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A novel two-step preparation of spinel LiMn2O4 nanowires and its electrochemical performance charaterization

Published online by Cambridge University Press:  01 June 2012

Hu Zhao ,
Dongfeng Chen ,
Meng Yan ,
Jie Peng ,
Mei Mei Wu ,
Xiao Ling Xiao  and
Zhong-Bo Hu
Hu Zhao
Affiliation:
College of Materials Science and Opto-Electronic Technology, Graduate University of Chinese Academy of Sciences, Beijing 100049, China
Dongfeng Chen
Affiliation:
Department of Nuclear Physics, China Institute of Atomic Energy, Beijing 102413, China
Meng Yan
Affiliation:
College of Materials Science and Opto-Electronic Technology, Graduate University of Chinese Academy of Sciences, Beijing 100049, China
Jie Peng
Affiliation:
Experimental Physics Center, Institute of High Energy Physics Chinese Academy of Science, Beijing 100049, China
Mei Mei Wu
Affiliation:
Department of Nuclear Physics, China Institute of Atomic Energy, Beijing 102413, China
Xiao Ling Xiao*
Affiliation:
College of Materials Science and Opto-Electronic Technology, Graduate University of Chinese Academy of Sciences, Beijing 100049, China
Zhong-Bo Hu*
Affiliation:
College of Materials Science and Opto-Electronic Technology, Graduate University of Chinese Academy of Sciences, Beijing 100049, China
*
a)Address all correspondence to these authors. e-mail: [email protected]
b)e-mail: [email protected]
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Abstract

LiMn2O4 nanowires have been synthesized by a two-step approach. γ-MnOOH nanowires are firstly synthesized by hydrothermal method and after further sintering with LiOH at 750 °C for about 3 h, the wire-like LiMn2O4 can be obtained. The structure of the final product is characterized by x-ray diffraction using Rietveld refinement. Its electrochemical performance is investigated by galvanostatic tests. The as-prepared LiMn2O4 nanowires display excellent cyclability. The LiMn2O4 nanowires with good cycle stability may be beneficial from the structural stability of LiMn2O4 crystal cell and one-dimensional nanostructure.

Type
Articles
Information
Journal of Materials Research , Volume 27 , Issue 13 , 14 July 2012 , pp. 1750 - 1754
Copyright
Copyright © Materials Research Society 2012

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