Hostname: page-component-586b7cd67f-rcrh6 Total loading time: 0 Render date: 2024-11-24T14:45:25.006Z Has data issue: false hasContentIssue false
  • English
  • Français

Molecular hydrogen carrier with activated nanohydride and ammonia

Published online by Cambridge University Press:  31 January 2011

Yoshitsugu Kojima ,
Kyoichi Tange ,
Satoshi Hino ,
Shigehito Isobe ,
Masami Tsubota ,
Kosei Nakamura ,
Masashi Nakatake ,
Hiroki Miyaoka ,
Hikaru Yamamoto  and
Takayuki Ichikawa
Yoshitsugu Kojima*
Affiliation:
Institute for Advanced Materials Research and Department of Quantum Matter, ADSM, Hiroshima University, Higashi-Hiroshima 739-8530, Japan
Satoshi Hino
Affiliation:
Department of Quantum Matter, ADSM, Hiroshima University, Higashi-Hiroshima 739-8530, Japan
Masami Tsubota
Affiliation:
Institute for Advanced Materials Research ADSM, Hiroshima University, Higashi-Hiroshima 739-8530, Japan
Kosei Nakamura
Affiliation:
Department of Quantum Matter, ADSM, Hiroshima University, Higashi-Hiroshima 739-8530, Japan
Masashi Nakatake
Affiliation:
Hiroshima Synchrotron Radiation Center, Hiroshima University, Higashi-Hiroshima 739-8526, Japan
Hiroki Miyaoka
Affiliation:
Institute for Advanced Materials Research ADSM, Hiroshima University,Higashi-Hiroshima 739-8530, Japan
Hikaru Yamamoto
Affiliation:
Department of Quantum Matter, ADSM, Hiroshima University, Higashi-Hiroshima 739-8530, Japan
Takayuki Ichikawa
Affiliation:
Institute for Advanced Materials Research and Department of Quantum Matter, ADSM, Hiroshima University, Higashi-Hiroshima 739-8530, Japan
*
a) Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

We show a drastically improved gas–solid reaction between NH3 and LiH by mechanical treatment for LiH, generating a hydrogen gas even at room temperature. The results of x-ray photoelectron spectroscopy showed that the mechanical pretreatment was effective in reducing a hydroxide phase from the surface of LiH. It was also possible to successfully recycle back LiNH2, which is the byproduct of this hydrogen desorption reaction, to LiH under 0.5-MPa H2 flow at 573 K. Thus, the LiH–NH3 system provides a recyclable H2 storage system to generate H2 at room temperature with 8.1 mass% and 4.5 kg/100 L hydrogen capacity.

Keywords

HydrogenationReactive ball millingX-ray photoelectron spectroscopy (XPS)
Type
Outstanding Symposium Papers
Information
Journal of Materials Research , Volume 24 , Issue 7 , July 2009 , pp. 2185 - 2190
Copyright
Copyright © Materials Research Society 2009

