Hostname: page-component-586b7cd67f-g8jcs Total loading time: 0 Render date: 2024-11-24T20:41:23.946Z Has data issue: false hasContentIssue false
  • English
  • Français

The oxidant peroxo method (OPM) as a new alternative for the synthesis of lead-based and bismuth-based oxides

Published online by Cambridge University Press:  15 January 2014

Emerson R. Camargo ,
Mayra Gonçalves Dancini  and
Masasto Kakihana
Emerson R. Camargo*
Affiliation:
Interdisciplinary Laboratory of Electrochemistry and Ceramics, Department of Chemistry, UFSCar-Federal University of São Carlos, São Carlos SP, 13565-905, Brazil
Mayra Gonçalves Dancini
Affiliation:
Interdisciplinary Laboratory of Electrochemistry and Ceramics, Department of Chemistry, UFSCar-Federal University of São Carlos, São Carlos SP, 13565-905, Brazil
Masasto Kakihana
Affiliation:
Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Aoba-ku, Sendai, Miyagi 980-8577, Japan
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

The oxidant peroxo method (OPM) exhibits several advantage and unique characteristics not found in the traditional methods for the synthesis of lead- and bismuth-based oxides. First of all, it is a clean method based on hydrogen peroxide that matches perfectly with the green chemistry approach. Second, the oxidizing local atmosphere provided by the precursor during its crystallization is unique among all the wet chemical techniques of synthesis, which usually result in reducing environment. Besides these advantages, only a few studies have focused on the use of the OPM to obtain better materials, which makes this field of study an excellent opportunity for the development of materials with higher purity and controlled morphologies.

