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Improved mechanical performance and wear resistance of Ti-coated cBN–WC–Ni composites

Published online by Cambridge University Press:  22 October 2019

Changchun Lv ,
Xiaoyong Ren ,
Chengbiao Wang  and
Zhijian Peng Open the ORCID record for Zhijian Peng [Opens in a new window]
Changchun Lv
Affiliation:
School of Engineering and Technology, China University of Geosciences, Beijing 100083, People’s Republic of China; and School of Science, China University of Geosciences, Beijing 100083, People’s Republic of China
Xiaoyong Ren*
Affiliation:
School of Engineering and Technology, China University of Geosciences, Beijing 100083, People’s Republic of China; and School of Science, China University of Geosciences, Beijing 100083, People’s Republic of China
Chengbiao Wang
Affiliation:
School of Engineering and Technology, China University of Geosciences, Beijing 100083, People’s Republic of China
Zhijian Peng*
Affiliation:
School of Engineering and Technology, China University of Geosciences, Beijing 100083, People’s Republic of China; and School of Science, China University of Geosciences, Beijing 100083, People’s Republic of China
*
a)Address all correspondence to these authors. e-mail: [email protected]
b)e-mail: [email protected]
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Abstract

Composites of 0–20 vol% Ti-coated cBN (cBN@Ti) particles dispersed in WC–Ni were densified by spark plasma sintering under 50 MPa at 1300 °C. The cBN particles were distributed homogeneously with a Ti-rich interfacial layer between the cBN particles and WC–Ni matrix. Increasing cBN@Ti to 20 vol% decreased the sample densification, but all the composites were still >97.5% dense. The Vickers hardness and flexural strength initially increased and then decreased, reaching the maximum values of 1820 HV10 with 15 vol% cBN@Ti and 1500 MPa with 5 vol% cBN@Ti, respectively, whereas the fracture toughness KIC gradually increased from 8 to 13 MPa m1/2. For cutting rocks, the wear significantly decreased with 5–15 vol% cBN@Ti but increased with 20 vol% cBN@Ti because of cBN particles pull-out.

Keywords

WC–Ni cemented carbideTi-coated cBNspark plasma sinteringmechanical properties
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 22 , 28 November 2019 , pp. 3844 - 3852
Copyright
Copyright © Materials Research Society 2019 

