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Materials-structure-property correlation study of spark plasma sintered AlCuCrFeMnWx (x = 0, 0.05, 0.1, 0.5) high-entropy alloys

Published online by Cambridge University Press:  04 March 2019

Devesh Kumar ,
Vishnu K. Sharma ,
Y.V.S.S. Prasad  and
Vinod Kumar Open the ORCID record for Vinod Kumar [Opens in a new window]
Devesh Kumar
Affiliation:
Department of Metallurgical and Materials Engineering, Malaviya National Institute of Technology (MNIT)Jaipur, 302017, India Department of Mechanical Engineering Jaipur Engineering College and Research Centre (JECRC), Jaipur 302017, India
Vishnu K. Sharma
Affiliation:
Department of Metallurgical and Materials Engineering, Malaviya National Institute of Technology (MNIT)Jaipur, 302017, India
Y.V.S.S. Prasad
Affiliation:
Department of Metallurgical and Materials Engineering, Malaviya National Institute of Technology (MNIT)Jaipur, 302017, India
Vinod Kumar*
Affiliation:
Discipline of Metallurgy and Materials Science, Indian Institute of Technology (IIT)Indore, 453552, India
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

A novel series of nanocrystalline AlCuCrFeMnWx (x = 0, 0.05, 0.1, 0.5) high-entropy alloys (HEAs) were synthesized by mechanical alloying followed by spark plasma sintering. The phase evolution of the current HEAs was studied using X-ray diffraction (XRD), transmission electron microscopy, and selected area electron diffraction. The XRD of the AlCuCrFeMn sintered HEA shows evolution of ordered B2 phase (AlFe type), sigma phase (Cr rich), and FeMn phase. AlCuCrFeMnWx (x = 0.05, 0.1, 0.5 mol) shows formation of ordered B2 phases, sigma phases, FeMn phases, and BCC phases. Micro-hardness of the AlCuCrFeMnWx samples was measured by Vickers microindentation and the maximum value observed is 780 ± 12 HV. As the tungsten content increases, the fracture strength under compression increases from 1010 to 1510 MPa. Thermodynamic parameters of present alloys confirm the crystalline phase formation, and finally structure–property relationship was proposed by conventional strengthening mechanisms.

Keywords

nanocrystallinediffractionhigh-entropy alloy
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 5: Focus Issue: Nanocrystalline High Entropy Materials: Processing Challenges and Properties , 14 March 2019 , pp. 767 - 776
Copyright
Copyright © Materials Research Society 2019 

