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Microwave heating of soda-lime glass by addition of iron powder

Published online by Cambridge University Press:  31 January 2011

Noboru Yoshikawa*
Affiliation:
Graduate School of Environmental Studies, Tohoku University, Sendai, Japan 980-8579
Haichuan Wang
Affiliation:
Department of Metallurgy, Anhui University of Technology, Ma-Anshan, Anhui, People’s Republic of China
Ken-ichi Mashiko
Affiliation:
Tohoku University, Sendai, Japan 980-8579; and Graduate School of Environmental Studies, Tohoku University, Sendai, Japan 980-8579
Shoji Taniguchi
Affiliation:
Graduate School of Environmental Studies, Tohoku University, Sendai, Japan 980-8579
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

Experimental studies were conducted to investigate the microwave (MW) heating behavior of soda-lime glass beads with added iron powder. These studies were intended to obtain fundamental knowledge for vitrification solidification and for the fabrication of metal-reinforced glass-matrix composites. The glass beads (0.2 mm diameter) did not heat very well by themselves at temperatures greater than 200 °C within 600 s in a multimode applicator at a power of 0.67 W. The addition of iron powder (average 70 μm, volume fraction 18%) made it possible to heat the glass beads above 700 °C within 60 s. At lower fractions of 3–11 vol%, however, a sudden temperature rise [thermal runaway (TRW)] occurred after the incubation time period. A single-mode MW applicator was used for clarifying the electric (E)-field and magnetic (H)-field contributions to the heating of each material and their mixtures. The results of this study demonstrated that the H-field contributed to the heating of the iron and then triggered the heating of the glass. The E-field component is necessary for heating the glass to a temperature higher than 800 °C. The factors determining the threshold values of the volume fraction causing TRW are discussed.

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Articles
Copyright
Copyright © Materials Research Society 2008

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References

REFERENCES

1Jones, D.A., Lelyveld, T.P., Mavrofidis, S.D., Kingman, S.W.Miles, N.J.: Microwave heating applications in environmental engineering: A review. Resources Conserv. Recycl. 34, 75 2002CrossRefGoogle Scholar
2Oda, S.J.: Dielectric processing of hazardous materials: Present and future opportunities in Microwave Processing of Materials III,, edited by R.L Beatty, W.H. Sutton, and M.F. Iskander (Mater. Res. Soc. Symp. Proc. 269, Pittsburgh, PA, 1992), p. 453CrossRefGoogle Scholar
3Menéndez, J.A., Domínguez, A., Inguanzo, M.Pis, J.J.: Microwave-induced drying, pyrolysis and gasification (MWDPG) of swage sludge: Vitrification of the solid residue. J. Anal. Appl. Pyrolysis 74(1-2), 406 2005CrossRefGoogle Scholar
4Hua-Shan, T.Chih-Ju, G.J.: Immobilization of chromium-contaminated soil by means of microwave energy. J. Hazard. Mater. 65(3), 267 1999Google Scholar
5Dauerman, L., Windgasse, G., Gu, H., Ibrahim, N.Sedhom, E.H.: Application of microwave treatment of hazardous wastes: a) Non-volatile organics; b) Heavy metals in Microwave Processing of Materials II, edited by W.B. Snyder, Jr., W.H. Sutton, M.F. Iskander, and D.L. Johnson (Mater. Res. Soc. Symp. Proc. 189, Pittsburgh, PA, 1991), p. 61CrossRefGoogle Scholar
6Morita, K., Nguyen, V.Q., Nakaoka, R.Mackenzie, J.D.: Immobilization of ash by microwave melting in Microwave Processing of Materials III,, edited by R.L Beatty, W.H. Sutton, and M.F. Iskander (Mater. Res. Soc. Symp. Proc. 269, Pittsburgh, PA,, 1992), p. 471CrossRefGoogle Scholar
7Abramovitch, R.A., Chang-Qing, L., Hicks, E.Sinard, J.: In situ remediation of soils contaminated with toxic metal ions using microwave energy. Chemosphere 53, 1077 2003CrossRefGoogle ScholarPubMed
8Minay, E.J., Veronesi, P., Cannillo, V., Leonelli, C.Boccaccini, A.R.: Control of pore size by metallic fibres in glass matrix composite foams produced by microwave heating. J. Eur. Ceram. Soc. 24, 3203 2004CrossRefGoogle Scholar
9Minay, E.J., Boccaccini, A.R., Veronesi, P., Cannillo, V.Leonelli, C.: Processing of novel glass matrix composites by microwave heating.J. Mater. Proc. Technol.,155–156(30), 1749 2004CrossRefGoogle Scholar
10Clark, D.Sutton, W.H.: Microwave processing of materials. Annu. Rev. Mater. Sci. 26, 299 1996CrossRefGoogle Scholar
11Kingery, W.D., Bowen, H.K.Uhlmann, D.R.: Introduction to Ceramics 2nd ed. John Wiley and Sons New York 1975Google Scholar
12Roy, R., Peelamedu, R., Hurtt, L., Cheng, J.Agrawal, D.: Definitive experimental evidence for microwave effects: Radically new effects of separated E and H fields, such as decrystallization of oxides in seconds. Mater. Res. Innovat. 6, 128 2002CrossRefGoogle Scholar
13Cheng, J., Roy, R.Agrawal, D.: Experimental proof of major role of magnetic field losses in microwave heating of metallic composites. J. Mater. Sci. Lett. 20, 1561 2001CrossRefGoogle Scholar
14Yoshikawa, N., Ishizuka, E.Taniguchi, S.: Heating of metal particles in a single-mode microwave applicator. Mater. Trans. 47(3), 898 2006CrossRefGoogle Scholar
15Material, Committee on Microwave Processing of: Microwave processing of materials in An Emerging Industrial Technology edited by Committee on Microwave Processing of Material National Academy Press Washington, DC 1994 36Google Scholar
16Kenkre, V.M., Skala, L.Weiser, M.W.: Theory of microwave interactions in ceramic materials: The phenomenon of thermal runaway. J. Mater. Sci. 26, 2483 1991CrossRefGoogle Scholar
17Von Hippel, A.R.: Dielectric Materials and Applications MIT Press Cambridge, MA 1954 404Google Scholar