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The corrosion and oxidation behavior of Zr-based metallic glasses

Published online by Cambridge University Press:  28 May 2014

Yonglong Hu ,
Wenhuan Cao  and
Chanhung Shek
Yonglong Hu*
Affiliation:
Department of Physics and Materials Science, City University of Hong Kong, Kowloon Tong, Hong Kong 999077, China
Wenhuan Cao
Affiliation:
Department of Physics and Materials Science, City University of Hong Kong, Kowloon Tong, Hong Kong 999077, China
Chanhung Shek
Affiliation:
Department of Physics and Materials Science, City University of Hong Kong, Kowloon Tong, Hong Kong 999077, China
*
a) Address all correspondence to this author. e-mail: [email protected]
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Abstract

Zr-based bulk metallic glasses are promising engineering materials due to their good glass-forming abilities and unique combination of good strength (∼1.9 GPa) and medium stiffness. In this study, the corrosion behaviors of Zr–Co–Al–Ag BMGs, with silver content from 0 to 11 at.%, in NaCl and H2SO4 solutions were investigated. The corrosion resistance increased when the silver content increased. The oxidation behaviors of Zr–Co–Al–Ag BMGs were also studied. The oxidation kinetics of all the samples obeyed a two-stage parabolic rate law, which consisted of an initial transient oxidation followed by a steady-state oxidation stage. The addition of Ag was found to reduce the oxidation resistance of Zr–Co–Al–Ag BMGs. Some white nodules, possibly cobalt oxide, were observed when the Zr–Co–Al–Ag BMG with 8 at.% Ag was oxidized at high temperature.

Keywords

bulk metallic glassescorrosionoxidation
Type
Articles
Information
Journal of Materials Research , Volume 29 , Issue 11 , 14 June 2014 , pp. 1248 - 1255
Copyright
Copyright © Materials Research Society 2014 

