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Effect of reaction temperature on the average crystallite size of SexTe1−x alloys

Published online by Cambridge University Press:  31 January 2011

Santokh S. Badesha
Affiliation:
Xerox Webster Research Center, 800 Phillips Road 0114-39D, Webster, New York 14580
George T. Fekete
Affiliation:
Xerox Webster Research Center, 800 Phillips Road 0114-39D, Webster, New York 14580
Ihor Tarnawskyj
Affiliation:
Xerox Webster Research Center, 800 Phillips Road 0114-39D, Webster, New York 14580
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Abstract

Electrophotographic properties of chalcogenide materials are readily influenced by altering their composition and/or structure. Dark decay and cycle down of photoreceptors utilizing small particle generators are both directly proportional to average crystallite size (ACS). This paper describes a novel chemical method to control the ACS of Se, Te, and Sex Te1−x alloys. These chalcogenide materials are prepared as powders by the reduction or coreduction of SeIV and/or TeIV intermediates with hydrazine, in organic media. To control the ACS of precipitated chalcogens the reaction is carried out at the desired temperature. X-ray diffraction measurements are used to determine the ACS, homogeneity, and phase of these precipitated powders.

Type
Rapid Communications
Copyright
Copyright © Materials Research Society 1986

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