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Improved thermal properties of Al powders coated with submicron-sized hollow nickel particles

Published online by Cambridge University Press:  31 January 2011

Jialiang Cheng ,
Huey H. Hng ,
Hsiao Y. Ng ,
Pei C. Soon  and
Yiew W. Lee
Huey H. Hng*
Affiliation:
School of Materials Science & Engineering, Division of Materials Science, Nanyang Technological University, Singapore 639798, Singapore
Yiew W. Lee
Affiliation:
DSO National Laboratories, Singapore 11, Singapore
*
a) Address all correspondence to this author. e-mail: [email protected]
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Abstract

This work investigates the coating of nano- to submicron-sized hollow nickel particles onto Al powders to optimize the thermal and combustion properties of Al-based energetic materials. Different wt% of hollow nickel particles coated onto Al particles was synthesized using an autocatalytic aqueous reduction method. X-ray diffraction results showed distinct crystalline Al and Ni phases indicating that a pure coating process was achieved. Homogeneous coating of hollow nickel particles onto individual Al particles was also reflected from the scanning electron microscope images. All the samples showed significant improvements in terms of their ignition and kinetics of combustion as compared to untreated Al. The most promising candidate produced was the 30wt%Ni–Al sample whereby the %complete combustion of Al exhibited the largest improvement. The hollow Ni-coated Al samples were also found to perform better than their physically mixed Ni–Al powder samples, as there is more intimate contact between the two components to hasten the overall combustion kinetics.

Keywords

AlEnergetic materialNi
Type
Articles
Information
Journal of Materials Research , Volume 24 , Issue 10 , October 2009 , pp. 3220 - 3225
Copyright
Copyright © Materials Research Society 2009

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References

1.Pokhil, P.F., Belyayev, A.F., Frolov, V.Y., Logachev, V.S., and Korotkov, A.I.: Combustion of Powdered Metals in Active Media (Foreign Defense Technical Information Center, VA, 1972).Google Scholar
2.Price, E.W.: Fundamentals of Solid-Propellant Combustion, Progress in Aeronautics and Astronautics, edited by Kuo, K. and Sommerfield, M. (AIAA, New York, 1984), p. 479.Google Scholar
3.Dokhan, A., Price, E.W., Seitzman, J.M., and Sigman, R.K.: The effects of bimodal aluminum with ultrafine aluminum on the burning rates of solid propellants. Proc. Combust. Inst. 29(2), 2939 (2002).Google Scholar
4.Breitler, A.L., Mal'tsev, V.M., and Popov, E.I.: Means of modifying metallic fuel in condensed systems. Combust. Explos. Shock Waves 26, 86 (1990).CrossRefGoogle Scholar
5.Thiers, L., Mukasyan, A.S., and Varma, A.: Thermal explosion in Ni–Al system: Influence of reaction medium microstructure. Combust. Flame 131, 198 (2002).Google Scholar
6.Akhatov, I., Vakhitova, N., Topolnikov, A., Zakirov, K., Wolfrum, B., Kurz, T., Lindau, O., Mettin, R., and Lauterborn, W.: Dynamics of laser-induced cavitation bubbles. Exp. Therm. Fluid Sci. 26(6–7), 731 (2002).Google Scholar
7.Gong, C. and Douglas, P.H.: Ultrasound induced sonochemical yield. J. Acoust. Soc. Am. 104, 2675 (1998).Google Scholar
8.Deng, Y.D., Liu, X., Shen, B., Liu, L., and Hu, W.B.: Preparation and microwave characterization of submicrometer-sized hollow nickel spheres. J. Magn. Magn. Mater. 303, 181 (2006).Google Scholar
9.Trunov, M.A., Schoenitz, M., Zhu, X., and Dreizin, E.L.: Effect of polymorphic phase transformations in alumina layer on ignition of aluminum particles. Combust. Flame 104, 310 (2005).Google Scholar
10.Kwon, Y-S., Moon, J-S., Ilyin, A.P., Gromov, A.A., and Popenko, E.M.: Estimation of the reactivity of aluminum superfine powders for energetic applications. Combust. Sci. Technol. 176(2), 277 (2004).Google Scholar
11.Cheng, J.L., Hng, H.H., Ng, H.Y., Soon, P.C., and Lee, Y.W.: Deposition of nickel nanoparticles onto aluminum powders using a modified polyol process. Mater. Res. Bull. 44, 95 (2009).Google Scholar
12.Curfs, C., Turrillas, X., Vaughan, G.B.M., Terry, A.E., Kvick, Å., and Rodríguez, M.A.: AlNi intermetallics obtained by SHS: A timeresolved x-ray diffraction study. Intermetallics 15, 1163 (2007).CrossRefGoogle Scholar
13.Chrifi-Alaoui, F.Z., Nassik, M., Mahdouk, K., and Gachon, J.C.: Enthalpies of formation of the Al–Ni intermetallic compounds. J. Alloys Compd. 364, 121 (2004).Google Scholar