Hostname: page-component-586b7cd67f-tf8b9 Total loading time: 0 Render date: 2024-11-28T10:43:30.989Z Has data issue: false hasContentIssue false
  • English
  • Français

Development of quaternary Fe–B–Y–Nb bulk glassy alloys with high glass-forming ability

Published online by Cambridge University Press:  03 March 2011

Dong Ho Kim ,
Jin Man Park ,
Do Hyang Kim  and
Won Tae Kim
Dong Ho Kim
Affiliation:
Center for Non-crystalline Materials, Department of Metallurgical Engineering, Yonsei University, Seodaemun-gu, Seoul 120-749, Korea
Jin Man Park
Affiliation:
Center for Non-crystalline Materials, Department of Metallurgical Engineering, Yonsei University, Seodaemun-gu, Seoul 120-749, Korea
Do Hyang Kim*
Affiliation:
Center for Non-crystalline Materials, Department of Metallurgical Engineering, Yonsei University, Seodaemun-gu, Seoul 120-749, Korea
Won Tae Kim
Affiliation:
Applied Science Division, Chongju University, Chongju 360-764, Korea
*
a) Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

The effects of niobium (Nb) addition on the glass-forming ability (GFA), crystallization behavior, and compressive mechanical property of iron (Fe)–boron (B)–yttrium (Y) alloys have been investigated. Among the (Fe71.2B24Y4.8)100−xNbx (x = 0, 2, 4, 6, 8) alloys investigated, (Fe71.2B24Y4.8)96Nb4 exhibits the highest GFA, enabling the formation of glassy rods with a maximum diameter of 7 mm, which is the largest among quaternary Fe-based alloys. The comparison of the crystallization behavior of the alloys shows that the formation of metastable Fe23B6 phase during crystallization in the (Fe71.2B24Y4.8)96Nb4 alloy can suppress the formation of other stable crystalline phases such as α-Fe, enhancing the stability of the glass phase. The present results show that the attainment of a significantly high GFA is possible even in a quaternary Fe-based alloy system by properly tailoring the competing crystalline phase by the modification of liquid chemistry.

Keywords

AlloyAmorphousFe
Type
Articles
Information
Journal of Materials Research , Volume 22 , Issue 2 , September 2006 , pp. 471 - 477
Copyright
Copyright © Materials Research Society 2007

