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Intercalation of cyclic amines in α–hafnium bis(hydrogen phosphate) monohydrate

Published online by Cambridge University Press:  31 January 2011

M. Suáarez ,
R. Llavona ,
M. L. Rodríguez ,
L. M. Barcina ,
A. Anillo  and
J. Rodríguez
M. Suáarez
Affiliation:
Departamento de Quimica Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain
R. Llavona
Affiliation:
Departamento de Quimica Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain
M. L. Rodríguez
Affiliation:
Departamento de Quimica Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain
L. M. Barcina
Affiliation:
Departamento de Quimica Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain
A. Anillo
Affiliation:
Departamento de Quimica Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain
J. Rodríguez*
Affiliation:
Departamento de Quimica Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain
*
a) Author correspondence to this addressed.
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Abstract

The intercalation in vapor phase of cyclic amines (aniline, benzylamine, cyclohexylamine, piperidine, and pyridine) in α–hafnium bis(hydrogen phosphate) monohydrate (α–HfP) has been investigated. Elemental and thermal analysis lead to the establishment of the intercalate composition. The general formula is x[Hf(HPO4)2 · y amine H2O] (1 - x) α–HfP where y = 2, 1 and x ≤ 1. When y = 1 (piperidine and pyridine) the amines form a monomolecular layer. When y = 2 (aniline, benzylamine, and cyclohexylamine) the arrangement is bimolecular. The results are compared to those described for α–ZrP.

Type
Articles
Information
Journal of Materials Research , Volume 13 , Issue 5 , May 1998 , pp. 1218 - 1224
Copyright
Copyright © Materials Research Society 1998