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1Schlapbach, L. and Züttel, A.: Hydrogen-storage materials for mobile applications. Nature 414, 353 (2001)CrossRefGoogle ScholarPubMed
2Kojima, Y., Akihiko Koiwai, Y., Suzuki, N., Haga, T., Hioki, T., and Tange, K.: Hydrogen adsorption and desorption by carbon materials. J. Alloys Compd. 421, 204 (2006)CrossRefGoogle Scholar
3Amendola, S.C., S.L. Sharp-Goldman, Janjua, M.S., Kelly, M.T., Petillo, P.J., and Binder, M.: An ultrasafe hydrogen generator: Aqueous, alkaline borohydride solutions and Ru catalyst. J. Power Sources 85, 186 (2000)CrossRefGoogle Scholar
4Züttel, A., Wenger, P., Rentsch, S., Sudan, P., Mauron, Ph., and Emmenegger, Ch.: LiBH4 a new hydrogen storage material. J. Power Sources 118, 1 (2003)CrossRefGoogle Scholar
5Bogdanovic, B. and Schwickardi, M.: Ti-doped alkali metal aluminium hydrides as potential novel reversible hydrogen-storage materials. J. Alloys Compd. 253–254, 1 (1997)CrossRefGoogle Scholar
6Chen, P., Xiong, Z., Luo, J., Lin, J., and Tan, K.L.: Interaction of hydrogen with metal nitrides and imides. Nature 420, 302 (2002)CrossRefGoogle ScholarPubMed
7Luo, W.: (LiNH2-MgH2): A viable hydrogen storage system. J. Alloys Compd. 381, 284 (2004)CrossRefGoogle Scholar
8Xiong, Z., Wu, G., Hu, J., and Chen, P.: Ternary imides for hydrogen storage. Adv. Mater. 16, 1522 (2004)CrossRefGoogle Scholar
9Leng, H.Y., Ichikawa, T., Hino, S., Hanada, N., Isobe, S., and Fujii, H.: New metal-N-H system composed of Mg(NH2)2 and LiH for hydrogen storage. J. Phys. Chem. B 108, 8763 (2004)CrossRefGoogle Scholar
10Nakamori, Y., Kitahara, G., Miwa, K., Towata, S., and Orimo, S.: Reversible hydrogen-storage functions for mixtures of Li3N and Mg3N2. Appl. Phys. A 80, 1 (2005)CrossRefGoogle Scholar
11Kojima, Y., Suzuki, K., Fukumoto, K., Kawai, Y., Kimbara, Y., Nakanishi, H., and Matsumoto, S.: Development of 10 kW-scale hydrogen generator using chemical hydride. J. Power Sources 125, 22 (2004)CrossRefGoogle Scholar
12Kojima, Y. and Haga, T.: Recycling process of sodium metaborate to sodium borohydride. Int. J. Hydrogen Energy 28, 989 (2003)CrossRefGoogle Scholar
13Yin, S.F., Xu, B.Q., Zhou, X.P., and Au, C.T.: A mini-review on ammonia decomposition catalysts for on-site generation of hydrogen for fuel-cell applications. Appl. Catal., A 277, 1 (2004)CrossRefGoogle Scholar
14Lide, D.R.: CRC Handbook of Chemistry and Physics, 84th ed. (CRC Press, New York, 2003–2004).Google Scholar
15Ichikawa, T., Isobe, S., Hanada, N., and Fujii, H.: Lithium nitride for reversible hydrogen storage. J. Alloys Compd. 365, 271 (2004)CrossRefGoogle Scholar
16Kahmer, T.M., McClune, W.F., Kabekkodu, S.N., and Clark, H.E.: PDF File (International Center for Diffraction Data, Swarthmore, PA, 2001).Google Scholar
17Oelerich, W., Klassen, T., and Borman, R.: Metal oxides as catalysts for improved hydrogen sorption in nanocrystalline Mgbased materials. J. Alloys Compd. 315, 237 (2001)CrossRefGoogle Scholar
18Hanada, N., Ichikawa, T., Hino, S., and Fujii, H.: Remarkable improvement of hydrogen sorption kinetics in magnesium catalyzed with Nb2O5. J. Alloys Compd. 420, 46 (2006)CrossRefGoogle Scholar
19Vajo, J.J., Skeith, S.L., and Mertens, F.: Reversible storage of hydrogen in destabilized LiBH4. J. Phys. Chem. B 109, 3719 (2005)CrossRefGoogle ScholarPubMed
20Williamson, G.K. and Hall, W.H.: X-ray line broadening from filled aluminium and wolfram. Acta Metall. 1, 22 (1953)CrossRefGoogle Scholar
21Miles, F.D.: The reaction between sodamide and hydrogen. Proc. R. Soc. Edinburgh 35, 134 (1915)CrossRefGoogle Scholar
22Leng, H.Y., Ichikawa, T., Hino, S., and Fujii, H.: Investigation of reaction between LiNH2 and H2. J. Alloys Compd. 463, 462 (2008)CrossRefGoogle Scholar
23Hino, S., Ichikawa, T., and Kojima, Y.: under preparation for publication.Google Scholar