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Electrochemical and ex-situ analysis on manganese oxide/graphene hybrid anode for lithium rechargeable batteries

Published online by Cambridge University Press:  23 September 2011

Haegyeom Kim ,
Sung-Wook Kim ,
Jihyun Hong ,
Young-Uk Park  and
Kisuk Kang
Haegyeom Kim
Affiliation:
Department of Materials Science and Engineering, Seoul National University, Seoul 151-742, Republic of Korea
Sung-Wook Kim
Affiliation:
Research Institute of Advanced Materials, Seoul National University, Seoul 151-742, Republic of Korea
Jihyun Hong
Affiliation:
Department of Materials Science and Engineering, Seoul National University, Seoul 151-742, Republic of Korea
Young-Uk Park
Affiliation:
Department of Materials Science and Engineering, Seoul National University, Seoul 151-742, Republic of Korea
Kisuk Kang*
Affiliation:
Department of Materials Science and Engineering, Seoul National University, Seoul 151-742, Republic of Korea
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

A Mn3O4/graphene hybrid material is fabricated using a facile and simple in-situ reduction process and shown to be a promising anode for lithium rechargeable batteries. The hybrid material retains a high capacity with a good cycle life of up to 990 mAh g−1 after 30 cycles. The excellent electrochemical performance is attributable to the unique nanostructure of the hybrid material. Highly crystalline Mn3O4 particles (20–30 nm) are uniformly dispersed on graphene whose high electronic conductivity and high surface area provide a conductive percolating network throughout the electrode in the hybrid material. The conductive graphene networks enhance an electron transfer in the electrode and promote the electrochemical activity of the crystalline Mn3O4.

Keywords

OxideLiEnergy storage
Type
Articles
Information
Journal of Materials Research , Volume 26 , Issue 20 , 28 October 2011 , pp. 2665 - 2671
Copyright
Copyright © Materials Research Society 2011

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