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Effect of Zr addition on the glass-forming ability and mechanical properties of Ni–Nb alloy

Published online by Cambridge University Press:  03 March 2011

Z.W. Zhu ,
H.F. Zhang ,
W.S. Sun  and
Z.Q. Hu
Z.W. Zhu
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
H.F. Zhang*
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
W.S. Sun
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
Z.Q. Hu
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
*
a) Address all correspondence to this author. e-mail address: [email protected]
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Abstract

The effect of zirconium (Zr) addition on the glass-forming ability (GFA) and mechanical properties of the Ni61.5Nb38.5 alloy has been studied. The addition of Zr improves the GFA. When x = 5 for Ni61.5Nb38.5−xZrx (in at.%) alloys, the alloy exhibits the best GFA and can be cast into 3-mm-diameter amorphous samples by using the copper mold injection-casting method. Differential scanning calorimetry measurements indicated that the thermal parameters, such as Trg and γ, have not a good correlation with the GFA in the Ni–Nb–Zr alloys. Compression tests reveal that the addition of Zr just decreases the fracture strength slightly from 3.4 to 3 GPa and that all of the tested samples exhibit a little compressive plasticity of about 2%. When x = 9, the feature of the fracture surface indicates that the alloy has a tendency for transition from the ductile to the brittle. And delicate “dimple” and microscale vein pattern structures have been observed on it.

Keywords

AmorphousFractureNi
Type
Articles
Information
Journal of Materials Research , Volume 22 , Issue 2 , September 2006 , pp. 453 - 459
Copyright
Copyright © Materials Research Society 2007

