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Effect of LiYO2 on the synthesis and pressureless sintering of Y2SiO5

Published online by Cambridge University Press:  31 January 2011

Ziqi Sun ,
Yanchun Zhou  and
Meishuan Li
Ziqi Sun
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, People’s Republic of China; and Graduate School of Chinese Academy of Sciences, Beijing 100039, People’s Republic of China
Yanchun Zhou*
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, People’s Republic of China
Meishuan Li
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

Y2SiO5 has potential applications as a high-temperature structural ceramic and environmental/thermal barrier coating. In this work, we synthesized single-phase Y2SiO5 powders utilizing a solid–liquid reaction method with LiYO2 as an additive. The reaction path of the Y2O3/SiO2/LiYO2 mixture with variation in temperatures and the role of the LiYO2 additive on preparation process were investigated in detail. The powders obtained by this method have good sinterability. Through a pressureless sintering process, almost fully dense Y2SiO5 bulk material was achieved with a very high density of 99.7% theoretical.

Keywords

CeramicSinteringReactivity
Type
Articles
Information
Journal of Materials Research , Volume 23 , Issue 3 , March 2008 , pp. 732 - 736
Copyright
Copyright © Materials Research Society 2008

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References

REFERENCES

1Warshaw, J., Roy, R.: Crystal chemistry of rare earth sesquioxides, aluminates and silicates. Prog. Sci. Technol. Rare Earths 1, 203 1963Google Scholar
2Shin, S.H., Jeon, D.Y., Suh, K.S.: Emission band shift of the cathodoluminescence of Y2SiO5:Ce phosphor affected by its concentration. Jpn. J. Appl. Phys. 40, 4715 2001CrossRefGoogle Scholar
3Bottger, T., Sun, Y., Reinemer, G.J., Core, R.L.: Diode laser frequency stabilization to transient spectral holes and spectral diffusion in Er3+:Y2SiO5 at 1536 nm. J. Lumin. 94–95, 565 2001CrossRefGoogle Scholar
4Deka, C., Chai, B., Shimony, Y., Zhang, X., Munin, E., Bass, M.: Laser performance of Cr4+:Y2SiO5. Appl. Phys. Lett. 61, 2141 1992CrossRefGoogle Scholar
5Lange, F.F., Singhal, S.C., Kuznicki, R.C.: Phase relations and stability studies in the Si3N4–SiO2–Y2O3 pseudoternary system. J. Am. Ceram. Soc. 60, 249 1977CrossRefGoogle Scholar
6Gauckler, L.J., Hohnke, H., Tien, T.Y.: The system Si3N4–SiO2–Y2O3. J. Am. Ceram. Soc. 63, 35 1980CrossRefGoogle Scholar
7Levin, E.M., Robbins, C.R., McMurdie, H.F.: Phase Diagrams for Ceramists—1969 Supplement The American Ceramic Society, Inc. Columbus, OH 1969 Fig. 2388, p. 76Google Scholar
8Wagner, S., Seifert, H.J., Aldinger, F.: High-temperature reaction of C/C-SiC composites with ceramic coatings, in Proceedings of the 10th International Conference on Advan. in Mater. & Mater. Proc. (ICAMMP-2002) Tata McGraw-Hill, New Delhi, 2002 71Google Scholar
9Ogura, Y., Kondo, M., Morimoto, T., Notomi, A., Sekigawa, T.: Oxygen permeability of Y2SiO5. Mater. Trans. 42, 1124 2001CrossRefGoogle Scholar
10Nowok, J.W., Kay, J.P., Kulas, R.J.: Thermal expansion and high-temperature phase transformation of the yttrium silicate Y2SiO5. J. Mater. Res. 16, 2251 2001CrossRefGoogle Scholar
11Wang, J., Tian, S., Li, G., Liao, F., Jing, X.: Preparation and x-ray characterization of low-temperature phases of R2SiO5 (R = rare earth elements). Mater. Res. Bull. 36, 1855 2005CrossRefGoogle Scholar
12Seifert, H.J., Wagner, S., Fabrichnaya, O., Lukas, H., Aldinger, F., Ullmann, T., Schmucker, M., Schneider, H.: Yttrium silicate coatings on chemical vapor deposition–SiC-precoated C/C–SiC: Thermodynamic assessment and high-temperature investigation. J. Am. Ceram. Soc. 88, 424 2005CrossRefGoogle Scholar
13Matovic, B., Rixecker, G., Aldinger, F.: Densification of Si3N4 with LiYO2 additive. J. Am. Ceram. Soc. 87, 546 2004CrossRefGoogle Scholar
14Matovic, B., Rixecker, G., Boskovic, S., Aldinger, F.: Effect of LiYO2 addition on sintering behavior and indentation properties of silicon nitride ceramics. Int. J. Mater. Res. 97, 1268 2006CrossRefGoogle Scholar
15Fukuda, K., Matrubara, H.: Anisotropic thermal expansion in yttrium silicate. J. Mater. Res. 18, 1715 2003CrossRefGoogle Scholar
16Kim, S., Sanders, T.: Thermodynamic modeling of phase diagrams in binary alkali silicate system. J. Am. Ceram. Soc. 74, 1833 1991CrossRefGoogle Scholar
17Bondar, I.A., Koroleva, N.K. ACerS–NIST Phase Equilibria Diagrams,, CD-ROM database, V3.0.1 (ACS, Westerville, OH, 2004 Fig. 06576Google Scholar
18Zhou, Y., Petric, A.: Thermodynamic stability of the lithium zirconates and lithium yttrium. J. Phys. Chem. Solids 55, 493 1994CrossRefGoogle Scholar