Keywords

ceramicchemical synthesispowder processing
Type
Articles
Information
Journal of Materials Research , Volume 29 , Issue 1: Focus Issue: Synthesis of Nanostructured Functional Oxides , 14 January 2014 , pp. 131 - 138
Copyright
Copyright © Materials Research Society 2013 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Yoshimura, M.: Importance of soft solution processing for advanced inorganic materials. J. Mater. Res. 13, 796 (1998).Google Scholar
Yoshimura, M. and Livage, J.: Soft processing for advanced inorganic materials. MRS Bull. 25, 12 (2000).CrossRefGoogle Scholar
Kakihana, M.: Sol-gel preparation of high temperature superconducting oxides. J. Sol-Gel Sci. Technol. 6, 7 (1996).CrossRefGoogle Scholar
Lakeman, C.D.E. and Payne, D.A.: Sol-gel processing of electrical and magnetic ceramics. Mater. Chem. Phys. 38, 305 (1994).CrossRefGoogle Scholar
Chandler, C.D., Roger, C., and Hampdem-Smith, M.J.: Chemical aspects of solution routes to perovskites-phase mixed-metal oxides from metalorganic precursors. Chem. Rev. 93, 1205 (1993).Google Scholar
Esch, J.H. and Feringa, B.L.: New functional materials based on self-assembling organogels: From serendipity towards design. Angew. Chem. Int. Ed. 39, 2263 (2000).Google Scholar
Camargo, E.R. and Kakihana, M.: Peroxide based route free from halides for the synthesis of lead titanate powder. Chem. Mater. 13, 1181 (2001).Google Scholar
Kubo, T.: A new heteropolyacid with carbon as a heteroatom in a Keggin-like structure. Nature 312, 537 (1984).Google Scholar
Yamanaka, K., Oakamoto, H., Kidou, H., and Kudo, T.: Peroxontungstic acid films for electrochrmic display devides. Jpn. J. Apl. Phys. 25, 1420 (1986).CrossRefGoogle Scholar
Hinokuma, K., Kisjhimoto, A., and Kudo, T.: Coloration dynamics of spin-coated MoO3·nH2O electrochromic films fabricated form peroxo-polymolybdate solution. J. Electrochem. Soc. 141, 876 (1994).Google Scholar
Safari, A., Lee, Y.H., Halliyal, A., and Newham, R.E.: 0-3 piezoelectric composites prepared by coprecipitated PbTiO3 powder. Am. Ceram. Soc. Bull. 66, 668 (1987).Google Scholar
Pfaff, G.: Peroxide route to synthesize strontium titanate powders of different composition. J. Eur. Ceram. Soc. 9, 121 (1992).Google Scholar
Pfaff, G.: Synthesis of magnesium stannates by thermal decomposition of peroxo-precursors. Thermochim. Acta 37, 83 (1994).CrossRefGoogle Scholar
Wang, Z. and Hu, X.: Fabricatopn and electrochromic properties of spin-coated TiO2 thin films from peroxo-polytitanic acid. Thin Solid Films 352, 62 (1999).CrossRefGoogle Scholar
Wang, Z., Hu, X., and Helmerson, U.: Peroxo sol-gel preparation: Photochromic/electrochromic properties of Mo-Ti oxide gels and thin films. J. Mater. Chem. 10, 2396 (2000).Google Scholar
Hou, J., Qu, Y., Krsmanovic, D., and Kumar, R.V.: Peroxide-based route assited with inverse microemulsion process to well-dispersed Bi4Ti3O12 nanocrystals. J. Nanopart. Res. 12, 1797 (2010).Google Scholar
Tengvall, P., Elwing, H., Sjöqvist, L., Lundström, I., and Bjursten, L.M.: Interaction between hydrogen peroxide and titanium: A possible role in the biocompatibility of titanium. Biomaterials 10, 118 (1989).CrossRefGoogle ScholarPubMed
Tengvall, P., Vikinge, T.P., Lundström, I., and Liedverg, B.: FT-Raman spectroscopic studies of the degradation of titanium peroxy gels made form metallic and hydrogen peroxide. J. Colloid. Interface Sci. 160, 10 (1993).Google Scholar
Camargo, E.R., Poppa, M., Frantti, J., and Kakihana, M.: Wet-chemical route for the preparation of lead zirconate: An amorphous carbon and halide free precursor synthesized by hydrogen peroxide-based route. Chem. Mater. 13, 3843 (2001).Google Scholar
Camargo, E.R. and Kakihana, M.: Lead hafnate (PbHfO3) perovskite powders obtained by the oxidant peroxo method free from halides and carbon. J. Am. Ceram. Soc. 85, 2107 (2002).Google Scholar
Camargo, E.R., Barrado, C.M., Ribeiro, C., Leite, E.R., and Longo, E.: Nanosized lead lanthanum titanate (PLT) ceramic powders synthesized by the oxidant peroxo method. J. Alloys Compd. 475, 817 (2009).CrossRefGoogle Scholar
Pinto, A.H., Souza, F.L., Chiquito, A.D., Longo, E., Leite, E.R., and Camargo, E.R.: Characterization of dense lead lanthanum titanate ceramics prepared from powders synthesized by the oxidant peroxo method. Mater. Chem. Phys. 124, 1051 (2010).Google Scholar
Pinto, A.H., Souza, F.L., Longo, E., Leite, E.R., and Camargo, E.R.: Structural and dielectric characterization of praseodymium-modified lead titanate ceramics synthesized by the OPM route. Mater. Chem. Phys. 130, 256 (2011).CrossRefGoogle Scholar
Camargo, E.R., Frantti, J., and Kakihana, M.: Low temperature chemical synthesis of lead zirconate titanate (PZT) powders free from halides and organics. J. Mater. Chem. 11, 1875 (2001).Google Scholar
Camargo, E.R., Longo, E., Leite, E.R., and Mastelaro, V.R.: Phase evolution of lead titanate from it amorphous precursor synthesized by the OPM wet-chemical route. J. Solid State Chem. 177, 1994 (2004).CrossRefGoogle Scholar
Camargo, E.R., Souza, F.L., Leite, E.R., and Kakihana, M.: Structural and electrical characterization of dense lead zirconate titanate. J. Appl. Phys. 96, 2169 (2004).CrossRefGoogle Scholar
Calderon-Moreno, J.M. and Camargo, E.R.: Electron microscopy studies on the formation and evolution of sodium niobate nanoparticles from a polymeric precursor. Catal. Today 78, 539 (2003).Google Scholar
Camargo, E.R., Longo, E., Leite, E.R., and Kakihana, M.: Qualitative measurement of residual carbon in wet-chemically synthesized powders. Ceram. Int. 30, 2235 (2004).Google Scholar
Zhang, Q.M., Wang, H., Kim, N., and Cross, L.E.: Direct evaluation of domain-wall and intrinsic contributions to the dielectric and piezoelectric response and their temperature dependence on lead zirconate-titanate ceramics. J. Appl. Phys. 75, 454 (1994)CrossRefGoogle Scholar