Hostname: page-component-586b7cd67f-rdxmf Total loading time: 0 Render date: 2024-11-24T10:43:34.415Z Has data issue: false hasContentIssue false
  • English
  • Français

Optical properties of the black diamond produced by ion implantation

Published online by Cambridge University Press:  30 June 2011

Jae-Won Park ,
Hyung-Jin Kim  and
Young-Chool Kim
Jae-Won Park*
Affiliation:
Korea Atomic Energy Research Institute, Yuseong-Gu, Daejeon 305-600, Korea
Hyung-Jin Kim
Affiliation:
Korea Atomic Energy Research Institute, Yuseong-Gu, Daejeon 305-600, Korea
Young-Chool Kim
Affiliation:
Hanmi Gemological Institute Laboratory, Bongik-dong, Jongno-gu, Seoul 110-390, Korea
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

The optical properties of N-ion-implanted diamond are evaluated. The color of implanted layer became glossy black with metallic luster, which was further enhanced after postimplantation annealing at 600 °C for 2 h in vacuum or inert gas atmosphere. Raman spectroscopy revealed that the crystalline diamond became completely disordered after irradiation, but surprisingly the crystalline nature was restored to a mixture of well-defined diamond and diamond-like carbon after annealing. When it was annealed in air at the same temperature, however, the black color disappeared, indicating a removal of the disordered or graphitized layer by oxidation. X-ray photoelectron spectroscopy and Raman analyses indicate that the black color of as-implanted diamond is associated mainly with the disordered carbon and modified band structure. Fourier transform infrared (FTIR) analysis shows that the implanted nitrogen atoms are in N–N and symmetrical 4N-vacancy bonding states, which are commonly found in the natural diamonds with yellow and brown tint.

Keywords

DiamondIon implantationOptical properties
Type
Articles
Information
Journal of Materials Research , Volume 26 , Issue 13 , 14 July 2011 , pp. 1572 - 1576
Copyright
Copyright © Materials Research Society 2011

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Willems, B., De Corte, K., and Van Tendeloo, G.: Why does polycrystalline natural diamond turn black after annealing. Phys. Status Solidi A 201, 2486 (2004).CrossRefGoogle Scholar
2.Mita, Y.: Change of absorption spectra in type-Ib diamond with heavy neutron irradiation. Phys. Rev. B 53(17), 11360 (1996).CrossRefGoogle ScholarPubMed
3.Chaiwong, C., Yu, L.D., Schinarakis, K., and Vilaithong, T.: Optical property modification of ruby and sapphire by N-ion implantation. Surf. Coat. Tech. 196, 108 (2005).CrossRefGoogle Scholar
4.McHargue, C.J., Farlow, G.C., Lewis, M.B., Williams, J.M.: Implantation of gases into sapphire. Nucl. Instrum. Methods, Phys. Res., Sect. B 19/20, 809 (1987).CrossRefGoogle Scholar
5.Prelas, M.A., Popovici, G., and Bigelow, L.K.: Handbook of Industrial Diamonds and Diamond Films (Marcel Dekker, New York, 1998), Ch.7, p. 232.Google Scholar
6.Collins, A.T.: The color of diamond and How it may be changed? J. Gemmol. 27(6), 341 (2001).CrossRefGoogle Scholar
7.Jagielski, J., Moncoffre, N., Delichere, P., and Marest, G.: On the possibility of β-C3N4 carbon nitride synthesis by C and N implantation into Cu. J. Mater. Sci. 34, 2949 (1999).CrossRefGoogle Scholar
8.Ripalda, J.M., Diaz, N., Roman, E., Galan, L., Montero, I., Goldoni, A., Baraldi, A., Lizzit, S., Comelli, G., and Paolucci, G.: Chemical shift resolved photoionization cross sections of amorphous carbon nitrides. Phys. Rev. Lett. 85(10), 2132 (2000).CrossRefGoogle Scholar
9.Raole, P.M., Mukherjee, S., and John, P.I.: X-ray photoelectron spectroscopic study of plasma source nitrogen ion implantation in single crystalline natural diamond. Diam. Relat. Mater. 14, 482 (2005).CrossRefGoogle Scholar
10.Birrell, J., Gerbi, J., Auciello, O., Gibson, J. M., Gruen, D. M., and Carlisle, J.A.: Bonding structure in nitrogen doped ultra-nanocrystalline diamond. J. Appl. Phys. 93, 5606 (2003).CrossRefGoogle Scholar
11.Lee, E.H., Hembree, D.M. Jr., Rao, G.R., and Mansur, L.K.: Raman scattering from ion-implanted diamond, graphite, and polymers. Phys. Rev. B 48(21), 48 (1993).CrossRefGoogle ScholarPubMed
12.Hickey, D.P., Jones, K.S., and Elliman, R.G.: Amorphization and graphitization of single-crystal diamond—A transmission electron microscopy study. Diam. Relat. Mater. 18, 1353 (2009).CrossRefGoogle Scholar
13.Prawer, S.: Ion implantation into diamond and diamond films. Diam. Relat. Mater. 4, 862 (1995).CrossRefGoogle Scholar
14.Grimsditch, M.H. and Ramdas, A.K.: Brilouin scattering in diamond. Phys. Rev. B 11, 3139 (1975).CrossRefGoogle Scholar
15.Chen, X., Sullivan, J.P., Friedmann, T.A., and Gibson, J.M.: Fluctuation microscopy studies of medium-range ordering in amorphous diamond-like carbon films. Appl. Phys. Lett. 84, 2823 (2004).CrossRefGoogle Scholar