Hostname: page-component-cd9895bd7-q99xh Total loading time: 0 Render date: 2024-12-27T12:36:10.621Z Has data issue: false hasContentIssue false

Effect of cooling rate on growth and transformation of primary Mg2Si in Al–Mg2Si in situ composites

Published online by Cambridge University Press:  11 May 2018

Dongtao Wang
Affiliation:
Key Laboratory of Electromagnetic Processing of Materials, Ministry of Education, Northeastern University, Shenyang 110004, People’s Republic of China
Haitao Zhang*
Affiliation:
Key Laboratory of Electromagnetic Processing of Materials, Ministry of Education, Northeastern University, Shenyang 110004, People’s Republic of China
Cheng Guo
Affiliation:
Key Laboratory of Electromagnetic Processing of Materials, Ministry of Education, Northeastern University, Shenyang 110004, People’s Republic of China
Hailin Wu
Affiliation:
Key Laboratory of Electromagnetic Processing of Materials, Ministry of Education, Northeastern University, Shenyang 110004, People’s Republic of China
Jianzhong Cui
Affiliation:
Key Laboratory of Electromagnetic Processing of Materials, Ministry of Education, Northeastern University, Shenyang 110004, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

In this paper, the morphology transition and the growth process of the primary Mg2Si in the Al–Mg2Si in situ composites were three-dimensionally investigated by observing the extracted Mg2Si particles. The primary Mg2Si transforms from perfect octahedron to truncated octahedron with increasing cooling rate. Combining with the crystal morphologies obtained at different growth stages, the growth mechanism of octahedral Mg2Si was discussed. In the early growth stage of the octahedral Mg2Si, the secondary branches preferentially grow on the advancing tips of the first branches. Then, the hollows in the {111} faces shrink gradually and the octahedral Mg2Si forms finally. With the increase of Mg2Si content, dendritic Mg2Si phases were observed and the truncated octahedron Mg2Si connect mutually to form the complicated morphology at low cooling rate. The high cooling rate transforms the morphology of the Mg2Si crystal. The growth rates of the 〈100〉 and 〈111〉 axes can be manipulated by adjusting the cooling rates, which are responsible for the evolution of the Mg2Si crystals.

