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Effect of metal vapor vacuum arc-implanted Cr on the electrochemical behavior of CrN-coated steels

Published online by Cambridge University Press:  03 March 2011

Ku-Ling Chang ,
Shih-Chun Chung ,
Sheng Han ,
Jyh-Wei Hsu ,
Xing Jian Guo  and
Han C. Shih
Ku-Ling Chang
Affiliation:
Department of Materials Science and Engineering, National Tsing Hua University,Hsinchu, Taiwan 300, Republic of China
Shih-Chun Chung
Affiliation:
Materials Research Laboratories, ITRI, Hsinchu, Taiwan 300, Republic of China
Sheng Han
Affiliation:
National Taichung Institute of Technology, Taichung, Taiwan 404, Republic of China
Jyh-Wei Hsu
Affiliation:
Department of Materials Science and Engineering, National Tsing Hua University,Hsinchu, Taiwan 300, Republic of China
Xing Jian Guo
Affiliation:
Department of Materials Science and Engineering, National Tsing Hua University,Hsinchu, Taiwan 300, Republic of China
Han C. Shih*
Affiliation:
Department of Materials Science and Engineering, National Tsing Hua University,Hsinchu, Taiwan 300, Republic of China
*
a) Address all correspondence to this author. e-mail: [email protected]
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Abstract

Using cathodic arc plasma to deposit CrN on the steel has been explored and extensively studied to improve the wear and corrosion resistance of the steel structures. Metal vapor vacuum arc (MEVVA) source implantation is a novel and profitable surface-modification process coupled with the cathodic arc plasma. The effect of the MEVVA-implanted chromium on the corrosion behavior in form of Cr/steel, CrN/steel, and CrN/Cr/steel was evaluated in an aerated 0.1N HCl solution. The composition and structure of the MEVVA-implanted chromium and the cathodic arc plasma deposited CrN on steel were both examined by x-ray diffraction and transmission electron microscopy. The polarization resistance (Rp) of all samples was measured and compared with the results obtained from electrochemical impedance spectroscopy simulated by the equivalent circuit, to interpret the effect of MEVVA-implanted chromium on the corrosion mechanism of the CrN/Cr/steel. The corrosion products associated with the microstructures were analyzed by electron probe x-ray microanalyzer. The results indicated that the corrosion resistance of the CrN-coated steel was significantly enhanced by the MEVVA-implanted chromium in the CrN/Cr/steel assembly.

Keywords

Physical vapor deposition (PVD)FilmCorrosion
Type
Articles
Information
Journal of Materials Research , Volume 19 , Issue 8 , August 2004 , pp. 2448 - 2456
Copyright
Copyright © Materials Research Society 2004

