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Effect of ultraviolet-irradiation on peeling-induced formation of surface gratings on PMMA films

Published online by Cambridge University Press:  09 June 2016

Ming-Yi Li ,
Fuqian Yang  and
Sanboh Lee
Ming-Yi Li
Affiliation:
Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu 300, Taiwan
Fuqian Yang
Affiliation:
Department of Chemical and Materials Engineering, University of Kentucky, Lexington, KY 40506
Sanboh Lee*
Affiliation:
Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu 300, Taiwan
*
a) Address all correspondence to this author. e-mail: [email protected]
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Abstract

Using the peeling-induced splitting method, the effect of the irradiation of ultraviolet (UV) light on the formation of surface gratings on the surface of PMMA(Poly(Methyl Methacrylate))-based films is investigated at room temperature. The thickness of the PMMA-based films is in range of 236–534 nm, and the irradiation dose is in range of 0–5 J/cm2. Surface gratings are formed on the surface of the irradiated PMMA-based films. The spatial wave length is a linear function of the film thickness, independent of the UV doses used. The peeling-induced splitting process introduces compressive stress on the surface of the PMMA-based films, much larger than the corresponding surface energy. The magnitude of the apparent surface force increases with the increase of the film thickness. All the surface gratings formed have amplitudes approximately in the same range.

Keywords

polymerradiation effectsself-assembly
Type
Articles
Information
Journal of Materials Research , Volume 31 , Issue 14 , 28 July 2016 , pp. 2004 - 2010
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Copyright
Copyright © Materials Research Society 2016 

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Footnotes

Contributing Editor: Franz Faupel

References

REFERENCES

Sun, W. and Yang, F.Q.: Self-organization of unconventional gradient concentric rings on precast PMMA Film. J. Phys. Chem. C 118, 10177–10182 (2014).Google Scholar
Sun, W. and Yang, F.Q.: Formation of self-organized gradient stripes on precast poly(methylmethacrylate) films. Langmuir 30, 6548–6555 (2014).Google Scholar
Lin, Z.Q. and Granick, S.: Pattern formed by droplet evaporation from restricted geometry. J. Am. Chem. Soc. 127, 2816–2817 (2005).Google Scholar
Wu, N., Pease, L.F., and Russel, W.B.: Toward large-scale alignment of electrohydrodynamic patterning of thin-polymer films. Adv. Funct. Mater. 16, 1992–1999 (2006).Google Scholar
Leach, K.A., Gupta, S., Dickey, M.D., Willson, C.G., and Russell, T.P.: Electric field and dewetting induced hierarchical structure formation in polymer/polymer/air trilayers. Chaos 15, 047506 (2005).Google Scholar
Voicu, N.E., Harkema, S., and Steiner, U.: Electric-field-induced pattern morphologies in thin liquid films. Adv. Funct. Mater. 16, 926–934 (2006).Google Scholar
Khang, D.Y., Kang, H., Kim, T., and Lee, H.H.: Low-pressure nanoimprint lithography. Nano Lett. 4, 633–637 (2004).Google Scholar
Suzuki, K., Youn, S.W., Hiroshima, H., and Takagi, H.: Nano-patterning on soluble block copolymer polyimide by nanoimprint. Jpn. J. Appl. Phys. 54, 088002 (2015).Google Scholar
Takei, S. and Hanabata, M.: Magnetic modulation doping in topological insulators toward high-temperature quantum anomalous Hall effect. Appl. Phys. Lett. 107, 182401 (2015).Google Scholar
Hofsass, H.: Surface instability and pattern formation by ion-induced erosion and mass redistribution. Appl. Phys. A: Mater. Sci. Process. 114, 401–422 (2014).Google Scholar
Huang, S.Q., Li, B., and Feng, X.Q.: Three-dimension analysis of spontaneous surface instability and pattern formation of thin soft films. J. Appl. Phys. 103, 083501 (2008).Google Scholar
Shenoy, V. and Sharma, A.: Surface instability and pattern formation in two interacting incompressible elastic films bonded to rigid substrates. Langmuir 18, 2216–2222 (2002).Google Scholar
Lin, C.C., Yang, F.Q., and Lee, S.: Surface wrinkling of an elastic film: Effect of residual surfaces stress. Langmuir 24, 13627–13631 (2008).Google Scholar
Liang, P.Y., Yang, F.Q., and Lee, S.: Fracture-induced formation of semi-concentric pattern on polymeric films. Mater. Chem. Phys. 135, 168–173 (2012).Google Scholar
Pease, L.F., Deshpande, P., Wang, Y., Russel, W.B., and Chou, S.Y.: Self-formation of sub-60-nm half-pitch gratings with large area through fracturing. Nat. Nanotechnol. 2, 545–548 (2007).Google Scholar
Cai, Y.J. and Newby, B.M.Z.: Fracture-induced formation of parallel silicones strips. J. Mater. Res. 25, 803–809 (2010).Google Scholar
Lee, Y.Y., Yang, F.Q., Chen, C.C., and Lee, S.: Process comparison for fracture-induced formation of surface structures on polymer films. Thin Solid Films 550, 334–339 (2014).Google Scholar
Clifford, S.S., Roman-Alicea, K., Tantbirojn, D., and Versluis, A.: Shrinkage and hardness of dental composites acquired with different curing light sources. Quintessence Int. 40, 203–214 (2009).Google Scholar
Decker, C.: Kinetic study and new applications of UV radiation curing. Macromol. Rapid Commun. 23, 1067–1093 (2002).Google Scholar
Faucitano, A., Buttafava, A., Camino, G., and Greci, L.: Photo-oxidation and stabilization of polymers. Trends Polym. Sci. 4, 92–98 (1996).Google Scholar
Freund, B.: Nanogratings: Breaking up is a grating experience. Nat. Nanotechnol. 2, 537–538 (2007).CrossRefGoogle ScholarPubMed
Huang, C.K., Lou, W.M., Tsai, C.J., Tung-Chuan, W.B., and Lin, H.Y.: Mechanical properties of polymer thin film measured by the bulge test. Thin Solid Films 515, 7222–7226 (2007).CrossRefGoogle Scholar
Owens, D.K. and Wendt, R.: Estimation of the surface free energy of polymers. J. Appl. Polym. Sci. 13, 1741–1747 (1969).Google Scholar