Type
Article
Copyright
Copyright © Materials Research Society 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Chen, L., Wang, H.Y., Liu, K., Wang, C., Luo, D., and Jiang, Q.C.: Growth of Mg2Si crystals shaped by {100} and {111} facets from Al–Mg–Si melts in the presence of calcium. CrystEngComm 19, 3058 (2017).CrossRefGoogle Scholar
Wang, L. and Qin, X.Y.: The effect of mechanical milling on the formation of nanocrystalline Mg2Si through solid-state reaction. Scr. Mater. 49, 243 (2003).CrossRefGoogle Scholar
Takeuchi, S., Hashimoto, T., and Suzuki, K.: Plastic deformation of Mg2Si with the C1 structure. Intermetallics 4, S147 (1996).CrossRefGoogle Scholar
He, Y., Zhang, H., Li, T., and Wang, X.: Calculation of Jackson’s factor of Mg2Si in Mg melt using coordination polyhedron. J. Alloys Compd. 581, 494 (2013).CrossRefGoogle Scholar
Qin, Q.D. and Zhao, Y.G.: Nonfaceted growth of intermetallic Mg2Si in Al melt during rapid solidification. J. Alloys Compd. 462, L28 (2008).CrossRefGoogle Scholar
Zhang, Y., Deng, B., Zhang, T., Gao, D., and Xu, A.W.: Effects of Cu2O polyhedral microcrystals on photocatalytic activity. J. Phys. Chem. C 114, 5073 (2010).CrossRefGoogle Scholar
Huang, W.C., Lyu, L.M., Yang, Y.C., and Huang, M.H.: Synthesis of Cu2O nanocrystals from cubic to rhombic dodecahedral structures and their comparative photocatalytic activity. J. Am. Chem. Soc. 134, 1261 (2012).CrossRefGoogle ScholarPubMed
Wang, H., Zhu, J.N., Li, J., Li, C., Zha, M., Wang, C., Yang, Z.Z., and Jiang, Q.C.: Refinement and modification of primary Mg2Si in Al–20Mg2Si alloy by a combined addition of yttrium and antimony. CrystEngComm 19, 6365 (2017).CrossRefGoogle Scholar
Chen, L., Wang, H.Y., Luo, D., Zhang, H.Y., Liu, B., and Jiang, Q.C.: Synthesis of octahedron and truncated octahedron primary Mg2Si by controlling the Sb contents. CrystEngComm 15, 1787 (2013).CrossRefGoogle Scholar
Chen, L., Wang, H.Y., Li, Y.J., Zha, M., and Jiang, Q.C.: Morphology and size control of octahedral and cubic primary Mg2Si in Mg–Si system by regulating Sr contents. CrystEngComm 16, 448 (2013).CrossRefGoogle Scholar
Nordin, N.A., Farahany, S., Ourdjini, A., Bakar, T.A.A., and Hamzah, E.: Refinement of Mg2Si reinforcement in a commercial Al–20% Mg2Si in situ composite with bismuth, antimony and strontium. Mater. Charact. 86, 97 (2013).CrossRefGoogle Scholar
Tebib, M., Samuel, A.M., Ajersch, F., and Chen, X.G.: Effect of P and Sr additions on the microstructure of hypereutectic Al–15Si–14Mg–4Cu alloy. Mater. Charact. 89, 112 (2014).CrossRefGoogle Scholar
Moussa, M.E., Waly, M.A., and El-Sheikh, A.M.: Effect of Ca addition on modification of primary Mg2Si, hardness and wear behavior in Mg–Si hypereutectic alloys. J. Magnesium Alloys 2, 230 (2014).CrossRefGoogle Scholar
Kim, J.J., Kim, D.H., Shin, K.S., and Kim, N.J.: Modification of Mg2Si morphology in squeeze cast Mg–Al–Zn–Si alloys by Ca or P addition. Scr. Mater. 41, 333 (1999).CrossRefGoogle Scholar
Ourfali, M.F., Todd, I., and Jones, H.: Effect of solidification cooling rate on the morphology and number per unit volume of primary Mg2Si particles in a hypereutectic Al–Mg–Si alloy. Metall. Mater. Trans. A 36, 1368 (2005).CrossRefGoogle Scholar
Wang, H.Y., Yu, H.C., Li, C., Zha, M., Wang, C., and Jiang, Q.C.: Morphology evolution of primary Mg2Si in Al–20Mg2Si–0.1Ca alloys prepared with various solidification cooling rates. CrystEngComm 19, 1680 (2017).CrossRefGoogle Scholar
Zhang, J., Fan, Z., Wang, Y.Q., and Zhou, B.L.: Effect of cooling rate on the microstructure of hypereutectic Al–Mg2Si alloys. J. Mater. Sci. 19, 1825 (2000).Google Scholar
Shimosaka, D., Kumai, S., Casarotto, F., and Watanabe, S.: Effect of cooling rates during solidification of Al–5.5% Mg–2.3% Si–0.6% Mn and Al–13% Mg2Si pseudo-binary alloys on their secondary-particle morphology and tear toughness. J. Jpn. Inst. Light Metals 61, 262 (2011).CrossRefGoogle Scholar
Reinfried, N., Schmidt, J., Kieback, B., and Grin, Y.: Spark plasma preparation of Mg2Si and Mg2Si–Mg composite. Metallkunde 85, 372 (1994).Google Scholar
Zhang, J.T., Zhao, Y.G., Xu, X.F., and Liu, X.B.: Effect of ultrasonic on morphology of primary Mg2Si in in situ Mg2Si/Al composite. Trans. Nonferrous Met. Soc. China 23, 2852 (2013).CrossRefGoogle Scholar
Li, C., Wu, Y.Y., Li, H., and Liu, X.F.: Morphological evolution and growth mechanism of primary Mg2Si phase in Al–Mg2Si alloys. Acta Mater. 59, 1058 (2011).CrossRefGoogle Scholar
Yu, H.C., Wang, H.Y., Chen, L., Liu, F., Wang, C., and Jiang, Q.C.: Heterogeneous nucleation of Mg2Si on Ca2Sb nucleus in Al–Mg–Si alloys. CrystEngComm 17, 7048 (2015).CrossRefGoogle Scholar
Li, G.H., Gill, H.S., and Varin, R.A.: Magnesium silicide intermetallic alloys. Metall. Mater. Trans. A 24, 2383 (1993).CrossRefGoogle Scholar
Xu, C.L., Wang, H.Y., Qiu, F., Yang, Y.F., and Jiang, Q.C.: Cooling rate and microstructure of rapidly solidified Al–20 wt% Si alloy. Mater. Sci. Eng., A 417, 275 (2006).CrossRefGoogle Scholar
Wang, R.Y., Lu, W.H., and Hogan, L.M.: Faceted growth of silicon crystals in Al–Si alloys. Metall. Mater. Trans. A 28, 1233 (1997).CrossRefGoogle Scholar
Qin, Q. and Li, W.: The formation and characterization of the primary Mg2Si dendritic phase in hypereutectic Al–Mg2Si alloys. Mater. Trans. 57, 85 (2016).CrossRefGoogle Scholar
Wang, W., Bian, X.F., Qin, J., and Syliusarenko, S.I.: The atomic-structure changes in Al–16% Si alloy above the liquidus. Metall. Mater. Trans. A 31, 2163 (2000).CrossRefGoogle Scholar
Xu, C.L., Wang, H.Y., Liu, C., and Jiang, Q.C.: Growth of octahedral primary silicon in cast hypereutectic Al–Si alloys. J. Cryst. Growth 291, 540 (2006).CrossRefGoogle Scholar