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References

Vel, L., Demazeau, G., and Etourneau, J.: Cubic boron nitride: Synthesis, physicochemical properties and applications. Mater. Sci. Eng. B 10, 149 (1991).CrossRefGoogle Scholar
Monteiro, S.N., Skury, A.L.D., de Azevedo, M.G., and Bobrovnitchii, G.S.: Cubic boron nitride competing with diamond as a superhard engineering material—An overview. J. Mater. Res. Technol. 2, 68 (2013).CrossRefGoogle Scholar
Ding, W.F., Xu, J.H., Shen, M., Fu, Y., Xiao, B., Su, H.H., and Xu, H.J.: Development and performance of monolayer brazed cBN grinding tools. Int. J. Adv. Manuf. Technol. 34, 491 (2007).CrossRefGoogle Scholar
Cook, M.W. and Bossom, P.K.: Trends and recent developments in the material manufacture and cutting tool application of polycrystalline diamond and polycrystalline cubic boron nitride. Int. J. Refract. Met. Hard Mater. 18, 147 (2000).CrossRefGoogle Scholar
Ronning, C., Feldermann, H., and Hofsäss, H.: Growth, doping and application of cubic boron nitride thin films. Diamond Relat. Mater. 9, 1767 (2000).CrossRefGoogle Scholar
Yaman, B. and Mandal, H.: Wear performance of spark plasma sintered Co/WC and cBN/Co/WC composites. Int. J. Refract. Met. Hard Mater. 42, 9 (2014).CrossRefGoogle Scholar
Locci, A.M., Orru, R., and Ca, G.: Simultaneous spark plasma synthesis and consolidation of WC/Co composites. J. Mater. Res. 20, 734 (2005).CrossRefGoogle Scholar
Ren, X.Y., Miao, H.Z., and Peng, Z.J.: A review of cemented carbides for rock drilling: An old but still tough challenge in geo-engineering. Int. J. Refract. Met. Hard Mater. 39, 61 (2013).CrossRefGoogle Scholar
Prakash, L.J.: Application of fine grained tungsten carbide based cemented carbides. Int. J. Refract. Met. Hard Mater. 13, 257 (1995).CrossRefGoogle Scholar
Martínez, V. and Echeberria, J.: Hot isostatic pressing of cubic boron nitride–tungsten carbide/cobalt (cBN–WC/Co) composites: Effect of cBN particle size and some processing parameters on their microstructure and properties. J. Am. Ceram. Soc. 90, 415 (2007).CrossRefGoogle Scholar
Yaman, B. and Mandal, H.: Spark plasma sintering of Co–WC cubic boron nitride composites. Mater. Lett. 63, 1041 (2009).CrossRefGoogle Scholar
Rong, H.Y., Peng, Z.J., Ren, X.Y., Wang, C.B., Fu, Z.Q., Qi, L.H., and Miao, H.Z.: Microstructure and mechanical properties of ultrafine WC–Ni–VC–TaC–cBN cemented carbides fabricated by spark plasma sintering. Int. J. Refract. Met. Hard Mater. 29, 733 (2011).CrossRefGoogle Scholar
Wang, B., Matsumaru, K., Yang, J.F., Fu, Z.Y., and Ishizaki, K.: The effect of cBN additions on densification, microstructure and properties of WC–Co composites by pulse electric current sintering. J. Am. Ceram. Soc. 95, 2499 (2012).CrossRefGoogle Scholar
Rasiński, M. and Michalski, A.: WC/Co/cBN composites produced by pulse plasma sintering method. J. Mater. Sci. 47, 7064 (2012).CrossRefGoogle Scholar
Wang, B., Qin, Y., Jin, F., Yang, J.F., and Ishizaki, K.: Pulse electric current sintering of cubic boron nitride/tungsten carbide–cobalt (cBN/WC–Co) composites: Effects of cBN particle size and volume fraction on their microstructure and properties. Mater. Sci. Eng. A 607, 490 (2014).CrossRefGoogle Scholar
Mao, C., Zhang, M.J., Zhang, J., Tang, K., Gan, H.Y., and Zhang, G.F.: The effect of processing parameters on the performance of spark plasma sintered cBN–WC–Co composites. J. Mater. Eng. Perform. 24, 4612 (2015).CrossRefGoogle Scholar
Mao, C., Ren, Y.H., Gan, H.Y., Zhang, M.J., Zhang, J., and Tang, K.: Microstructure and mechanical properties of cBN–WC–Co composites used for cutting tools. Int. J. Adv. Manuf. Technol. 76, 2043 (2015).CrossRefGoogle Scholar
Michalski, A., Cymerman, K., and Rasiński, M.: Microstructure of the cBN/WC6Co composite produced by the pulse plasma sintering (PPS) method. Int. J. Refract. Met. Hard Mater. 50, 197 (2015).CrossRefGoogle Scholar
Solozhenko, V.L., Turkevich, V.Z., and Holzapfel, W.B.: Refined phase diagram of boron nitride. J. Phys. Chem. B 103, 2903 (1999).CrossRefGoogle Scholar
Hotta, M. and Goto, T.: Effect of time on microstructure and hardness of βSiAlON–cubic boron nitride composites during spark plasma sintering. Ceram. Int. 37, 521 (2011).CrossRefGoogle Scholar
Zhang, J.F., Tu, R., and Goto, T.: Densification of SiO2–cBN composites by using Ni nanoparticle and SiO2 nanolayer coated cBN powder. Ceram. Int. 38, 4961 (2012).CrossRefGoogle Scholar
Kitiwan, M., Ito, A., Zhang, J.F., and Goto, T.: Densification and mechanical properties of cBN–TiN–TiB2 composites prepared by spark plasma sintering of SiO2-coated cBN powder. J. Eur. Ceram. Soc. 34, 3619 (2014).CrossRefGoogle Scholar
Zhang, J.F., Tu, R., and Goto, T.: Spark plasma sintering of Al2O3–cBN composites facilitated by Ni nanoparticle precipitation on cBN powder by rotary chemical vapor deposition. J. Eur. Ceram. Soc. 31, 2083 (2011).CrossRefGoogle Scholar
Wang, Y., Qiu, X.M., Sun, D.Q., and Yin, S.Q.: Influence of Ti on microstructure and strength of c-BN/Cu–Ni–Sn–Ti composites. Int. J. Refract. Met. Hard Mater. 29, 293 (2011).CrossRefGoogle Scholar
Wang, Y., Lei, K., Ruan, Y., and Dong, W.: Microstructure and wear resistance of c-BN/Ni–Cr–Ti composites prepared by spark plasma sintering. Int. J. Refract. Met. Hard Mater. 54, 98 (2016).CrossRefGoogle Scholar
Yang, L.M., Gong, J.H., Yue, Z.M., and Chu, X.R.: Preparation and characterization of cBN-based composites from cBN–Ti3AlC2 mixtures. Diamond Relat. Mater. 66, 183 (2016).CrossRefGoogle Scholar
Ding, W.F., Xu, J.H., Shen, M., Fu, Y.C., and Xiao, B.: Behavior of titanium in the interfacial region between cubic BN and active brazing alloy. Int. J. Refract. Met. Hard Mater. 24, 432 (2006).CrossRefGoogle Scholar
Sudre, O. and Lange, F.F.: Effect of inclusions on densification: I, microstructural development in an Al2O3 matrix containing a high volume fraction of ZrO2 inclusions. J. Am. Ceram. Soc. 75, 519 (1992).CrossRefGoogle Scholar
Wang, L.J., Jiang, W., Chen, L.D., and Bai, G.Z.: Microstructure of Ti5Si3–TiC–Ti3SiC2 and Ti5Si3–TiC nanocomposites in situ synthesized by spark plasma sintering. J. Mater. Res. 19, 3004 (2004).CrossRefGoogle Scholar
Yan, G., Yue, W., Meng, D.Z., Lin, F., Wu, Z.Y., and Wang, C.B.: Wear performances and mechanisms of ultrahard polycrystalline diamond composite material grinded against granite. Int. J. Refract. Met. Hard Mater. 54, 46 (2016).CrossRefGoogle Scholar
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