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Explosion Phase Formation of Nanocrystalline Boron Nitrides Upon Pulsed-Laser-Induced Liquid/Solid Interfacial Reaction

Published online by Cambridge University Press:  31 January 2011

J.B. Wang
Affiliation:
State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Zhongshan University, Guangzhou 510275, People's Republic of China, and Department of Physics, Xiangtan University, Xiangtan 411105, People's Republic of China
X.L. Zhong
Affiliation:
Department of Physics, Xiangtan University, Xiangtan 411105, People's Republic of China
C.Y. Zhang
Affiliation:
Department of Physics, Xiangtan University, Xiangtan 411105, People's Republic of China
B.Q. Huang
Affiliation:
Department of Physics, Xiangtan University, Xiangtan 411105, People's Republic of China
G.W. Yang
Affiliation:
State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Zhongshan University, Guangzhou 510275, People's Republic of China, and Department of Physics, Xiangtan University, Xiangtan 411105, People's Republic of China
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Abstract

Boron nitride (BN) nanocrystals with explosion (E) phase were prepared by a novel laser-assisted materials fabrication, i.e., pulsed-laser-induced liquid (acetone)/solid (hexagonal boron nitride bulk) interfacial reaction at normal temperature and pressure. Typical diameters of these synthesized quasi-spherical BN nanocrystals were in the range of 30 to 80 nm. Transmission electron microscopy, x-ray diffraction, and Fourier transformed infrared spectroscopy were used to identify the morphologies and structures of the synthesized nanocrystals. Additionally, we proposed the formation mechanism of cubic-BN and E-BN nanocrystals upon pulsed-laser-induced liquid/solid interfacial reaction, in which both liquid and solid were simultaneously involved.

Type
Articles
Copyright
Copyright © Materials Research Society 2003

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