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References

REFERENCES

1Inoue, A.: Stabilization of metallic supercooled liquid and bulk amorphous alloys. Acta Mater. 48, 279 (2000).CrossRefGoogle Scholar
2Johnson, W.L.: Bulk glass-forming metallic alloys: Science and technology. MRS Bull. 24, 42 (1999).Google Scholar
3Inoue, A., Kato, A., Zhang, T., Kim, S.G., and Masumoto, T.: Mg-Cu-Y amorphous-alloys with high mechanical strengths produced by a metallic mold casting method. Mater. Trans., JIM 32, 609 (1991).Google Scholar
4Inoue, A. and Zhang, T.: Fabrication of bulky Zr-based glassy alloys by suction casting into copper mold. Mater. Trans., JIM 36, 1184 (1995).CrossRefGoogle Scholar
5Peker, A. and Johnson, W.L.: A highly processable metallic glass: Zr41.2Ti13.8Cu12.5Ni10.0Be22.5. Appl. Phys. Lett. 63, 2342 (1993).CrossRefGoogle Scholar
6Inoue, A., Shinohara, Y., and Gook, J.S.: Thermal and magnetic properties of bulk Fe-based glassy alloys prepared by copper mold casting. Mater. Trans., JIM 36, 1427 (1995).Google Scholar
7Zhang, T. and Inoue, A.: Thermal and mechanical properties of Ti-Ni-Cu-Sn amorphous alloys with a wide supercooled liquid region before crystallization. Mater. Trans., JIM 39, 1001 (1998).Google Scholar
8Inoue, A., Zhang, W., Zhang, T., and Kurosaka, K.: High-strength Cu-based bulk glassy alloys in Cu-Zr-Ti and Cu-Hf-Ti ternary systems. Acta Mater. 49, 2645 (2001).CrossRefGoogle Scholar
9Wang, X.M., Yoshii, I., Inoue, A., Kim, Y.H., and Kim, I.B.: Bulk amorphous Ni75−xNb5MxP20−yBy (M = Cr, Mo) alloys with large supercooling and high strength. Mater. Trans., JIM 40, 1130 (1999).Google Scholar
10Mukai, T., Nieh, T.G., Kawamura, Y., Inoue, A., and Higashi, K.: Effect of strain rate on compressive behavior of a Pd40Ni40P20 bulk metallic glass. Intermetallics 10, 1071 (2002).Google Scholar
11Zhang, W. and Inoue, A.: Formation and mechanical properties of Ni-based Ni-Nb-Ti-Hf bulk glassy alloys. Scripta Mater. 48, 641 (2003).CrossRefGoogle Scholar
12Lee, M., Bae, D., Kim, W., and Kim, D.: Ni-based refractory bulk amorphous alloys with high thermal stability. Mater. Trans. 44, 2084 (2003).Google Scholar
13Choi-Yim, H., Xu, D.H., and Johnson, W.L.: Ni-based bulk metallic glass formation in the Ni-Nb-Sn and Ni-Nb-Sn-X (X = B,Fe,Cu) alloy systems. Appl. Phys. Lett. 82, 1030 (2003).Google Scholar
14Choi-Yim, H., Xu, D., Lind, M.L., Loffler, J.F., and Johnson, W.L.: Structure and mechanical properties of bulk glass-forming Ni-Nb-Sn alloys. Scripta Mater. 54, 187 (2006).Google Scholar
15Yi, S., Park, T.G., and Kim, D.H.: Ni-based bulk amorphous alloys in the Ni-Ti-Zr-(Si,Sn) system. J. Mater. Res. 15, 2425 (2000).CrossRefGoogle Scholar
16Lee, M.H., Lee, J.Y., Bae, D.H., Kim, W.T., Sordelet, D.J., and Kim, D.H.: A development of Ni-based alloys with enhanced plasticity. Intermetallics 12, 1133 (2004).Google Scholar
17Xu, D., Duan, G., Johnson, W.L., and Garland, C.: Formation and properties of new Ni-based amorphous alloys with critical casting thickness up to 5 mm. Acta Mater. 52, 3493 (2004).Google Scholar
18Chih-Yuan, L., Hung-Yu, T., and Tsung-Shune, C.: Soft magnetic ternary iron-boron-based bulk metallic glasses. Appl. Phys. Lett. 86, 162501 (2005).Google Scholar
19Kawashima, A., Kurishita, H., Kimura, H., Zhang, T., and Inoue, A.: Fracture toughness of Zr55Al10Ni5Cu30 bulk metallic glass by 3-point bend testing. Mater. Trans. 46, 1725 (2005).Google Scholar
20Leonhardt, M., Loser, W., and Lindenkreuz, H.G.: Solidification kinetics and phase formation of undercooled eutectic Ni-Nb melts. Acta Mater. 47, 2961 (1999).Google Scholar
21Zhu, Z.W., Zhang, H.F., Pan, D.G., Sun, W.S., and Hu, Z.Q.: Fabrication of binary Ni-Nb bulk metallic glass with high strength and compressive plasticity. Adv. Eng. Mater. 8, 953 (2006).CrossRefGoogle Scholar
22Turnbull, D.: Under what condition can a glass be formed? Contemp. Phys. 10, 473 (1969).Google Scholar
23Lu, Z.P. and Liu, C.T.: A new glass-forming ability criterion for bulk metallic glasses. Acta Mater. 50, 3501 (2002).CrossRefGoogle Scholar
24Takeuchi, A. and Inoue, A.: Calculations of mixing enthalpy and mismatch entropy for ternary amorphous alloys. Mater. Trans., JIM 41, 1372 (2000).Google Scholar
25Yamaura, S., Sakurai, M., Hasegawa, M., Wakoh, K., Shimpo, Y., Nishida, M., Kimura, H., Matsubara, E., and Inoue, A.: Hydrogen permeation and structural features of melt-spun Ni-Nb-Zr amorphous alloys. Acta Mater. 53, 3703 (2005).CrossRefGoogle Scholar
26Hays, C.C., Kim, C.P., and Johnson, W.L.: Microstructure controlled shear band pattern formation and enhanced plasticity of bulk metallic glasses containing in situ formed ductile phase dendrite dispersions. Phys. Rev. Lett. 84, 2901 (2000).Google Scholar
27Chen, G.L., Hui, X.D., Fan, S.W., Kou, H.C., and Yao, K.F.: Concept of chemical short range order domain and the glass forming ability in multicomponent liquid. Intermetallics 10, 1221 (2002).Google Scholar
28Das, J., Tang, M.B., Kim, K.B., Theissmann, R., Baier, F., Wang, W.H., and Eckert, J.: “Work-hardenable” ductile bulk metallic glass. Phys. Rev. Lett. 94, 205501 (2005).CrossRefGoogle ScholarPubMed
29Kim, Y.C., Fleury, E., Lee, J.C., and Kim, D.H.: Origin of the simultaneous improvement of strength and plasticity in Ti-based bulk metallic glass matrix composites. J. Mater. Res. 20, 2474 (2005).Google Scholar
30Xi, X.K., Zhao, D.Q., Pan, M.X., Wang, W.H., Wu, Y., and Lewandowski, J.J.: Fracture of brittle metallic glasses: Brittleness or plasticity. Phys. Rev. Lett. 94, 125510 (2005).CrossRefGoogle ScholarPubMed
31Pan, D.G., Zhang, H.F., Wang, A.M., Wang, Z.G., and Hu, Z.Q.: Fracture instability in brittle Mg-based bulk metallic glasses. (Unpublished work 2006).Google Scholar
32Yavari, A.R.: Absence of thermal embrittlement in some Fe-B and Fe-Si-B glassy alloys. Mater. Sci. Eng. 98, 491 (1988).CrossRefGoogle Scholar