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Microstructure and Chemistry of Annealed Al–Cu–Fe–Cr Quasicrystalline Approximant Coatings

Published online by Cambridge University Press:  03 March 2011

M.J. Daniels ,
J.S. Zabinski ,
H. Wu ,
C.R.M. Grovenor  and
J.C. Bilello
M.J. Daniels*
Affiliation:
Center for Nanomaterials Science, Department of Materials Science and Engineering,University of Michigan, Ann Arbor, Michigan 48109-2136
J.S. Zabinski
Affiliation:
Air Force Research Laboratory, Wright-Patterson Air Force Base, Dayton, Ohio 45433
H. Wu
Affiliation:
School of Engineering, Coventry University, Coventry CV1 5FB, United Kingdom
C.R.M. Grovenor
Affiliation:
Department of Materials, University of Oxford, Oxford OX1 3PH, United Kingdom
J.C. Bilello
Affiliation:
Center for Nanomaterials Science, Department of Materials Science and Engineering,University of Michigan, Ann Arbor, Michigan 48109-2136
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

An as-deposited Al–Cu–Fe–Cr film was annealed in flowing argon to study development of a quasicrystalline approximant microstructure. Sputter profile x-ray photoemission spectroscopy analysis showed oxygen incorporation reached approximately 70 at.% at the surface of the film, declined monotonically, and stabilized at ∼10 at.% at a depth of 160 nm. Synchrotron grazing incidence x-ray scattering was used to probe the structure of the coating at various penetration depths by altering the angle of the incident x-ray beam. An amorphous structure was observed near the termination surface, which coexisted with a compressively strained crystalline aluminum. These phases were the dominant microstructure to a depth of 110 nm. Below 150 nm, the film was primarily O1 decagonal approximant. Cross-section transmission electron microscopy elucidated a columnar growth morphology with associated porosity in the interstices between the columns. The resulting development of the Al–Cu–Fe–Cr decagonal approximant coatings from the precursor is reported.

Keywords

AnnealingPhysical vapor deposition (PVD)Quasicrystal
Type
Articles
Information
Journal of Materials Research , Volume 20 , Issue 1 , January 2005 , pp. 176 - 182
Copyright
Copyright © Materials Research Society 2004

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