Separation of Gold Microcrystals in Glass with an Electric Field

Published online by Cambridge University Press:  03 March 2011

Guoliang Wang ,
Kaiming Liang ,
Wei Liu ,
Feng Zhou ,
Hua Shao  and
Anmin Hu
Guoliang Wang*
Affiliation:
Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, People’s Republic of China
Kaiming Liang
Affiliation:
Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, People’s Republic of China
Wei Liu
Affiliation:
Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, People’s Republic of China
Feng Zhou
Affiliation:
Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, People’s Republic of China
Hua Shao
Affiliation:
Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, People’s Republic of China
Anmin Hu
Affiliation:
Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

Based on static electromagnetics theory and thermodynamics theory, a new model is proposed to describe the phase separation from the glass doped with metal particles in a static electric field. This model is proved by a heat-treatment experiment of boracic silicate glass doped with gold. The results indicate that the externally applied electric field promotes the phase separation of the glass and leads to a different size of the droplet phase just as this new model has predicted.

Keywords

Nucleation & growthGlassThermodynamic properties
Type
Articles
Information
Journal of Materials Research , Volume 19 , Issue 4 , April 2004 , pp. 1024 - 1028
Copyright
Copyright © Materials Research Society 2004

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References

REFERENCES

1Recard, D., Roussignol, P. and Plytzanis, C.: Opt. Lett. 10, 511 (1985).Google Scholar
2Sasai, J. and Hirao, K.I.: Solids. 290, 49 (2001).Google Scholar
3Kineri, T., Mori, M., Kadono, K., Sakaguchi, T., Miya, M., Wakabayashi, H. and Tsuchiya, T.: J. Ceram. Soc. Jpn. 103, 117 (1995).Google Scholar
4Battaglin, G., Boscolo-Boscoletto, A., Mazzoldi, P., Meneghini, C. and Arnold, G.W.: Nucl. Instrum. and Meth. B 116, 527 (1996).Google Scholar
5Matsuoka, J., Mizutani, R., Kaneko, S., Nasu, H., Kamiya, K., Kadono, K., Sakaguchi, T. and Miya, M.: J. Ceram. Soc. Jpn. 101, 53 (1993).Google Scholar
6Selvan, S.T., Hayakawa, T., Nogami, M., Kobayashi, Y., Liz-Marzan, L.M., Hamanaka, Y. and Nakamura, A.: J. Phys. Chem. B. 106, 10157 (2002).Google Scholar
7Valentin, E., Bernas, H., Ricolleau, C. and Creuzet, F.: Phys. Rev. Lett. 86, 99 (2001).Google Scholar
8Schmelzer, J., Lembke, U. and Kranold, R.: J. Chem. Phys. 113, 1268 (2000).CrossRefGoogle Scholar
9Hopper, R.W. and Uhlmann, D.R.: Phys. Chem. Glasses. 14, 37 (1973).Google Scholar
10Liu, W., Liang, K.M., Zheng, Y.K., Gu, S.R. and Chen, H.: J. Phys. D: Appl. Phys. 30, 3366 (1997).Google Scholar
11Liu, W., Gu, X.M., Liang, K.M., Chen, H., Zheng, Y.K. and Gu, S.R.: Metall. Mater. Trans. B. 30B, 685 (1999).Google Scholar
12Liu, W., Liang, K.M., Gu, X.M., Zheng, Y.K. and Gu, S.R.: J. Mater. Sci. 34, 3455 (1999).CrossRefGoogle Scholar
13Bleaney, B.I. and Bleaney, B. in Electricity and Magnetism , 3rd ed. (Oxford University Press, Oxford, U.K., 1976), Chap. 1 and 2Google Scholar
14Pratima, R. and Robert, D.: Solids. 203, 202 (1996).Google Scholar