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Oxidized starch films reinforced with natural halloysite

Published online by Cambridge University Press:  25 November 2011

Weina Kong
Affiliation:
Department of Science, Tianjin University, Tianjin 300072, People’s Republic of China
Wenchao Wang
Affiliation:
Department of Science, Tianjin University, Tianjin 300072, People’s Republic of China
Jianping Gao*
Affiliation:
Department of Science, Tianjin University, Tianjin 300072, People’s Republic of China
Tianlin Liu
Affiliation:
Department of Science, Tianjin University, Tianjin 300072, People’s Republic of China
Yu Liu*
Affiliation:
Department of Science, Tianjin University, Tianjin 300072, People’s Republic of China
*
a)Address all correspondence to these authors. e-mail: [email protected]
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Abstract

Oxidized starch (OSt) films reinforced with natural halloysite were prepared by adding modified natural halloysite nanotubes into an OSt matrix. The halloysite/OSt films were characterized by x-ray diffraction, scanning electron microscopy, and ultraviolet spectrometry. The mechanical properties and moisture absorbability of the films were also studied. The modified halloysite nanotubes were well distributed in the starch matrix, and the tensile strength (TS) of the films was greatly enhanced, but the moisture adsorption ability of the films only changed slightly. The flexibility of the films was improved by adding glycerol but at a cost of reducing the TS. Incorporating a small amount of poly(vinyl alcohol) (PVA) improved both the TS and the percent elongation at break of the halloysite/OSt films.