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References

1.Clearfield, A., Inorganic Ion Exchange Materials (CRC Press, Boca Raton, FL, 1982).Google Scholar
2.Alberti, G. and Costantino, U., Inclusion Compounds. Vol. 5. Inorganic and Physical Aspects of Inclusion (Oxford University Press, Oxford, 1991).Google Scholar
3.Clearfield, A., Design of New Materials (Plenum Press, New York, 1987).Google Scholar
4.Alberti, G., Recent Developments in Ion Exchange (Elsevier, Amsterdam, 1987).Google Scholar
5.Clearfield, A., Kuchenmeister, M., Wade, K., and Sylvester, P., Pillaring of Layered Inorganic Compounds: Fundamentals, Synthesis of Microporous Materials. Vol. II, Expanded Clays and Other Microporous Solids, edited by Occelli, M. L. and Robson, H. E. (Van Nostrand Reinhold, New York, 1992), Chap. 12.Google Scholar
6.García, J. R., Llavona, R., Su'arez, M., and Rodríguez, J., J. Trends Inorg. Chem. 3, 209 (1993).Google Scholar
7.Clearfield, A., Chem. Rev., 88, 125 (1988).CrossRefGoogle Scholar
8.Clearfield, A., Mesoporous Pillared Layered Materials, edited by Sequeire, C. A. C. and Hudson, M. J., Multifuntional Mesoporous Inorganic Solids (Kluwer Academic Publishers, The Netherlands, 1993).CrossRefGoogle Scholar
9.Clearfield, A., Intercalation Chemistry of Selected Layered Oxides and Phosphates, edited by Muller-Warmuty, W. and Schöllhorn, R., Progress in Intercalation Research (Kluwer Academic Publishers, The Netherlands, 1994).CrossRefGoogle Scholar
10.Clearfield, A. and Costantino, U., Layered Metal Phosphates and Their Intercalation Chemistry, edited by Alberti, G. and Bein, T. (Pergamon Press, New York, 1996).Google Scholar
11.García, J. R., Suárez, M., Llavona, R., and Rodríguez, J., J. Chem. Soc. Dalton Trans., 2605 (1984).CrossRefGoogle Scholar
12.Alvarez, C., Llavona, R., García, J. R., Suárez, M., and Rodríguez, J., Inorg. Chem. 26, 1045 (1987).CrossRefGoogle Scholar
13.Llavona, R., Suárez, M., García, J. R., and Rodríguez, J., Inorg. Chem. 28, 2863 (1989).CrossRefGoogle Scholar
14.Clearfield, A. and Tindwa, R. M., J. Inorg. Nucl. Chem. 41, 871 (1979).CrossRefGoogle Scholar
15.Menéendez, A., Bárcena, M., Jaimez, E., García, J. R., and Rodríguez, J., J. Chem. Mater. 5, 1078 (1993).CrossRefGoogle Scholar
16.Herzog-Cance, M. H., Jones, D. J., Meijad, R. El, Roziere, J., and Tomkinson, J., J. Chem. Soc. Faraday Trans. 88, 2275 (1992).CrossRefGoogle Scholar
17.Costantino, U., J. Inorg. Nucl. Chem. 43, 1895 (1981).CrossRefGoogle Scholar
18.Ding, Y., Jones, D. J., Marielles-Torres, P., and Roziere, J., Chem. Mater. 7, 3 (1995).CrossRefGoogle Scholar
19.Kijima, T. and Cleno, S., J. Chem. Soc. Dalton Trans., 61 (1986).CrossRefGoogle Scholar
20.Behrendt, D., Beneke, K., and Lagaly, G., Angew. Chem. Int. 15, 544 (1976).CrossRefGoogle Scholar
21.Costantino, U., J. Chem. Soc. Dalton Trans., 402 (1975).Google Scholar
22.Johnson, J. W., J. Chem. Soc. Chem. Commun., 263 (1980).CrossRefGoogle Scholar
23.Mairelles-Torres, P., Olivera-Pastor, P., Rodriguez-Castellon, E., Jimenez-Lopez, A., and Tomlinson, A., J. Mater. Chem. 1, 739 (1991).CrossRefGoogle Scholar
24.Clearfield, A. and Roberts, B. D., Inorg. Chem. 27, 3237 (1988).CrossRefGoogle Scholar
25.Espina, A., Parra, J. B., García, J. R., Pajares, J. A., and Rodríguez, J., J. Mat. Chem. Phys. 35, 250 (1993).CrossRefGoogle Scholar
26.Menéndez, F., Espina, A., Trobajo, C., and Rodríguez, J., J. Mater. Res. Bull. 25, 1531 (1990).CrossRefGoogle Scholar
27.Casciola, M., Costantino, U., Croce, L. di, and Marmotini, F., J. Incl. Phenom. 6, 291 (1988).CrossRefGoogle Scholar
28.Tomita, I., Magami, K., Watanabe, H., Suzuki, K., and Nakamura, T., Bull. Chem. Soc. Jpn. 56, 3186 (1983).CrossRefGoogle Scholar
29.Tomita, I., Banju, M., Noguchi, K., and Nakamura, T., Bull. Chem. Soc. Jpn. 57, 3281 (1984).CrossRefGoogle Scholar
30.Rodríguez, M. L., Suárez, M., García, J. R., and Rodríguez, J., J. Solid State Ionics 63, 488 (1993).CrossRefGoogle Scholar
31.Costantino, U., Massucci, M. A., Ginestra, A. La, Tarola, A. M., and Zampa, L., J. Incl. Phenom. 4, 147 (1986).CrossRefGoogle Scholar
32.Behrendt, D., Beneke, K., and Lagaly, G., Angew. Chem., Int. De. Engl. 15, 544 (1976).CrossRefGoogle Scholar
33.Alberti, G., Cardini-Galli, P., Costantino, U., and Torracca, E., J. Inorg. Nucl. Chem. 29, 571 (1967).CrossRefGoogle Scholar
34.Kolthoff, M., Sandell, E. B., Meehan, E. J., and Bruckenstein, S., Quantitative Chemical Analysis (Nigar, Buenos Aires, 1972).Google Scholar
35.Cheron, B. and Sandorfy, C., Can. J. Chem. 36, 1958 (1958).Google Scholar
36.Troup, V. M. and Clearfield, A., Inorg. Chem. 16, 3311 (1977).CrossRefGoogle Scholar
37.Bellamy, L. J., The Infrared Spectra of Complex Molecules (Chapman and Hall, New York, 1975).CrossRefGoogle Scholar
38.Yamanaka, S., Oribe, Y., and Tanaka, M., J. Inorg. Nucl. Chem. 38, 323 (1976).CrossRefGoogle Scholar
39.Kijima, T., Thermochim. Acta 59, 95 (1982).CrossRefGoogle Scholar