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Exothermic reactions in cold-rolled Ni/Al reactive multilayer foils

Published online by Cambridge University Press:  31 January 2011

X. Qiu ,
J. Graeter ,
L. Kecskes  and
J. Wang
X. Qiu
Affiliation:
Department of Mechanical Engineering, Louisiana State University, Baton Rouge, Louisiana 70803
J. Graeter
Affiliation:
Department of Mechanical Engineering, Louisiana State University, Baton Rouge, Louisiana 70803
L. Kecskes
Affiliation:
United States Army Research Laboratory, Aberdeen Proving Ground, Maryland 21005
J. Wang*
Affiliation:
Department of Physics and Tsinghua–Foxcoon Nanotechnology Research Center, Tsinghua University, Beijing 100084, China; and Department of Mechanical Engineering, Louisiana State University, Baton Rouge, Louisiana 70803
*
a) Address all correspondence to this author. e-mail: [email protected]
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Abstract

Exothermic reactions in cold-rolled Ni/Al reactive multilayer foils were investigated in this study. A two-stage reaction process was observed in the self-propagating reactions in the cold-rolled foils that were ignited by a point-source flame. Foils taken out of the flame after completing the first stage of the reaction process were compared to those allowed to complete both stages. Differences in the phase-evolution sequence from the two types of foils were studied by differential scanning calorimetry (DSC), using slow and controlled heating of the samples. Several exothermic peaks could be identified from the DSC thermograms for both types of foils. Using the DSC, both the as-cold-rolled and partially reacted foils were heated to each peak temperature to identify the reaction product associated with each peak. X-ray diffraction and scanning electron microscopy analyses showed that the first two peaks corresponded to the formation of Al3Ni, while the third peak corresponded to the formation of AlNi.

Keywords

Chemical reactionAlNi
Type
Articles
Information
Journal of Materials Research , Volume 23 , Issue 2 , February 2008 , pp. 367 - 375
Copyright
Copyright © Materials Research Society 2007

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References

REFERENCES

1Ma, E., Thompson, C.V., Clevenger, L.A.Tu, K.N.: Self-propagating explosive reactions in Al/Ni multilayer thin films. Appl. Phys. Lett. 57, 1262 1990Google Scholar
2Weihs, T.P.: Handbook of Thin Film Process Technology Institute of Physics Bristol, UK 1998 F7:1, F7:13Google Scholar
3Reiss, M.E., Esber, C.M., Van Heerden, D., Gavens, A.J., Williams, M.E.Weihs, T.P.: Self-propagating formation reactions in Nb/Si multilayers. Mater. Sci. Eng., A 261, 217 1999CrossRefGoogle Scholar
4Wang, J., Besnoin, E., Duckham, A., Spey, S.J., Reiss, M.E., Knio, O.M.Weihs, T.P.: Joining of stainless-steel specimens with nanostructured Al/Ni foils. J. Appl. Phys. 95, 248 2004CrossRefGoogle Scholar
5Wang, J., Besnoin, E., Knio, O.M.Weihs, T.P.: Effects of physical properties of components on reactive nanolayer joining. J. Appl. Phys. 97, 4307 2005CrossRefGoogle Scholar
6Duckham, A., Spey, S.J., Wang, J., Reiss, M.E.Weihs, T.P.: Reactive nanostructured foil used as a heat source for joining titanium. J. Appl. Phys. 96, 2336 2004Google Scholar
7Wang, J., Besnoin, E., Duckham, A., Spey, S.J., Reiss, M., Knio, O.M., Powers, M., Whitener, M.Weihs, T.P.: Room-temperature soldering with nanostructured foils. Appl. Phys. Lett. 83, 3987 2003Google Scholar
8Swiston, A.J. Jr., Hufnagel, T.C.Weihs, T.P.: Joining bulk metallic glass using reactive multilayer foils. Scripta Mater. 48, 1575 2003Google Scholar
9Wang, J., Besnoin, E., Knio, O.M.Weihs, T.P.: Investigating the effect of applied pressure on reactive multilayer foil joining. Acta Mater. 52, 5265 2004Google Scholar
10Qiu, X.Wang, J.: Reactive multilayer foils for silicon wafer bonding in Advanced Electronic Packaging, edited by V.P. Atluri, S. Sharan, C-P. Wong, and D. Frear (Mater. Res. Soc. Symp. Proc.) 968 Warrendale, PA 2007 968-V02-06Google Scholar
11Ma, E., Thompson, C.V.Clevenger, L.A.: Nucleation and growth during reactions in multilayer Al/Ni films: The early stage of Al3Ni formation. J. Appl. Phys. 69, 2211 1991Google Scholar
12Barmak, K., Michaelsen, C.Lucadamo, G.: Reactive phase formation in sputter-deposited Ni/Al multilayer thin films. J. Mater. Res. 12, 133 1997CrossRefGoogle Scholar
13Edelstein, A.S., Everett, R.K., Richardson, G.Y., Qadri, S.B., Altman, E.I., Foley, J.C.Perepezko, J.H.: Intermetallic phase formation during annealing of Al/Ni multilayers. J. Appl. Phys. 76, 7850 1994CrossRefGoogle Scholar
14Blobaum, K.J., Van Heerden, D., Gavens, A.J.Weihs, T.P.: Al/Ni formation reactions: Characterization of the metastable Al9Ni2 phase and analysis of its formation. Acta Mater. 51, 3871 2003Google Scholar
15Sieber, H., Park, J.S., Weissmüller, J.Perepezko, H.: Structural evolution and phase formation in cold-rolled aluminum–nickel multilayers. Acta Mater. 49, 1139 2001Google Scholar
16Qiu, X.Wang, J.: Experimental evidence of two-stage formation of Al3Ni in reactive Ni/Al multilayer foils. Scripta Mater. 56, 1055 2007Google Scholar
17Battezzati, L., Pappalepore, P., Purbiano, F.Gallino, I.: Solid state reactions in Al/Ni alternate foils induced by cold rolling and annealing. Acta Mater. 47, 1901 1999CrossRefGoogle Scholar
18Weihs, T.P.Reiss, M.: Method of making reactive multilayer foil and resulting product. U.S. Patent No. 6 534 194 (May 18) 2003Google Scholar
19Sauvage, X., Dinda, G.P.Wilde, G.: Non-equilibrium intermixing and phase transformation in severely deformed Al/Ni multilayers. Scripta Mater. 56, 181 2007CrossRefGoogle Scholar
20Mann, A.B., Gavens, A.J., Reiss, M.E., Van Heerden, D., Bao, G.Weihs, T.P.: Modeling and characterizing the propagation velocity of exothermic reactions in multilayer foils. J. Appl. Phys. 82, 1178 1997Google Scholar
21Gavens, A.J., Van Heerden, D., Mann, A.B., Reiss, M.E.Weihs, T.P.: Effect of intermixing on self-propagating exothermic reactions in Al/Ni nanolaminate foils. J. Appl. Phys. 87, 1255 2000Google Scholar
22Coffey, K.R., Clevenger, L.A., Barmak, K., Rudman, D.A.Thompson, C.V.: Experimental evidence for nucleation during thin-film reactions. Appl. Phys. Lett. 55, 852 1989CrossRefGoogle Scholar
23Pretorius, R., Vredenberg, A.M., Saris, F.W.de Reus, R.: Prediction of phase formation sequence and phase stability in binary metal–aluminum thin-film systems using the effective heat of formation rule. J. Appl. Phys. 70, 3636 1991Google Scholar