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Direct formation of nanostructured graphitic carbon from an acrylic ion-exchange resin at 600°C

Published online by Cambridge University Press:  02 December 2011

Guoqiang He ,
Xueming Ma ,
Zhengbing Xu ,
Zaoxue Yan ,
Hui Meng  and
Pei K. Shen
Guoqiang He
Affiliation:
The Key Laboratory of Low-carbon Chemistry & Energy Conservation of Guangdong Province, State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-Sen University, Guangzhou 510275, People’s Republic of China
Xueming Ma
Affiliation:
The Key Laboratory of Low-carbon Chemistry & Energy Conservation of Guangdong Province, State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-Sen University, Guangzhou 510275, People’s Republic of China
Zhengbing Xu
Affiliation:
Key Laboratory of Nonferrous Metal Materials and New Processing Technology, Ministry of Education, Guangxi University, Nanning, Guangxi 530004, People’s Republic of China
Zaoxue Yan
Affiliation:
The Key Laboratory of Low-carbon Chemistry & Energy Conservation of Guangdong Province, State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-Sen University, Guangzhou 510275, People’s Republic of China
Hui Meng*
Affiliation:
The Key Laboratory of Low-carbon Chemistry & Energy Conservation of Guangdong Province, State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-Sen University, Guangzhou 510275, People’s Republic of China
Pei K. Shen*
Affiliation:
The Key Laboratory of Low-carbon Chemistry & Energy Conservation of Guangdong Province, State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-Sen University, Guangzhou 510275, People’s Republic of China
*
a)Address all correspondence to these authors. e-mail: [email protected]
b)e-mail: [email protected]
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Abstract

Graphitic carbon (GC) is prepared using an ion-exchange resin as carbon source at 600 °C. A Co salt is selected as the graphitization catalyst and is pre-exchanged onto the resin during the ion-exchange process. The GC is characterized by transmission electron microscopy, x-ray diffraction, Raman spectroscopy, and thermogravimetry. Analysis of the crystallization shows that graphitization can occur at a temperature of as low as 600 °C, compared to the usual temperature of above 2000 °C in industry and above 1000 °C in literature. Different carbon structures have been found for different pretreatments of the resin and different heat treatment temperatures. This energy-saving method is an important breakthrough for the economic mass production of GC.

Keywords

CarbonizationChemical synthesisEnergetic material
Type
Articles
Information
Journal of Materials Research , Volume 26 , Issue 24 , 28 December 2011 , pp. 3083 - 3090
Copyright
Copyright © Materials Research Society 2011

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