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Hierarchical ZnO films with microplate/nanohole structures induced by precursor concentration and colloidal templates, their superhydrophobicity, and enhanced photocatalytic performance

Published online by Cambridge University Press:  03 July 2013

Zhigang Li ,
Guotao Duan ,
Guangqiang Liu ,
Zhengfei Dai ,
Jinlian Hu ,
Weiping Cai  and
Yue Li
Zhigang Li
Affiliation:
Department of Physics & Electronic Engineering, Taizhou University, Taizhou, Zhejiang 318000, China
Guotao Duan
Affiliation:
Key Laboratory of Materials Physics and School of Materials Science and Engineering, Institute of Solid State Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Chinese Academy of Sciences, Hefei 230031, Anhui, China
Guangqiang Liu
Affiliation:
Key Laboratory of Materials Physics and School of Materials Science and Engineering, Institute of Solid State Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Chinese Academy of Sciences, Hefei 230031, Anhui, China
Zhengfei Dai
Affiliation:
Key Laboratory of Materials Physics and School of Materials Science and Engineering, Institute of Solid State Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Chinese Academy of Sciences, Hefei 230031, Anhui, China
Jinlian Hu
Affiliation:
School of Materials Science and Engineering, Anhui University of Technology, Ma-An-Shan 243002, Anhui, China
Weiping Cai
Affiliation:
Key Laboratory of Materials Physics and School of Materials Science and Engineering, Institute of Solid State Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Chinese Academy of Sciences, Hefei 230031, Anhui, China
Yue Li*
Affiliation:
Key Laboratory of Materials Physics and School of Materials Science and Engineering, Institute of Solid State Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Chinese Academy of Sciences, Hefei 230031, Anhui, China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

A facile inexpensive route has been developed to prepare ZnO hierarchical materials with microplate/nanohole structures based on the colloidal monolayer template by the precursor thermal decomposition. These hierarchical structured materials demonstrated an excellent superhydrophobicity with self-cleaning effect and an enhanced photocatalytic performance to organic molecules, which are attributed to big roughness and large surface area of such special hierarchical structures. The formation mechanism of such hierarchical structures was investigated in detail by tracing morphology changing at different precursor concentrations. At high precursor concentration, both incompletely restricted ZnO growth of colloidal templates and preferable growth of microplates take place at the same time, and hence, ZnO hierarchical materials with microplate/nanohole structures are formed. With increasing precursor concentration, the number density of ZnO microplates tends to be larger. The large number density of ZnO microplates and holes on the microplates render the sample a large surface area and surface roughness, leading to good superhydrophobicity and photocatalytic activity. Such hierarchical ZnO micro/nanostructured materials have important applications in environmental science, microfluidic devices, etc.

Type
Articles
Information
Journal of Materials Research , Volume 29 , Issue 1: Focus Issue: Synthesis of Nanostructured Functional Oxides , 14 January 2014 , pp. 115 - 122
Copyright
Copyright © Materials Research Society 2013 

