Hostname: page-component-cd9895bd7-lnqnp Total loading time: 0 Render date: 2024-12-29T12:50:27.988Z Has data issue: false hasContentIssue false
  • English
  • Français

Decoration of carbon nanotubes with gold nanoparticles by electroless deposition process using ethylenediamine as a cross linker

Published online by Cambridge University Press:  09 September 2016

Aliyu Muhammad ,
Nor Azah Yusof ,
Reza Hajian  and
Jaafar Abdullah
Aliyu Muhammad
Affiliation:
Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, Serdang 43400, Selangor, Malaysia
Nor Azah Yusof*
Affiliation:
Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, Serdang 43400, Selangor, Malaysia; and Institute of Advanced Technology, Universiti Putra Malaysia, Serdang 43400, Selangor, Malaysia
Reza Hajian*
Affiliation:
Institute of Advanced Technology, Universiti Putra Malaysia, Serdang 43400, Selangor, Malaysia
Jaafar Abdullah
Affiliation:
Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, Serdang 43400, Selangor, Malaysia; and Institute of Advanced Technology, Universiti Putra Malaysia, Serdang 43400, Selangor, Malaysia
*
a) Address all correspondence to these authors. e-mail: [email protected]
b) e-mail: [email protected]
Get access

Abstract

Herein, we present a method for decorating multi-walled carbon nanotubes (MWCNTs) with gold nanoparticles (AuNPs) using ethylenediamine (en) as a linker between MWCNTs and AuNPs. The amine group in en is as growth points for synthesis of AuNPs through electrostatic attraction between the amine groups and ${\rm{AuCl}}_4^ -$ anion while sodium citrate act as reducing agent. The influence of HAuCl4 concentration on the size and distribution of AuNPs in the structure of the Au-decorated nanotubes were investigated. Morphology of the decorated nanotubes was characterized by field emission scanning electron microscopy and transmission electron microscopy while the elemental composition of the decorated tubes and crystallography were investigated by energy dispersive x-ray, x-ray diffraction, Raman spectroscopy, and Fourier transform infrared techniques. Cyclic voltammetric and electrochemical impedance spectroscopic analysis revealed that the Au-decorated nanotubes have increased the electro-active surface area and conductivity of electrochemical substrate.

