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Effect of TiO2 addition on the combustion synthesis in the Ti–B4C system

Published online by Cambridge University Press:  31 January 2011

Ping Shen ,
Binglin Zou  and
Qichuan Jiang
Ping Shen
Affiliation:
Key Laboratory of Automobile Materials, Department of Materials Science and Engineering, Jilin University, Changchun 130025, People’s Republic of China
Binglin Zou
Affiliation:
Key Laboratory of Automobile Materials, Department of Materials Science and Engineering, Jilin University, Changchun 130025, People’s Republic of China
Qichuan Jiang*
Affiliation:
Key Laboratory of Automobile Materials, Department of Materials Science and Engineering, Jilin University, Changchun 130025, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

The effects of TiO2 addition on the reaction behavior, product, and mechanism in the Ti–B4C system were investigated in this study. The reaction could be self-sustaining for the TiO2 addition no more than ∼33% of the total weight of the reactants. With an increase in the TiO2 addition, the combustion temperature and wave velocity decrease progressively, the ignition delay time first decreases and then increases, while the constituents of the reaction products do not vary significantly unless the relative addition content of TiO2 exceeds ∼22 wt%. Therefore, TiO2 could be used as a favorable reaction regulator for the Ti–B4C system. The reaction mechanism, as determined by differential thermal analysis and combustion front quenching experiment in combination with subsequent x-ray diffraction examination, is changed more or less by the addition of TiO2 with the extent depending on the addition amount.

Keywords

Combustion synthesis (SHS)CompositeCeramic
Type
Articles
Information
Journal of Materials Research , Volume 23 , Issue 5 , May 2008 , pp. 1327 - 1333
Copyright
Copyright © Materials Research Society 2008

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References

REFERENCES

1Upadhya, K., Yang, J.M.Hoffman, W.P.: Materials for ultrahigh temperature structural applications. Am. Ceram. Soc. Bull. 76, 51 1997Google Scholar
2Gotman, I., Travitzky, N.A.Gutmanas, E.Y.: Dense in situ TiB2/TiN and TiB2/TiC ceramic-matrix composites: Reactive synthesis and properties. Mater. Sci. Eng., A 244, 127 1998CrossRefGoogle Scholar
3Zhang, X.H., Zhu, C.C., Qu, W., Zhang, X.D.Kvanin, V.L.: Self-propagating high temperature combustion synthesis of TiC/TiB2 ceramic-matrix composites. Comp. Sci. Technol. 62, 2037 2002Google Scholar
4Song, I., Wang, L., Wixom, M.Thompson, L.T.: Self-propagating high temperature synthesis and dynamic compaction of titanium diboride/titanium carbide composites. J. Mater. Sci. 35, 2611 2000CrossRefGoogle Scholar
5Zou, B.L., Shen, P., Gao, Z.M.Jiang, Q.C.: Combustion synthesis of TiCx-TiB2 composites with hypoeutectic, eutectic and hypereutectic microstructures. J. Eur. Ceram. Soc. 2008 doi: 10.1016/j.jeurceramicsoc.2008.02.014CrossRefGoogle Scholar
6Zou, B.L., Shen, P.Jiang, Q.C.: Reaction synthesis of TiC–TiB2/Al composites from Al–Ti–B4C system. J. Mater. Sci. 42, 9927 2007CrossRefGoogle Scholar
7Liang, Y.H., Wang, H.Y., Yang, Y.F., Zhao, R.Y.Jiang, Q.C.: Effect of Cu content on the reaction behaviors of self-propagating high-temperature synthesis in Cu–Ti–B4C system. J. Alloys Compd. 2007 doi: 10.1016/j.jallcom.2007.08.033Google Scholar
8Yang, Y.F., Wang, H.Y., Zhao, R.Y., Liang, Y.H.Jiang, Q.C.: Effect of Ni content on the reaction behaviors of self-propagating high-temperature synthesis in the Ni–Ti–B4C system. Int. J. Refract. Met. Hard Mater. 26, 77 2008CrossRefGoogle Scholar
9Levin, L., Frage, N.Dariel, M.P.: The effect of Ti and TiO2 additions on the pressureless sintering of B4C. Metall. Mater. Trans. A 30, 3201 1999CrossRefGoogle Scholar
10Kakazey, M., Vlasova, M., Gonzalez-Rodriguez, J.G., Patiň, M. Dominguez-Leder, R.: X-ray and EPR study of reactions between B4C and TiO2. Mater. Sci. Eng., A 418, 111 2006CrossRefGoogle Scholar
11Walker, J.K.: Synthesis of TiB2 by the borothermic/carbothermic reduction of TiO2 with B4C. Adv. Ceram. Mater. 3, 601 1988CrossRefGoogle Scholar
12Shen, P., Zou, B.L., Jin, S.B.Jiang, Q.C.: Reaction mechanism in self-propagating high temperature synthesis of TiC–TiB2/Al composites from an Al–Ti–B4C system. Mater. Sci. Eng., A 454–455, 300 2007CrossRefGoogle Scholar
13Holt, J.B.Munir, Z.A.: Combustion synthesis of titanium carbide: Theory and experiment. J. Mater. Sci. 21, 251 1986CrossRefGoogle Scholar
14Zou, B.L., Shen, P.Jiang, Q.C.: Effect of Al content on the reaction synthesis of the (TiC + TiB2 + α–Al2O3)/Al composites from an Al–TiO2–B4C system. J. Am. Ceram. Soc. (unpublished)Google Scholar
15Ordanyan, S.S., Unrod, V.I.Avgustinik, A.I.: Reactions in the system TiCx–TiB2. Powder Metall. Met. Ceram. 14, 729 1975CrossRefGoogle Scholar