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Exoelectron emission from unexcited metallic glasses Fe78B13Si9 during heat treatment

Published online by Cambridge University Press:  31 January 2011

Yoshihisa Watanabe ,
Tadayoshi Kubozoe  and
Yoshikazu Nakamura
Yoshihisa Watanabe
Affiliation:
Department of Materials Science and Engineering, National Defense Academy, 1-10-20 Hashirimizu, Yokosuka, Kanagawa 239, Japan
Tadayoshi Kubozoe*
Affiliation:
Department of Materials Science and Engineering, National Defense Academy, 1-10-20 Hashirimizu, Yokosuka, Kanagawa 239, Japan
Yoshikazu Nakamura
Affiliation:
Department of Materials Science and Engineering, National Defense Academy, 1-10-20 Hashirimizu, Yokosuka, Kanagawa 239, Japan
*
a)Professor Emeritus, National Defense Academy.
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Abstract

Exoelectron emission from the surface of unexcited metallic glasses Fe78B13Si9 during heat treatment has been studied under ultra high vacuum condition. In the first heating cycle, exoelectrons are emitted from the as-cast ribbon in the temperature range from approximately 423 K to 773 K (150 °C to 500 °C), although the surface of the specimen is not excited by ionizing radiation, chemical processes, or mechanical treatments prior to measurements. In the second and subsequent heating cycles, however, there is no anomalous emission observed in the same temperature range. In order to elucidate the mechanism of emission, the surface of the specimen is observed by the atomic force microscope (AFM) before and after measurements. In the AFM image, many crystallites in the amorphous matrix can be found in the surface of the heated specimen. These experimental results show that exoelectrons are emitted in the same temperature range as the early stages of crystallization on the surface of metallic glasses. We hypothesize that the two effects are correlated.

Type
Articles
Information
Journal of Materials Research , Volume 7 , Issue 6 , June 1992 , pp. 1396 - 1399
Copyright
Copyright © Materials Research Society 1992

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