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References

REFERENCES

Yan, R., Gargas, D., and Yang, P.: Nanowire photonics. Nat. Photonics 3, 569 (2009).Google Scholar
Roduner, E.: Size matters: Why nanomaterials are different. Chem. Soc. Rev. 35, 583 (2006).CrossRefGoogle ScholarPubMed
Cobley, C.M., Chen, J., Cho, E.C., Wang, L.V., and Xia, Y.: Gold nanostructures: A class of multifunctional materials for biomedical applications. Chem. Soc. Rev. 40, 44 (2011).CrossRefGoogle ScholarPubMed
Wang, Z.L.: Towards self-powered nanosystems: From nanogenerators to nanopiezotronics. Adv. Funct. Mater. 18, 3553 (2008).Google Scholar
Varin, R.A., Zbroniec, L., Polanski, M., and Bystrzycki, J.: A review of recent advances on the effects of microstructural refinement and nano-catalytic additives on the hydrogen storage properties of metal and complex hydrides. Energies 4, 1 (2011).CrossRefGoogle Scholar
Morariu, M., Voicu, N., Schäffer, E., Lin, Z., Russell, T.P., and Steiner, U.: Hierarchical structure formation and pattern replication induced by an electric field. Nat. Mater. 2, 48 (2003).Google Scholar
Dorozhkin, S.V.: A hierarchical structure for apatite crystals. J. Mater. Sci. - Mater. Med. 18, 363 (2007).Google Scholar
Duan, G., Cai, W., Luo, Y., Li, Y., and Lei, Y.: Hierarchical surface rough ordered Au particle arrays and their surface enhanced Raman scattering. Appl. Phys. Lett. 89, 181918 (2006).Google Scholar
Lao, J.Y., Wen, J.G., Wang, D.Z., and Ren, Z.F.: Hierarchical ZnO nanostructures. Nano. Lett. 2, 1287 (2002).CrossRefGoogle Scholar
Gao, P.X., Ding, Y., and Wang, Z.L.: Crystallographic-orientation aligned ZnO nanorods grown by tin catalyst. Nano. Lett. 3, 1315 (2003).Google Scholar
Cho, S.O., Lee, E.J., Lee, H.M., Kim, J.G., and Kim, Y.J.: Controlled synthesis of abundantly branched, hierarchical nanotrees by electron irradiation of polymers. Adv. Mater. 18, 60 (2006).Google Scholar
Wang, L., Guo, S.J., and Dong, S.J.: Facile electrochemical route to directly fabricate hierarchical spherical cupreous micro structures: Toward superhydrophobic surface. Electrochem. Commun. 10, 655 (2008).Google Scholar
Wu, C., Lei, L., Zhu, X., Yang, J., and Xie, Y.: Large-Scale synthesis of titanate and anatase tubular hierarchitectures. Small Mol. 3, 1518 (2007).CrossRefGoogle ScholarPubMed
Li, Y., Sasaki, T., Shimizu, Y., and Koshizaki, N.: Hexagonal-close-packed, hierarchical amorphous TiO2 nanocolumn arrays: Transferability, enhanced photocatalytic activity, and superamphiphilicity without UV irradiation. J. Am. Chem. Soc. 130, 14755 (2008).Google Scholar
Li, Y., Sasaki, T., Shimizu, Y., and Koshizaki, N.: A hierarchically ordered TiO2 hemispherical particle array with hexagonal-non-close-packed tops: Synthesis and stable superhydrophilicity without UV irradiation. Small Mol. 4, 2286 (2008).Google Scholar
Barthlott, W. and Neinhuis, C.: Purity of the sacred lotus, or escape from contamination in biological surfaces. Planta Med. 202, 1 (1997).Google Scholar
Sun, T.L., Feng, L., Gao, X.F., and Jiang, L.: Bioinspired surfaces with special wettability. Acc. Chem. Res. 38, 644 (2005).CrossRefGoogle ScholarPubMed
Wang, S.T., Song, Y.L., and Jiang, L.: Photoresponsive surfaces with controllable wettability. J. Photochem. Photobiol., C 8, 18 (2007).CrossRefGoogle Scholar
Li, X-M., Reinhoudt, D., and Crego-Calama, M.: What do we need for a superhydrophobic surface? A review on the recent progress in the preparation of superhydrophobic surfaces. Chem. Soc. Rev. 36, 1350 (2007).Google Scholar