Type
Articles
Copyright
Copyright © Materials Research Society 2011

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References

REFERENCES

1.Das, K., Ray, D., Bandyopadhyay, N.R., Gupta, A., Sengupta, S., Sahoo, S., Mohanty, A., and Misra, M.: Preparation and characterization of cross-linked starch/poly(vinyl alcohol) green films with low moisture absorption. Ind. Eng. Chem. Res. 49, 2176 (2010).CrossRefGoogle Scholar
2.Belhassen, R., Boufi, S., Vilaseca, F., Lo′ pez, J.P., Me’ndez, J.A., Franco, E., Pe′ lach, M.A., and Mutje′, P.: Biocomposites based on Alfa fibers and starch-based biopolymer. Polym. Adv. Technol. 20, 1068 (2009).CrossRefGoogle Scholar
3.Sreedhar, B., Chattopadhyay, D.K., Karunakar, M.S.H., and Sastry, A.R.K.: Thermal and surface characterization of plasticized starch polyvinyl alcohol blends crosslinked with epichlorohydrin. J. Appl. Polym. Sci. 101, 25 (2006).CrossRefGoogle Scholar
4.Zou, G.X., Qu, J.P., and Zou, X.L.: Optimization of water absorption of starch/PVA composites. Polym. Compos. 28, 674 (2007).CrossRefGoogle Scholar
5.Avella, M., Errico, M.E., Rimedio, R., and Sadocco, P.: Preparation of biodegradable polyesters/high amylose starch composites by reactive blending and their characterization. J. Appl. Polym. Sci. 83, 1432 (2002).CrossRefGoogle Scholar
6.Carvalho, A.J.F., Job, A.E., Alves, N., Curvelo, A.A.S., and Gandini, A.: Thermoplastic starch/natural rubber blends. Carbohydr. Polym. 53, 95 (2003).CrossRefGoogle Scholar
7.Follain, N., Joly, C., and Dole, P.: Properties of starch based blends. Part 2. Influence of poly vinyl alcohol addition and photocrosslinking on starch based materials mechanical properties. Carbohydr. Polym. 60, 185 (2005).CrossRefGoogle Scholar
8.Park, H.R., Chough, S.H., Yun, Y.H., and Yoon, S.D.: Properties of starch/PVA blend films containing citric acid as additive. J. Polym. Environ. 13, 375 (2005).CrossRefGoogle Scholar
9.Wu, H.X., Liu, C.H., Chen, J.G., Chen, Y., Anderson, D.P., and Chang, P.R.: Oxidized pea starch/chitosan composite films: Structural characterization and properties. J. Appl. Polym. Sci. 118, 3082 (2010).CrossRefGoogle Scholar
10.Wan, Y.Z., Luo, H.L., He, F., Liang, H., Huang, Y., and Li, X.L.: Mechanical, moisture absorption, and biodegradation behaviors of bacterial cellulose fiber-reinforced starch biocomposites. Compos. Sci. Technol. 69, 1212 (2009).CrossRefGoogle Scholar
11.Wang, Q., Hu, X.W., Du, Y.M., and Kennedy, J.F.: Alginate/starch blend fibers and their properties for drug controlled release. Carbohydr. Polym. 82, 842 (2010).CrossRefGoogle Scholar
12.Kristo, E. and Biliaderis, C.G.: Physical properties of starch nanocrystal-reinforced pullulan films. Carbohydr. Polym. 68, 146 (2007).CrossRefGoogle Scholar
13.Mu, C.D., Liu, F., Cheng, Q.S., Li, H.L., Wu, B., Zhang, G.Z., and Lin, W.: Collagen cryogel cross-linked by dialdehyde starch. Macromol. Mater. Eng. 295, 100 (2010).CrossRefGoogle Scholar
14.Gomes, M.E., Ribeiro, A.S., Malafaya, P.B., Reis, R.L., and Cunha, A.M.: A new approach based on injection moulding to produce biodegradable starch-based polymeric scaffolds: Morphology, mechanical and degradation behavior. Biomaterials 22, 883 (2001).CrossRefGoogle Scholar
15.Blazek, J. and Copeland, L.: Amylolysis of wheat starches. II. Degradation patterns of native starch granules with varying functional properties. J. Cereal Sci. 52, 295 (2010).CrossRefGoogle Scholar
16.Leonor, I.B., Ito, A., Onuma, K., Kanzaki, N., and Reis, R.L.: In vitro bioactivity of starch thermoplastic/hydroxyapatite composite biomaterials: An in situ study using atomic force microscopy. Biomaterials 24, 579 (2003).CrossRefGoogle Scholar
17.Kampeerapappun, P., Aht-Ong, D., Pentrakoon, D., and Srikulkit, K.: Preparation of cassava starch/montmorillonite composite film. Carbohydr. Polym. 67, 155 (2007).CrossRefGoogle Scholar
18.Mondragón, M., Hernánde, E.M., Rivera-Armenta, J.L., and Rodríguez-González, F.J.: Injection molded thermoplastic starch/natural rubber/clay nanocomposites: Morphology and mechanical properties. Carbohydr. Polym. 77, 80 (2009).CrossRefGoogle Scholar
19.Vertuccio, L., Gorrasi, G., Sorrentino, A., and Vittoria, V.: Nano clay reinforced PCL/starch blends obtained by high-energy ball milling. Carbohydr. Polym. 75, 172 (2009).CrossRefGoogle Scholar
20.Ismail, H., Pasbakhsh, P., Ahmad Fauzi, M.N., and Abu Bakar, A.: Morphological, thermal and tensile properties of halloysite nanotubes filled ethylene propylene diene monomer (EPDM) nanocomposites. Polym. Test. 27, 841 (2008).CrossRefGoogle Scholar
21.Shchukin, D.G., Zheludkevich, M., Yasakau, K., Lamaka, S., Ferreira, M.G.S., and Mohwald, H.: Layer-by-Layer nanocontainers for self-healing corrosion protection. Adv. Mater. 18, 1672 (2006).CrossRefGoogle Scholar
22.Shchukin, D.G. and Mohwald, H.: Surface-engineered nanocontainers for entrapment of corrosion inhibitors. Adv. Funct. Mater. 17, 1451 (2007).CrossRefGoogle Scholar
23.Price, R.R., Gaber, B.P., and Lvov, Y.M.: In-vitro release characteristics of tetracycline HCl, khellin and nicotinamide adenine dineculeotide from halloysite; a cylindrical mineral. J. Microencapsul. 18, 713 (2001).Google ScholarPubMed
24.Machado, G.S., Castro, K.A.D.F., Wypych, F., and Nakagaki, S.: Immobilization of metalloporphyrins into nanotubes of natural halloysite toward selective catalysts for oxidation reactions. J. Mol. Catal. Chem. 283, 99 (2008).CrossRefGoogle Scholar
25.Marney, D.C.O., Russell, L.J., Wu, D.Y., Nguyen, T., Cramm, D., Rigopoulos, N., Wright, N., and Greaves, M.: The suitability of halloysite nanotubes as a fire retardant for nylon 6. Polym. Degrad. Stab. 93, 1971 (2008).CrossRefGoogle Scholar
26.Pasbakhsh, P., Ismail, H., Ahmad Fauzi, M.N., and Abu Baka, A.: EPDM/modified halloysite nanocomposites. Appl. Clay Sci. 48, 405 (2010).CrossRefGoogle Scholar
27.Zheng, Y.A. and Wang, A.Q.: Enhanced adsorption of ammonium using hydrogel composites based on chitosan and halloysite. J. Macromol. Sci. Pure Appl. Chem. 47, 33 (2010).CrossRefGoogle Scholar
28.Hughes, A.D. and King, M.R.: Use of naturally occurring halloysite nanotubes for enhanced capture of flowing cells. Langmuir 26, 12155 (2010).CrossRefGoogle ScholarPubMed
29.Vergaro, V., Abdullayev, E., Lvov, Y.M., Zeitoun, A., Cingolani, R., Rinaldi, R., and Leporatti, S.: Cytocompatibility and uptake of halloysite clay nanotubes. Biomacromolecules 11, 820 (2010).CrossRefGoogle ScholarPubMed
30.Ning, N.Y., Yin, Q.J., Luo, F., Zhang, Q., Du, R., and Fu, Q.: Crystallization behavior and mechanical properties of polypropylene/halloysite composites. Polymer 48, 7374 (2007).CrossRefGoogle Scholar
31.Chang, P.R., Yu, J.G., and Ma, X.F.: Fabrication and characterization of Sb2O3/carboxymethyl cellulose sodium and the properties of plasticized starch composite films. Macromol. Mater. Eng. 294, 762 (2009).CrossRefGoogle Scholar