Keywords

conductivityelectro-active surface areacharacterization
Type
Articles
Information
Journal of Materials Research , Volume 31 , Issue 18: Focus Section: Reinventing Boron Chemistry for the 21st Century , 28 September 2016 , pp. 2897 - 2905
Check for updates
Copyright
Copyright © Materials Research Society 2016 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Dai, H.: Carbon nanotubes: Synthesis, integration, and properties. Acc. Chem. Res. 35, 1035 (2002).Google Scholar
Ajayan, P.M. and Zhou, O.Z.: Applications of carbon nanotubes. In Topics in Applied Physics, Vol. 80: Carbon Nanotubes: Synthesis, Structure, Properties, and Applications, M.S. Dresselhaus, G. Dresselhaus, and P. Avouris, eds. (Springer Berlin Heidelberg, Berlin, 2001); pp. 391–425.Google Scholar
Ahmadzadeh Tofighy, M. and Mohammadi, T.: Nitrate removal from water using functionalized carbon nanotube sheets. Chem. Eng. Res. Des. 90(11), 1815 (2012).Google Scholar
Rezaei, B. and Damiri, D.: Using of multi-walled carbon nanotubes electrode for adsorptive stripping voltammetric determination of ultratrace levels of RDX explosive in the environmental samples. J. Hazard. Mater. 183(1–3), 138 (2010).Google Scholar
Afkhami, A., Khoshsafar, H., Bagheri, H., and Madrakian, T.: Construction of a carbon ionic liquid paste electrode based on multi-walled carbon nanotubes-synthesized Schiff base composite for trace electrochemical detection of cadmium. Mater. Sci. Eng., C 35, 8 (2014).Google Scholar
Chen, J. and Lu, G.: Carbon Nanotube-Nanoparticle Hybrid Structures (INTECH, Shanghai, 2007).Google Scholar
Georgakilas, V., Gournis, D., Tzitzios, V., Pasquato, L., Guldi, D.M., and Prato, M.: Decorating carbon nanotubes with metal or semiconductor nanoparticles. J. Mater. Chem. 17, 2679 (2007).Google Scholar
Clement, P., Hafaiedh, I., Parra, E.J., Thamri, A., Guillot, J., Abdelghani, A., and Llobet, E.: Iron oxide and oxygen plasma functionalized multi-walled carbon nanotubes for the discrimination of volatile organic compounds. Carbon 78, 510 (2014).Google Scholar
Clément, P., Korom, S., Struzzi, C., Parra, E.J., Bittencourt, C., Ballester, P., and Llobet, E.: Deep cavitand self-assembled on Au NPs-MWCNT as highly sensitive benzene sensing interface. Adv. Funct. Mater. 25, 4011 (2015).Google Scholar
Daniel, M.C. and Astruc, D.: Gold nanoparticles: Assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology. Chem. Rev. 104, 293 (2004).CrossRefGoogle Scholar
Hajian, R., Yusof, N.A., Faragi, T., and Shams, N.: Fabrication of an electrochemical sensor based on gold nanoparticles/carbon nanotubes as nanocomposite materials: Determination of myricetin in some drinks. PloS One 9(5), 1 (2014).Google Scholar
Li, F., Wang, Z., Shan, C., Song, J., Han, D., and Niu, L.: Preparation of gold nanoparticles/functionalized multiwalled carbon nanotube nanocomposites and its glucose biosensing application. Biosens. Bioelectron. 24, 1765 (2009).Google Scholar
Shi, Y., Yang, R., and Yuet, P.K.: Easy decoration of carbon nanotubes with well dispersed gold nanoparticles and the use of the material as an electrocatalyst. Carbon 47(4), 1146 (2009).Google Scholar
Downard, A.J., Tan, E.S.Q., and Yu, S.S.C.: Controlled assembly of gold nanoparticles on carbon surfaces. New J. Chem. 30, 1283 (2006).Google Scholar
Hou, X., Wang, L., Wang, X., and Li, Z.: Coating multiwalled carbon nanotubes with gold nanoparticles derived from gold salt precursors. Diamond Relat. Mater. 20(10), 1329 (2011).Google Scholar
Zhang, R., Wang, Q., Zhang, L., Yang, S., Yang, Z., and Ding, B.: The growth of uncoated gold nanoparticles on multiwalled carbon nanotubes. Colloids Surf., A 312, 136 (2008).Google Scholar
Li, N., Xu, Q., Zhou, M., Xia, W., Chen, X., Bron, M., Schuhmann, W., and Muhler, M.: Ethylenediamine-anchored gold nanoparticles on multi-walled carbon nanotubes: Synthesis and characterization. Electrochem. Commun. 12(7), 939 (2010).Google Scholar
Kongkanand, A., Vinodgopal, K., Kuwabata, S., and Kamat, P.V.: Highly dispersed Pt catalysts on single-walled carbon nanotubes and their role in methanol oxidation. J. Phys. Chem. B 110, 16185 (2006).Google Scholar
Murugesan, S., Myers, K., and Subramanian, V.R.: Amino-functionalized and acid treated multi-walled carbon nanotubes as supports for electrochemical oxidation of formic acid. Appl. Catal., B 103(3–4), 266 (2011).Google Scholar
Freitas, T.A., Mattos, A.B., Silva, B.V.M., and Dutra, R.F.: Amino-functionalization of carbon nanotubes by using a factorial design: Human cardiac troponin T immunosensing application. Biomed Res. Int. 2014, 929786 (2014).Google Scholar
Liang, S., Li, G., and Tian, R.: Multi-walled carbon nanotubes functionalized with a ultrahigh fraction of carboxyl and hydroxyl groups by ultrasound-assisted oxidation. J. Mater. Sci. 5(7), 3513 (2016).Google Scholar
Shah, P. and Murthy, C.N.: Studies on the porosity control of MWCNT/polysulfone composite membrane and its effect on metal removal. J. Membr. Sci. 437, 90 (2013).Google Scholar
Huang, Y.Y. and Terentjev, E.M.: Dispersion of carbon nanotubes: Mixing, sonication, stabilization, and composite properties. Polymers 4, 275 (2012).Google Scholar
Zhang, R., Hummelgard, M., and Olin, H.: Simple and efficient gold nanoparticles deposition on carbon nanotubes with controllable particle sizes. Mater. Sci. Eng., B 158, 48 (2009).Google Scholar
Islam, M.R., Bach, L.G., Nga, T.T., and Lim, K.T.: Covalent ligation of gold coated iron nanoparticles to the multi-walled carbon nanotubes employing click chemistry. J. Alloys Compd. 561, 201 (2013).CrossRefGoogle Scholar
Lngford, J.I. and Wilson, A.J.C.: Scherer after sixty years. J. Appl. Cryst. 11, 102 (1978).Google Scholar
Ghodselahi, T., Aghababaie, N., Mobasheri, H., and Salimi, K.Z.: Applied surface science fabrication and characterization and biosensor application of gold nanoparticles on the carbon nanotubes. Appl. Surf. Sci. 355, 1175 (2015).Google Scholar
Ferrari, A. and Basko, D.: Raman spectroscopy as a versatile tool for studying the properties of graphene. Nat. Nanotechnol. 8, 235 (2013).Google Scholar
Dresselhaus, M.S., Jorio, A., Hofmann, M., Dresselhaus, G., and Saito, R.: Perspectives on carbon nanotubes and graphene Raman spectroscopy. Nano Lett. 10(3), 751 (2010).Google Scholar
Zardini, H.Z., Amiri, A., Shanbedi, M., Maghrebi, M., and Baniadam, M.: Enhanced antibacterial activity of amino acids-functionalized multi walled carbon nanotubes by a simple method. Colloid Surf., B 92, 196 (2012).Google Scholar
Wang, J.: Analytical Electrochemistry (John Wiley & Sons, New York, 2006).Google Scholar
Bard, A.J. and Faulkner, L.R.: Electrochemical Methods: Fundamentals and Applications (John Wiley, New York, NY, 2000).Google Scholar
Jia, L. and Wang, H.: Electrochemical reduction synthesis of graphene/Nafion nanocomposite film and its performance on the detection of 8-hydroxy-2'-deoxyguanosine in the presence of uric acid. J. Electroanal. Chem. 705, 37 (2013).Google Scholar
Liu, Y., Yin, F., Long, Y., Zhang, Z., and Yao, S.: Study of the immobilization of alcohol dehydrogenase on Au-colloid modified gold electrode by piezoelectric quartz crystal sensor, cyclic voltammetry, and electrochemical impedance techniques. J. Colloid Interface Sci. 258, 75 (2003).Google Scholar