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Johnson, W.L.: Bulk amorphous metal: An emerging engineering material. JOM 54, 40 (2002).CrossRefGoogle Scholar
2Nishiyama, N., Amiya, K., and Inoue, A.: Bulk metallic glasses for industrial products. Mater. Trans. 45, 1245 (2004).CrossRefGoogle Scholar
3Park, E.S. and Kim, D.H.: Design of bulk metallic glasses with high glass forming ability and enhancement of plasticity in metallic glass matrix composite. Met. Mater.-Int. 11, 19 (2005).CrossRefGoogle Scholar
4Lee, K.S. and Chang, Y.S.: Deformation behavior of Zr-based bulk metallic glass in an undercooled liquid state under compressive loading. Met. Mater.-Int. 11, 53 (2005).CrossRefGoogle Scholar
5Inoue, A. and Shen, B.L.: Formation and soft magnetic properties of Fe-B-Si-Zr bulk glassy alloys with high saturation magnetization above 1.5 T. Mater. Trans. 43, 2350 (2002).CrossRefGoogle Scholar
6Yi, S., Kim, K.B., and Sohn, H.S.: Fabrication of Fe-based bulk amorphous alloys using hot metal and commercial ferro-alloys. Mater. Trans. 46, 2237 (2005).CrossRefGoogle Scholar
7Stoica, M., Eckert, J., Roth, S., Zhang, Z.F., Schultz, L., and Wang, W.H.: Mechanical behavior of Fe65.5Cr4Mo4Ga4P12C5B5.5 bulk metallic glass. Intermet 13, 764 (2005).CrossRefGoogle Scholar
8Inoue, A. and Shen, B.L.: A new Fe-based bulk glassy alloy with outstanding mechanical properties. Adv. Mater. 16, 2189 (2004).CrossRefGoogle Scholar
9Pang, S.J., Jhang, T., Asami, K., and Inoue, A.: Bulk glassy Fe-Cr-Mo-C-B alloys with high corrosion resistance. Corros. Sci. 44, 1847 (2002).CrossRefGoogle Scholar
10Inoue, A., Zhang, T., Koshiba, H., and Mikino, A.: New bulk amorphous Fe-(Co, Ni)-M-B (M = Zr, Hf, Nb, Ta, Mo, W) alloys with good soft magnetic properties. J. Appl. Phys. 83, 6326 (1998).CrossRefGoogle Scholar
11Lu, Z.P., Liu, C.T., Carmichael, C.A., Porter, W.D., and Deevi, S.C.: Bulk glass formation in an Fe-based Fe-Y-Zr-M (M = Cr, Co, Al)-Mo-B system. J. Mater. Res. 19, 921 (2004).CrossRefGoogle Scholar
12Inoue, A., Shen, B.L., and Chang, C.T.: Super-high strength of over 4000 MPa for Fe-based bulk glassy alloys in [(Fe1−xCox)0.75B0.2Si0.05]96Nb4 system. Acta Mater. 52, 4093 (2004).CrossRefGoogle Scholar
13Ponnambalam, V., Poon, S.J., and Shiflet, G.J.: Fe-based bulk metallic glasses with diameter thickness larger than one centimeter. J. Mater. Res. 19, 1320 (2004).CrossRefGoogle Scholar
14Lu, Z.P., Liu, C.T., Thompson, J.R., and Porter, W.T.: Structural amorphous steels. Phys. Rev. Lett. 92, 245503 (2004).CrossRefGoogle ScholarPubMed
15Stoica, M., Hajlaoui, K., Lemoulec, A., and Yavari, A.R.: New ternary Fe-based bulk metallic glass with high boron content. Philos. Mag. Lett. 86, 267 (2006).CrossRefGoogle Scholar
16Song, D.S., Kim, J-H., Fleury, E., Kim, W.T., and Kim, D.H.: Synthesis of ferromagnetic Fe-based bulk glassy alloys in the Fe-Nb-B-Y system. J. Alloys Compd. 389, 159 (2005).CrossRefGoogle Scholar
17Amiya, K., Urata, A., Nishiyama, N., and Inoue, A.: Fe-B-Si-Nb bulk metallic glasses with high strength above 4000 MPa and distinct plastic elongation. Mater. Trans. 45, 1214 (2004).CrossRefGoogle Scholar
18Zhang, J., Tan, H., Feng, Y.P., and Li, Y.: The effect of Y on glass forming ability. Scripta Mater. 53, 183 (2005).CrossRefGoogle Scholar
19Villars, P. and Calvert, L.D.: Pearson’s Hand Book of Crystallographic Data for Intermetallic Phases (ASM International, Materials Park, OH, 1991), pp. 350, 370.Google Scholar
20Boer, F.R., Boom, R., Mattens, W.C.M., Miedemaal, A.R., and Niessen, A.K.: Cohesion in Metals (North-Holland, Amsterdam, The Netherlands, 1989), pp. 217, 245.Google Scholar
21Imafuku, M., Sato, S., Koshiba, H., Matsubara, E., and Inoue, A.: Structural variation of Fe-Nb-B metallic glasses during crystallization process. Scripta Mater. 44, 2369 (2001).CrossRefGoogle Scholar
22Nakamura, T., Matsubara, E., Imafuku, M., Koshiba, H., Inoue, A., and Waseda, Y.: Structural study of amorphous Fe70M10B20 (M=Cr, W, Nb, Zr and Hf) alloys by x-ray diffraction. Mater. Trans. 42, 1530 (2001).CrossRefGoogle Scholar
23Zhang, Y.R. and Ramanujan, R.V.: The effect of niobium alloying additions on the crystallization of a Fe-Si-B-Nb alloy. J. Alloys Compd. 403, 197 (2005).CrossRefGoogle Scholar
24Inoue, A.: Stabilization of metallic supercooled liquid and bulk amorphous alloys. Acta Mater. 48, 279 (2000).CrossRefGoogle Scholar
25Lu, Z.P., Li, Y., and Ng, S.C.: Reduced glass transition temperature and glass forming ability of bulk glass forming alloys. J. Non-Cryst. Solids 270, 103 (2000).CrossRefGoogle Scholar
26Lu, Z.P. and Liu, C.T.: A new glass-forming ability criterion for bulk metallic glasses. Acta Mater. 50, 3501 (2002).CrossRefGoogle Scholar
27Inoue, A. and Takeuchi, A.: Recent progress in bulk glassy, nanoquasicrystalline and nanocrystalline alloys. Mater. Sci. Eng., A 375–377, 16 (2004).CrossRefGoogle Scholar