Hostname: page-component-586b7cd67f-tf8b9 Total loading time: 0 Render date: 2024-11-24T11:08:09.466Z Has data issue: false hasContentIssue false

Formation of interfacial η′-Cu6Sn5 in Sn–0.7Cu/Cu solder joints during isothermal aging

Published online by Cambridge University Press:  27 June 2011

Zhongbing Luo
Affiliation:
School of Materials Science and Engineering, Dalian University of Technology, Dalian 116085, China
Lai Wang
Affiliation:
School of Materials Science and Engineering, Dalian University of Technology, Dalian 116085, China
Qinqin Fu
Affiliation:
School of Materials Science and Engineering, Dalian University of Technology, Dalian 116085, China
Chongqian Cheng
Affiliation:
School of Materials Science and Engineering, Dalian University of Technology, Dalian 116085, China
Jie Zhao*
Affiliation:
School of Materials Science and Engineering, Dalian University of Technology, Dalian 116085, China
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

The formation of interfacial η′-Cu6Sn5 in Sn–0.7Cu/Cu solder joints at different aging temperatures was studied using x-ray diffraction (XRD). The time-temperature-formation curve was obtained and is discussed based on the phase transformation from existing η-Cu6Sn5 and interfacial reaction at temperatures below 186 °C. A minimum formation time was observed in the temperature range of 135–150 °C.

Type
Materials Communications
Copyright
Copyright © Materials Research Society 2011

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Laurila, T., Vuorinen, V., and Kivilahti, J.K.: Interfacial reactions between lead-free solders and common base materials. Mater. Sci. Eng., R 49, 1 (2005).CrossRefGoogle Scholar
2.Tarascon, J.M. and Armand, M.: Issues and challenges facing rechargeable lithium batteries. Nature 414, 359 (2001).CrossRefGoogle ScholarPubMed
3.Larsson, A.K., Stenberg, L., and Lidin, S.: The superstrusture of domain-twinned η′-Cu6Sn5. Acta Crystallogr. B 50, 636 (1994).CrossRefGoogle Scholar
4.Larsson, A.K., Stenberg, L., and Lidin, S.: Crystal structure modulations in η-Cu5Sn4. Z. Kristallogr. 210, 832 (1995).CrossRefGoogle Scholar
5.Lidin, S. and Larsson, A.K.: A survey of superstructures in intermetallic NiAs-Ni2In-type phases. J. Solid State Chem. 118, 313 (1995).CrossRefGoogle Scholar
6.Gangulee, A., Das, G.C., and Bever, M.B.: An x-ray diffraction and calorimetric investigation of the compound Cu6Sn5. Metall. Trans. 4, 2063 (1973).CrossRefGoogle Scholar
7.Ghosh, G. and Asta, M.: Phase stability, phase transformations, and elastic properties of Cu6Sn5: Ab initio calculations and experimental results. J. Mater. Res. 20, 3102 (2005).CrossRefGoogle Scholar
8.Nogita, K., Gourlay, C.M., and Nishimura, T.: Cracking and phase stability in reaction layers between Sn-Cu-Ni solders and Cu substrates. J. Miner. Met. Mater. Soc. 61, 45 (2009).CrossRefGoogle Scholar
9.Schwingenschlögl, U., Paola, C.D., Nogita, K., and Gourlay, C.M.: The influence of Ni additions on the relative stability of η and η′ Cu6Sn5. Appl. Phys. Lett. 96, 061908 (2010).CrossRefGoogle Scholar
10.Savitzky, A. and Golay, M.J.E.: Smoothing and differentiation of data by simplified least squares procedures. Anal. Chem. 36, 1627 (1964).CrossRefGoogle Scholar
11.Christian, J.W.: The Theory of Transformations in Metals and Alloys, 2nd ed. (Elsevier Science, Oxford, UK, 2002), pp. 11, 16, 532, 702709.CrossRefGoogle Scholar