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Measurements of mechanical properties of α-phase in Cu–Sn alloys by using instrumented nanoindentation

Published online by Cambridge University Press:  23 September 2011

Yang Li ,
Kang He ,
Chengwei Liao  and
Chunxu Pan
Yang Li
Affiliation:
School of Physics and Technology and Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education, Wuhan University, Wuhan, 430072, China
Kang He
Affiliation:
School of Physics and Technology and Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education, Wuhan University, Wuhan, 430072, China
Chengwei Liao
Affiliation:
School of Physics and Technology and Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education, Wuhan University, Wuhan, 430072, China
Chunxu Pan*
Affiliation:
School of Physics and Technology and Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education, Wuhan University, Wuhan, 430072, China; and Center for Archaeometry, Wuhan University, Wuhan, 430072, China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

Instrumented nanoindentation technique is a powerful approach for accurately measuring mechanical properties of materials in micron or even nanoscale. In this article, the effect of tin (Sn) content upon mechanical properties of the α-phase in Cu–Sn alloys was studied by using an instrumented nanoindentation. The experimental results revealed that: (i) the hardness of the α-phase exhibited a linear relationship with Sn content (C) increasing, i.e., H = 0.0757C + 0.8916, when it was less than the maximum solid solubility (15.8 wt.%), which is in good agreement with the Friedel–Mott–Suzuki theory; (ii) the variation of Young’s modulus in a narrow range of 120–130 GPa is attributed to orientation variation of the α-phase in casting Cu–Sn dendrites.

Keywords

NanoindentationAlloyHardness
Type
Articles
Information
Journal of Materials Research , Volume 27 , Issue 1: Focus Issue: Instrumented Indentation , 14 January 2012 , pp. 192 - 196
Copyright
Copyright © Materials Research Society 2011

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References

REFERENCES

1.Gordon, R. and Knopf, R.: Metallurgy of bronze used in tools from Machu Picchu, Peru. Archaeometry 48, 57 (2006).CrossRefGoogle Scholar
2.Park, J.S., Park, C.W., and Lee, K.J.: Implication of peritectic composition in historical high-tin bronze metallurgy. Mater. Charact. 60, 1268 (2009).CrossRefGoogle Scholar
3.Joseph, R.D.: Copper and Copper Alloys. (ASM International. Handbook Committee, 2001), pp. 44–46.Google Scholar
4.Selver, R. and Varol, R.: Some thermal and physical characteristics of sintered tin bronze bearings. Metall. 57, 28 (2002).Google Scholar
5.Ünlüa, B.S. and Atik, E.: Evaluation of effect of alloy elements in copper based CuSn10 and CuZn30 bearings on tribological and mechanical properties. J. Alloy. Comp. 489, 262 (2010).CrossRefGoogle Scholar
6.He, T.K.: Synthetic study on the alloying technique for bronze in the pre-QIN period. Studies in the History of Natural Sciences 16, 273 (1997) (Article in Chinese, Abstract in English).Google Scholar
7.Scott, D.A.: Metallography and Microstructure of Ancient and Historic Metals. (The Getty Conservation Institute J. Paul Getty Museum, Malibu CA, 1991), p. 121.Google Scholar
8.Audy, J. and Audy, K.: Analysis of bell materials: Tin bronzes. China Foundry 5, 199 (2008).Google Scholar
9.Pethicai, J.B., Hutchings, R., and Oliver, W.C.: Hardness measurement at penetration depths as small as 20 nm. Philos. Mag. A 48, 593 (1983).CrossRefGoogle Scholar
10.Oliver, W.C. and Pharr, G.M.: An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments. J. Mater. Res. 7, 1564 (1992).CrossRefGoogle Scholar
11.Li, X.D. and Bhushan, B.: A review of nanoindentation continuous stiffness measurement technique and its applications. Mater. Charact. 48, 11 (2002).CrossRefGoogle Scholar
12.Oliver, W.C. and Pharr, G.M.: Measurement of hardness and elastic modulus by instrumented indentation: Advances in understanding and refinements to methodology. J. Mater. Res. 19, 3 (2004).CrossRefGoogle Scholar
13.Riede, F. and Wheeler, J.M.: Testing the “Laacher See hypothesis”: Tephra as dental abrasive. J. Archaeol. Sci. 36, 2384 (2009).CrossRefGoogle Scholar
14.Darnell, L.A., Teaford, M.F., Livi, K.J.T., and Weihs, T.P.: Variations in the mechanical properties of Alouatta palliata molar enamel. Am. J. Phys. Anthropol. 141, 7 (2010).CrossRefGoogle ScholarPubMed
15.Sanson, G.D., Kerr, S.A., and Gross, K.A.: Do silica phytoliths really wear mammalian teeth? J. Archaeol. Sci. 34, 526 (2007).CrossRefGoogle Scholar
16.Lerner, H., Du, X.D., Costopoulos, A., and Ostoja-Starzewski, M.: Lithic raw material physical properties and use-wear accrual. J. Archaeol. Sci. 34, 711 (2007).CrossRefGoogle Scholar
17.Fleischer, R. and Hibbard, W.: The Relation Between Structure and Mechanical Properties of Metals, Vol. 1. (H.M.S.O., London, 1963), p. 262.Google Scholar
18.Mott, N. and Nabarro, F.: Report on the Strength of Solids. (Physical Society, London, 1948), pp. 1–19.Google Scholar
19.Mott, N.: Imperfections in Nearly Perfect Crystals. (John Wiley, New York, 1952), p. 173.Google Scholar
20.Nabarro, F.: Dislocations and Properties of Real Materials. (The Institute of Metals, London, 1985), p. 152.Google Scholar
21.Friedel, J.: Dislocations. (Addison-Wesley, New York, 1964), p. 224.Google Scholar
22.Suzuki, T., Takeuchi, S., and Yoshinaga, H.: Dislocation Dynamics and Plasticity. (Springer-Verlag, Berlin Heidelberg, 1991), p. 32.CrossRefGoogle Scholar
23.Schmidt, E. and Boas, W.: Plasticity of Crystals, English Translation. (Hughes and Co., London, 1950), p.191.Google Scholar
24.Dub, S.N., Lim, Y.Y., and Chaudhri, M.M.: Nanohardness of high purity Cu (111) single crystals: The effect of indenter load and prior plastic sample strain. J. Appl. Phys. 107, 043510 (2010).CrossRefGoogle Scholar
25.ISO 1577-1: “Metallic materials-Instrumented indentation test for hardness and materials parameter-Test method.” (ISO Central Secretariat, Geneva, Switzerland, 2002).Google Scholar
26.Chen, J. and Lai, Y.S.: Towards elastic anisotropy and strain-induced void formation in Cu-Sn crystalline phases. Microelectron. Reliab. 49, 264 (2009).CrossRefGoogle Scholar
27.An, R., Wang, C.Q., Tian, Y.H., and Wu, H.: Determination of the elastic properties of Cu3Sn through first-principles calculations. J. Electron. Mater. 37(4), 477 (2008).CrossRefGoogle Scholar
28.Guo, Z.D., Wang, X.F., Yang, X.P., Jiang, D.M., Ma, X.M., and Song, H.W.: Relationships between young’s modulus, hardness and orientation of grain in polycrystalline copper. Acta Metall. Sin. 44, 901 (2008).Google Scholar