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References

REFERENCES

1.Kim, S.S., Han, G.J. and Lee, Y.G.: Deposition behaviours of CrN films on the edge area by cathodic arc plasma deposition process. Thin Solid Films 334, 133 (1998).CrossRefGoogle Scholar
2.Navinsek, B., Panjan, P. and Milosev, I.: PVD coatings as an environmentally clean alternative to electroplating and electroless processes. Surf. Coat. Technol. 116–119, 476 (1999).CrossRefGoogle Scholar
3.Creus, J., Idrissi, H., Mazille, H., Sanchette, F. and Jacquot, P.: Improvement of the corrosion resistance of CrN coated steel by an interlayer. Surf. Coat. Technol. 107, 183 (1998).CrossRefGoogle Scholar
4.Vacandio, F., Massiani, Y., Gravier, P., Rossi, S., Bonora, P.L. and Fedrizzi, L.: Improvement of the electrochemical behaviour of AlN films produced by reactive sputtering using various under-layers. Electrochim. Acta . 46, 3827 (2001).CrossRefGoogle Scholar
5.Han, S., Lin, J.H., Tsai, S.H., Chung, S.C., Wang, D.Y., Lu, F.H. and Shih, H.C.: Corrosion and tribological studies of chromium nitride coated on steel with an interlayer of electroplated chromium. Surf. Coat. Technol. 133–134, 460 (2000).CrossRefGoogle Scholar
6.Herranen, M., Wicklund, U., Carlson, J.O. and Hogmark, S.: Corrosion behaviour of Ti/TiN multilayer coated tool steel. Surf. Coat. Technol. 99, 191 (1998).CrossRefGoogle Scholar
7.Jehn, H.A.: Improvement of the corrosion resistance of PVD hard coating-substrate systems. Surf. Coat. Technol. 125, 212 (2000).CrossRefGoogle Scholar
8.Hirvonen, J-P., Nastasi, M. and Mayer, J.W.: Microstructure of ion-bombarded Fe-Ti and Fe-Ti-C multilayered films. J. Appl. Phys. 60, 980 (1986).CrossRefGoogle Scholar
9.Hirvonen, J.K., Carosella, C.A., Kant, R.A., Singer, I., Vardiman, R. and Rath, B.B.: Improvement of metal properties by ion implantation. Thin Solid Films 63, 5 (1979).CrossRefGoogle Scholar
10.Tonghe, Zhang, Huixing, Zhang, Changzhou, Ji, Xiaoji, Zhang, Yuguang, Wu, Furong, Ma, Furong, Ma, Hong, Liang, Hanzhang, Shou and Jianzhong, Shi: Industrialization of MEVVA source ion implantation. Surf. Coat. Technol. 128–129, 1 (2000).CrossRefGoogle Scholar
11.Li, Yongliang, Zhang, Tonghe and Wang, Xiaoyan: Structure of corrosion resistance on H13 steels with titanium and carbon implantation. Surf. Coat. Technol . 128–129, 205 (2000).CrossRefGoogle Scholar
12.Tonghe, Zhang, Yuguang, Wu, Zhiyong, Zhao and Zhiwei, Deng: The ternary Ti(Zr,N) phases formation and modification of TiN coatings by Zr+ MEVVA ion implantation. Surf. Coat. Technol. 131, 326 (2000).CrossRefGoogle Scholar
13.Peng, D.Q., Bai, X.D., Zhou, Q.G., Liu, X.Y., Yu, R.H. and Zhang, D.L.: Studies on the corrosion behavior of cesium-implanted zirconium. J. Nucl. Mater. 324, 71 (2004).CrossRefGoogle Scholar
14.Zhang, T., Xie, J., Ji, C., Chen, J., Xu, H., Li, J., Sun, G. and Zhang, H.X.: Influence of the structure of implanted steel with Y, Y+C and Y+Cr on the behaviors of wear, oxidation and corrosion resistance. Surf. Coat. Technol . 72, 93 (1995).CrossRefGoogle Scholar
15.Zhang, T., Wang, X., Liang, H., Zhang, H., Zhou, G., Sun, G., Zhao, W. and Xue, J.: Behavior of MEVVA metal ion implantation for surface medication of materials. Surf. Coat. Technol . 83, 280 (1996).CrossRefGoogle Scholar
16.Brown, I.G., Godechot, X. and Yu, K.M.: Novel Metal-ion surface modification technique. Appl. Phys. Lett. 58, 1392 (1991).CrossRefGoogle Scholar
17.Hirvonen, J-P., Ruck, D., Yan, S., Mahiout, A., Torri, P. and Likonen, J.: Corrosion resistance of N-,Cr- or Cr+N-implanted AISI 420 stainless steel. Surf. Coat. Technol. 74–75, 760 (1995).CrossRefGoogle Scholar
18.Ashworth, V., Baxter, D., Grant, W.A., Procter, R.P.M. and Wellington, T.C.: The effect of ion implantation on the corrosion behavior of pure iron-II. Chromium ion implantation. Corros. Sci. 16, 775 (1976).Google Scholar
19.Zhu, H.N. and Liu, B.X.: CrSi2 films synthesized by high current Cr ion implantation and their physical properties. Appl. Surf. Sci. 161, 240 (2000).CrossRefGoogle Scholar
20.Han, S., Chen, H.Y., Chang, K.L., Weng, K.W., Wang, D.Y., Lu, F.H. and Shih, H.C.: Effects of MEVVA-implanted chromium on the structure and properties of CrN film. Thin Solid Films 447–448, 425 (2004).CrossRefGoogle Scholar
21.Liu, C., Bi, Q. and Matthews, A.: EIS comparison on corrosion performance of PVD TiN and CrN coated mild steel in 0.5N NaCl aqueous solution. Corros. Sci. 43, 1953 (2001).CrossRefGoogle Scholar
22.Souto, R.M. and Alanyali, H.: Electrochemical characteristics of steel coated with TiN and TiAlN coatings. Corros. Sci. 42, 2201 (2000).CrossRefGoogle Scholar
23.Liu, C., Bi, Q., Leyland, A. and Matthews, A.: An electrochemical impedance spectroscopy study of the corrosion behaviour of PVD coated steels in 0.5N NaCl aqueous solution: Part I. Establishment of equivalent circuits for EIS data modeling. Corros. Sci. 45, 1243 (2003).CrossRefGoogle Scholar
24.Liu, C., Bi, Q., Leyland, A. and Matthews, A.: An electrochemical impedance spectroscopy study of the corrosion behaviour of PVD coated steels in 0.5N NaCl aqueous solution: Part II. EIS interpretation of corrosion behaviour. Corros. Sci. 45, 1257 (2003).CrossRefGoogle Scholar
25.Merl, D.K., Panjan, P., Čekada, M. and Maček, M.: The corrosion behavior of Cr-(C,N) PVD hard coatings deposited on various substrates. Electrochim. Acta . 49, 1527 (2004).CrossRefGoogle Scholar