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References

Murty, B.S., Yeh, J.W., and Ranganathan, S.: High-Entropy Alloy, 1st ed. (Elsevier Inc., London, 2014).CrossRefGoogle Scholar
Yeh, J.W.: Recent progress in high-entropy alloys. Ann. Chimie Sci. Matériaux 31, 633–648 (2006).CrossRefGoogle Scholar
Yeh, J.W., Chen, S.K., Gan, J.Y., Lin, S.J., Chin, T.S., Shun, T.T., Tsau, C.H., and Chang, S.Y.: Formation of simple crystal structures in Cu–Co–Ni–Cr–Al–Fe–Ti–V alloys with multiprincipal metallic elements. Metall. Mater. Trans. A 35, 2533–2536 (2004).CrossRefGoogle Scholar
Maulik, O., Kumar, D., Kumar, S., Fabijanic, D.M., and Kumar, V.: Structural evolution of spark plasma sintered AlFeCuCrMgx (x = 0, 0.5, 1, 1.7) high entropy alloys. Intermetallics 77, 46–56 (2016).CrossRefGoogle Scholar
Hemphill, M.A., Yuan, T., Wang, G.Y., Yeh, J.W., Tsai, C.W., Chuang, A., and Liaw, P.K.: Fatigue behavior of Al0.5CoCrCuFeNi high entropy alloys. Acta Mater. 60, 5723–5734 (2012).CrossRefGoogle Scholar
Yao, H.W., Qiao, J.W., Gao, M.C., Hawk, J.A., Ma, S.G., Zhou, H.F., and Zhang, Y.: NbTaV–(Ti, W) refractory high-entropy alloys: Experiments and modeling. Mater. Sci. Eng., A 674, 203–211 (2016).CrossRefGoogle Scholar
Miracle, D.B.: Critical assessment 14: High entropy alloys and their development as structural materials. Mater. Sci. Technol. 31, 1142–1147 (2015).CrossRefGoogle Scholar
Pickering, E.J. and Jones, N.G.: High-entropy alloys: A critical assessment of their founding principles and future prospects. Int. Mater. Rev. 61, 183–202 (2016).CrossRefGoogle Scholar
Han, Z.D., Luan, H.W., Liua, X., Chen, N., Li, X.Y., Shao, Y., and Yao, K.F.: Microstructures and mechanical properties of TixNbMoTaW refractory high entropy alloys. Mater. Sci. Eng., A 712, 380–385 (2018).CrossRefGoogle Scholar
Yao, H.W., Qiao, J.W., Hawk, J.A., Zhou, H.F., Chen, M.W., and Gao, M.C.: Mechanical properties of refractory high-entropy alloys: Experiments and modeling. J. Alloys Compd. 696, 1139–1150 (2017).CrossRefGoogle Scholar
Jiang, H., Jiang, L., Han, K., Lu, Y., Wang, T., Cao, Z., and Li, T.: Effects of tungsten on microstructure and mechanical properties of CrFeNiV0.5Wx and CrFeNi2V0.5Wx high-entropy alloys. J. Mater. Eng. Perform. 24, 4594–4600 (2015).CrossRefGoogle Scholar
Xian, X., Lin, L., Zhong, Z., Zhang, C., Chen, C., Song, K., Cheng, J., and Wu, Y.: Precipitation and its strengthening of Cu-rich phase in CrMnFeCoNiCux high-entropy alloys. Mater. Sci. Eng., A 713, 134–140 (2018).CrossRefGoogle Scholar
Zhang, L.J., Yu, P.F., Zhang, M.D., Liu, D.J., Zhou, Z., Ma, M.Z., Liaw, P.K., Lia, G., and Liu, R.P.: Microstructure and mechanical behaviors of GdxCoCrCuFeNi high-entropy alloys. Mater. Sci. Eng., A 707, 708–716 (2017).CrossRefGoogle Scholar
Chen, X., Sui, Y., Qi, J., He, Y., Wei, F., Meng, Q., and Sun, Z.: Microstructure of Al1.3CrFeNi eutectic high entropy alloy and oxidation behavior at 1000 °C. J. Mater. Res. 32, 2109–2116 (2017).CrossRefGoogle Scholar
Kumar, D., Maulik, O., Kumar, S., Prasad, Y.V.S.S., and Kumar, V.: Phase and thermal study of equiatomic AlCuCrFeMnW high entropy alloy processed via spark plasma sintering. Mater. Chem. Phys. 210, 71–77 (2018).CrossRefGoogle Scholar
Khodabakhshi, F., Haghshenas, M., Eskandari, H., and Koohbor, B.: Hardness-strength relationships in fine and ultra-fine grained metals processed through constrained groove pressing. Mater. Sci. Eng., A 636, 331–339 (2015).CrossRefGoogle Scholar
Takeuchi, A. and Inoue, A.: Calculations of mixing enthalpy and mismatch entropy for ternary amorphous alloys. Mater. Trans. JIM 41, 1372–1378 (2000).CrossRefGoogle Scholar
Zhang, Y., Zuo, T.T., Tang, Z., Gao, M.C., Dahmen, K.A., Liaw, P.K., and Lu, Z.P.: Microstructure and properties of high-entropy alloy. Prog. Mater. Sci. 61, 1–93 (2014).CrossRefGoogle Scholar
Guo, S., Ng, C., Lu, J., and Liu, C.T.: Effect of valence electron concentration on stability of fcc and bcc phase in high entropy alloy. J. Appl. Phys. 109, 103505 (2011).CrossRefGoogle Scholar
Dong, Y., Lu, Y., Jiang, L., Wang, T., and Li, T.: Effects of electronegativity on the stability of topologically closed packed phase in high entropy alloy. Intermetallics 52, 105e109 (2014).CrossRefGoogle Scholar
Kumar, D., Maulik, O., Kumar, S., Prasad, Y.V.S.S., Sharma, V.K., and Kumar, V.: Impact of tungsten on phase evolution in nanocrystalline AlCuCrFeMnWx (x = 0, 0.05, 0.1, and 0.5 mol) high entropy alloys. Mater. Res. Express 4, 114004 (2018).CrossRefGoogle Scholar
Tsai, M.H., Tsai, K.Y., Tsai, C.W., Lee, C., Juan, C.C., and Yeh, J.W.: Criterion for sigma phase formation in Cr- and V-containing high entropy alloys. Mater. Res. Lett. 1, 207–212 (2013).CrossRefGoogle Scholar
Tabor, D.: The hardness and strength of metals. J. Inst. Met. 79, 1–18 (1951).Google Scholar
Ganji, R.S., Karthik, P.S., Rao, K.B.S., and Rajulapati, K.V.: Strengthening mechanisms in equiatomic ultrafine grained AlCoCrCuFeNi high-entropy alloy studied by micro- and nanoindentation methods. Acta Mater. 125, 58–68 (2017).CrossRefGoogle Scholar
Sriharitha, R., Murty, B.S., and Kottada, R.S.: Alloying, thermal stability and strengthening in spark plasma sintered AlxCoCrCuFeNi high entropy alloys. J. Alloys Compd. 583, 419–426 (2014).CrossRefGoogle Scholar
Williamson, G.K. and Smallman, R.E.: Dislocation densities in some annealed and cold-worked metals from measurements on the X-ray debye-scherrer spectrum. Philos. Mag. 1, 34–46 (1956).CrossRefGoogle Scholar
Labusch, R.: Statistical theories of solid solution hardening. Acta Metall. 20, 917–927 (1972).CrossRefGoogle Scholar
Senkov, O.N., Scott, J.M., Senkova, S.V., Meisenkothen, F., Miracle, D.B., and Woodward, C.F.: Microstructure and elevated temperature properties of a refractory TaNbHfZrTi alloy. J. Mater. Sci. 47, 4062–4074 (2012).CrossRefGoogle Scholar
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