Shirtcliffe, N.J., McHale, G., Atherton, S., and Newton, M.I.: Introduction to superhydrophobicity. Adv. Colloid Interface Sci. 161, 124 (2010).Google Scholar
Nakajima, A., Hashimoto, K., and Watanabe, T.: Recent studies on super-hydrophobic films. Monatsh. Chem. 132, 31 (2001).Google Scholar
Guo, Z., Liu, W., and Su, B-L.: Superhydrophobic surfaces: From natural to biomimetic to functional. J. Colloid Interface Sci. 353, 335 (2011).Google Scholar
Chen, W., Fadeev, A., Hsieh, M., Öner, D., Youngblood, J., and McCarthy, T.: Ultrahydrophobic and ultralyophobic surfaces: Some comments and examples. Langmuir 15, 3395 (1999).Google Scholar
Han, J.T., Kim, S.Y., Woo, J.S., and Lee, G-W.: Transparent, conductive, and superhydrophobic films from stabilized carbon nanotube/silane sol mixture solution. Adv. Mater. 20, 3724 (2008).Google Scholar
Lau, K.K.S., Bico, J., Teo, K.K.B., Chhowalla, M., Amaratunga, G.A.J., Milne, W.I., McKinley, G.H., and Gleason, K.K.: Superhydrophobic carbon nanotube forests. Nano. Lett. 3, 1701–1705 (2003).Google Scholar
Zhang, G., Wang, D.Y., Gu, Z-Z., and Möhwald, H.: Facile fabrication of super-hydrophobic surfaces from binary colloidal assembly. Langmuir 21, 9143 (2005).Google Scholar
Nakajima, A., Fujishima, A., Hashimoto, K., and Watanabe, T.: Superhydrophobic films from raspberry-like particles. Adv. Mater. 11, 1365 (1999).Google Scholar
Zhang, L., Zhou, Z., Cheng, B., DeSimone, J.M., and Samulski, E.T.: Superhydrophobic behavior of a perfluoropolyether lotus-leaf-like topography. Langmuir 22, 8576 (2006).Google Scholar
Xia, F., Feng, L., Wang, S., Sun, T., Song, W., Jiang, W., and Jiang, L.: Dual-responsive surfaces that switch between superhydrophilicity and superhydrophobicity. Adv. Mater. 18, 432 (2006).CrossRefGoogle Scholar
Wang, S., Feng, L., and Jiang, L.: One-step solution-immersing process towards bionic superhydrophobic surfaces. Adv. Mater. 18, 767 (2006).Google Scholar
Lee, E.J., Lee, H.M., Li, Y., Hong, L.Y., Kim, D.P., and Cho, S.O.: Hierarchical pore structures fabricated by electron irradiation of silicone grease and their applications to superhydrophobic and superhydrophilic films. Macromol. Rapid Commun. 28, 246 (2007).Google Scholar
Li, Y., Cai, W.P., Cao, B.Q., Duan, G.T., Sun, F.Q., Li, C.C., and Jia, L.C.: Two-dimensional hierarchical porous silica film and its tunable superhydrophobicity. Nanotechnology 17, 238 (2006).CrossRefGoogle Scholar
Li, Y., Duan, G.T., and Cai, W.P.: Controllable superhydrophobic and lipophobic properties of ordered pore indium oxide array films. J. Colloid Interface Sci. 314, 615 (2007).Google Scholar
Zhang, G. and Wang, D.: Colloidal lithography—the art of nanochemical patterning. Chem. Asian J. 4, 236 (2009).Google Scholar
Li, Y., Koshizaki, N., and Cai, W.: Periodic one-dimensional nanostructured arrays based on colloidal templates, applications, and devices. Coord. Chem. Rev. 255, 357 (2011).Google Scholar
Li, Y., Cai, W., and Duan, G.: Ordered micro/nanostructured arrays based on the monolayer colloidal crystals. Chem. Mater. 20, 615 (2008).Google Scholar
Li, Y., Cai, W.P., Cao, B.Q., Duan, G.T., Li, C.C., Sun, F.Q., and Zeng, H.B.: Morphology-controlled 2D ordered arrays by heating-induced deformation of 2D colloidal monolayer. J. Mater. Chem. 16, 609 (2006).CrossRefGoogle Scholar
Duan, G.T., Cai, W.P., Li, Y., Li, Z.G., Cao, B.Q., and Luo, Y.Y.: Transferable ordered Ni hollow sphere arrays induced by electrodeposition on colloidal monolayer. J. Phys. Chem. B 110, 7184 (2006).Google Scholar
