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Morphology and electronic properties of carbon nanotubes grown with Fe catalyst

Published online by Cambridge University Press:  03 March 2011

E. Kowalska ,
J. Radomska ,
P. Byszewski ,
P. Kowalczyk ,
K. Antonova ,
R. Diduszko ,
H. Lange  and
P. Dłuzewski
E. Kowalska*
Affiliation:
Industrial Institute of Electronics, ul. Dluga 44/50, 00-241 Warsaw, Poland
J. Radomska
Affiliation:
Industrial Institute of Electronics, ul. Dluga 44/50, 00-241 Warsaw, Poland
P. Byszewski
Affiliation:
Institute of Physics, PAS, al. Lotników 321/46, 02-668 Warsaw, Poland
P. Kowalczyk
Affiliation:
Department of Solid State Physics, University of Łódź, ul. Pomorska 149/153, 90-236 Łódź, Poland
K. Antonova
Affiliation:
Institute of Solid State Physics, BAS, blvd. Tzarigradsko chaussee 72, 1784 Sofia, Bulgaria
R. Diduszko
Affiliation:
Industrial Institute of Electronics, ul. Długa 44/50, 00-241 Warsaw, Poland
H. Lange
Affiliation:
Department of Chemistry, Warsaw University, ul. Pasteuro 1, 02-093 Warsaw, Poland
P. Dłuzewski
Affiliation:
Institute of Physics, PAS, al. Lotników 32146, 02-668 Warsaw, Poland
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

We describe the synthesis and characterization of aligned carbon nanotubes deposited on quartz substrates by pyrolysis of a xylene–ferrocene mixture at 700 °C at atmospheric pressure. For microscopic characterization of the pyrolyzed products, scanning and transmission electron microscopies and scanning tunneling microcopy were used, and properties of bulk samples were characterized by Raman spectroscopy and x-ray powder diffraction methods. The nanotubes have topological defects and many contain metal particles. Scanning tunneling spectroscopy proved that the nanotubes had a metallic electrical conductivity with resonant states near the Fermi energy. The states are ascribed to the dangling bonds originating from the defects.

Type
Articles
Information
Journal of Materials Research , Volume 18 , Issue 10 , October 2003 , pp. 2451 - 2458
Copyright
Copyright © Materials Research Society 2003

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