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Oxidation of Zr2[Al(Si)]4C5 and Zr3[Al(Si)]4C6 in air

Published online by Cambridge University Press:  31 January 2011

L.F. He ,
Y.W. Bao ,
M.S. Li ,
J.Y. Wang  and
Y.C. Zhou
L.F. He
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China; and Graduate School of Chinese Academy of Sciences, Beijing 100039, China
Y.W. Bao
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
M.S. Li
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
J.Y. Wang
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
Y.C. Zhou*
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

The oxidation behavior of Zr2[Al(Si)]4C5 and Zr3[Al(Si)]4C6 in air has been investigated. The oxidation kinetics of bulk Zr2[Al(Si)]4C5 and Zr3[Al(Si)]4C6 at 900–1300 °C generally follow a parabolic law at a very short initial stage and then a linear law for a long period with the activation energy of 237.9 and 226.8 kJ/mol, respectively. The oxide scales have a duplex structure, consisting of mainly an outer porous layer of ZrO2, Al2O3, and aluminosilicate/mullite, and a thin inner compact layer of these oxides plus remaining carbon. The oxidation resistance of Zr2[Al(Si)]4C5 and Zr3[Al(Si)]4C6 has been improved compared with Zr2Al3C4, and is much better than ZrC due to larger fraction of protective oxidation products, Al2O3 and aluminosilicate/mullite.

Keywords

CeramicOxidationOxide
Type
Articles
Information
Journal of Materials Research , Volume 23 , Issue 12: Biomimetic and Bio-enabled Materials Science and Engineering , December 2008 , pp. 3339 - 3346
Copyright
Copyright © Materials Research Society 2008

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