Li, Y., Li, C.C., Cho, S.O., Duan, G.T., and Cai, W.P.: Silver hierarchical bowl-like array: Synthesis, superhydrophobicity, and optical properties. Langmuir 23, 9802 (2007).Google Scholar
Li, Y., Huang, X.J., Heo, S.H., Li, C.C., Choi, Y.K., Cai, W.P., and Cho, S.O.: Superhydrophobic bionic surfaces with hierarchical microsphere/SWCNT composite arrays. Langmuir 23, 2169 (2007).Google Scholar
Li, Y., Lee, E.J., and Cho, S.O.: Superhydrophobic coatings on curved surfaces featuring remarkable supporting force. J. Phys. Chem. C 111, 14813 (2007).Google Scholar
Min, W-L., Jiang, B., and Jiang, P.: Bioinspired self-cleaning antireflection coatings. Adv. Mater. 20, 3914 (2008).Google Scholar
Kosiorek, A., Kandulski, W., Glaczynska, H., and Giersig, M.: Fabrication of nanoscale rings, dots, and rods by combining shadow nanosphere lithography and annealed polystyrene nanosphere masks. Small Mol. 1, 439 (2005).Google Scholar
Wang, K.X., Yao, B.D., Morris, M.A., and Holmes, J.D.: Supercritical fluid processing of thermally stable mesoporous titania thin films with enhanced photocatalytic activity. Chem. Mater. 17, 4825 (2005).Google Scholar
Zhang, X.T., Jin, M., Liu, Z.Y., Tryk, D.A., Nishimoto, S., Murakami, T., and Fujishima, A.: Superhydrophobic TiO2 surfaces: Preparation, photocatalytic wettability conversion, and superhydrophobic-superhydrophilic patterning. J. Phys. Chem. C 111, 14521 (2007).Google Scholar
Gao, W., Dickinson, L., Grozinger, C., Morin, F.G., and Reven, L.: Self-assembled monolayers of alkylphosphonic acids on metal oxides. Langmuir 12, 6429 (1996).Google Scholar
Wenzel, R.N.: Surface roughness and contact angle. J. Phys. Colloid Chem. 53, 1446 (1949).Google Scholar
Cassie, A.B.D. and Baxter, S.: Wettability of porous surfaces. Trans. Faraday Soc. 40, 546 (1944).Google Scholar
Kwak, G., Seol, M., Tak, Y., and Yong, K.: Superhydrophobic ZnO nanowire surface: Chemical modification and effects of UV irradiation. J. Phys. Chem. C 113, 12085 (2009).Google Scholar
Li, M., Zhai, J., Liu, H., Song, Y., Jiang, L., and Zhu, D.: Electrochemical deposition of conductive superhydrophobic zinc oxide thin films. J. Phys. Chem. B 107, 9954 (2003).Google Scholar
Li, Y., Cai, W.P., Duan, G.T., Cao, B.Q., Sun, F.Q., and Lu, F.: Superhydrophobicity of 2D ZnO ordered pore arrays formed by solution-dipping template method. J. Colloid Interface Sci. 287, 634 (2005).Google Scholar
Cui, J.J., Yang, Q.H., and Wang, X.D.: Photocatalysed reduction nature of nano ZnO. Bull. Chin. Ceram. Soc. 1, 23 (2006).Google Scholar
Zhou, J.P., Fu, W.L., Qiu, K.Q., and Chen, Q.Y.: Wettability of porous two dimensional ZnO nanocrystal films. J. Funct. Mater. Dev. 13, 195 (2007).Google Scholar
Liu, H., Huang, B., Qin, X., Zhang, X., and Wang, Z.: Fabrication and photocatalytic of mushroom-like ZnO microcrystals via a solvothermal route. Rare Met. 30, 173 (2011).Google Scholar
Ma, C., Zhou, Z., Wei, H., Yang, Z., Wang, Z., and Zhang, Y.: Rapid large-scale preparation of ZnO nanowire for photocatalytic application. Nano. Res. Lett. 6, 536 (2011).Google Scholar
Nasr-Esfahani, M. and Nekoubin, A.: Well-aligned arrays of vertically oriented ZnO nanorod films for photocatalytic degradation of textile dye. AIP Conf. Proc. 1341, 309 (2011).Google Scholar
Sun, F., Cai, W., Li, Y., Cao, B., Lei, Y., and Zhang, L.: Morphology-controlled growth of large-area two-dimensional ordered pore arrays. Adv. Funct. Mater. 14, 283 (2004).Google Scholar
Li, Y., Cai, W., Duan, G., Cao, B., and Sun, F.: Two-dimensional ordered polymer hollow sphere and convex structure arrays based on monolayer pore films. J. Mater. Res. 20, 338 (2005).CrossRefGoogle Scholar