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References

REFERENCES

Suryanarayana, C. and Inoue, A.: Bulk Metallic Glasses (CRC Press Inc, Boca Raton, 2010), pp. 307, 353, 383.Google Scholar
Zhang, C., Li, N., Pan, J., Guo, S.F., Zhang, M., and Liu, L.: Enhancement of glasses-forming ability and bio-corrosion resistance of Zr-Co-Al bulk metallic glasses by the addition of Ag. J. Alloys Compd. 504S, 163 (2010).Google Scholar
Jin, K.F. and Löffler, J.F.: Bulk metallic glass formation in Zr–Cu–Fe–Al alloys. Appl. Phys. Lett. 86, 241909 (2005).CrossRefGoogle Scholar
Liu, L., Qiu, C.L., Suna, M., Chen, Q., Chan, K.C., and Pang, G.K.H.: Improvements in the plasticity and biocompatibility of Zr–Cu–Ni–Al bulk metallic glass by the microalloying of Nb. Mater. Sci. Eng., A 449–451, 193 (2007).Google Scholar
Wang, J.G., Choi, B.W., Nieh, T.G., and Liu, C.T.: Nano-scratch behavior of a bulk Zr–10Al–5Ti–17.9Cu–14.6Ni amorphous alloy. J. Mater. Res. 15, 913 (2000).Google Scholar
Jiang, Q.K., Nie, X.P., Li, Y.G., Jin, Y., Chang, Z.Y., Huang, X.M., and Jiang, J.Z.: Ni-free Zr-based bulk metallic glasses with critical diameter above 20 mm. J. Alloys Compd. 443, 191 (2007).CrossRefGoogle Scholar
Zhang, X.F., Wang, Y.M., Qiang, J.B., Wang, Q., Wang, D.H., Li, D.J., Shek, C.H., and Dong, C.: Optimum Zr–Al–Co bulk metallic glass composition Zr53Al23.5Co23.5. Intermetallics 12, 1275 (2004).CrossRefGoogle Scholar
Zhang, T. and Inoue, A.: Formation, thermal and mechanical properties of bulk glassy alloys in Zr–Al–Co and Zr–Al–Co–Cu systems. Mater. Sci. Eng., A 375, 432 (2004).CrossRefGoogle Scholar
Zhang, T. and Inoue, A.: New glassy Zr-Al-Fe and Zr-Al-Co alloys with a large supercooled liquid region. Mater. Trans. 43, 267 (2002).CrossRefGoogle Scholar
Wada, T., Zhang, T., and Inoue, A.: Formation, thermal stability and mechanical properties in Zr-Al-Co bulk glassy alloys. Mater. Trans. 43, 2843 (2002).CrossRefGoogle Scholar
Pang, S.J., Zhang, T., Asami, K., and Inoue, A.: Formation, corrosion behavior, and mechanical properties of bulk glassy Zr-Al-Co-Nb alloys. J. Mater. Res. 18, 1652 (2003).CrossRefGoogle Scholar
Wada, T., Qin, F.X., Wang, X.M., Yoshimura, M., Inoue, A., Sugiyama, N., Ito, R., and Matsushita, N.: Formation and bioactivation of Zr-Al-Co bulk metallic glasses. J. Mater. Res. 24, 2941 (2009).CrossRefGoogle Scholar
Hua, N., Pang, S., Li, Y., Wang, J., Li, R., Georgarakis, K., Yavari, A.R., Vaughan, G., and Zhang, T.: Ni-and Cu-free Zr–Al–Co–Ag bulk metallic glasses with superior glass-forming ability. J. Mater. Res. 26, 539 (2011).CrossRefGoogle Scholar
Cao, W.H., Zhang, J.L., and Shek, C.H.: Oxidation behavior of Zr56Co28Al16 bulk metallic glasses. Corros. Sci. 65, 528 (2012).Google Scholar
Carvalho, F.L.S., Borges, C.S., Branco, J.R.T, and , M.M. Pereira, : Structure analysis of hydroxyapatite/bioactive glass composite coatings obtained by plasma spray processing. J. Non-Cryst. Solids 247, 64 (1999).CrossRefGoogle Scholar
Verne, E., Ferraris, M., Ventrella, A., Paracchini, L., Krajewski, A., and Ravaglioli, A.: Sintering and plasma spray deposition of bioactive glass-matrix composites for medical applications. J. Eur. Ceram. Soc. 18, 363 (1998).Google Scholar
Nie, X.P., Yang, X.H., Chen, L.Y., Yeap, K.B., Zeng, K.Y., Li, D., Pan, J.S., Wang, X.D., Cao, Q.P., Ding, S.Q., and Jiang, J.Z.: The effect of oxidation on the corrosion resistance and mechanical properties of a Zr-based metallic glass. Corros. Sci. 53, 3557 (2011).CrossRefGoogle Scholar
Nie, X.P., Yang, X.H., Ma, Y., Chen, L.Y., Yeap, K.B., Zeng, K.Y., Li, D., Pan, J.S., Wang, X.D., Cao, Q.P., Ding, S.Q., and Jiang, J.Z.: Thermal oxidation effect on corrosion behavior of Zr46Cu37.5Ag8.4Al8 bulk metallic glass. Intermetallics 22, 84 (2012).CrossRefGoogle Scholar
Tao, P.J., Yang, Y.Z., Bai, X.J., Mu, Z.X., Li, G.Q., Xie, Z.W., and Chen, X.C.: Study on implantation of Co ions in ZrCuNiAl bulk metallic glasses. Surf. Coat. Technol. 203, 1656 (2009).Google Scholar
Tao, P.J., Yang, Y.Z., Mu, Z.X., Chen, X.C., and Xie, Z.W.: Influences of ion implantation on non-isothermal crystallization behaviors of bulk metallic glasses. J. Alloys Compd. 479, 736 (2009).Google Scholar
Basu, A., Samant, A.N., Harimkar, S.P., Dutta Majumdar, J., Manna, I., and Narendra Dahotre, B.: Laser surface coating of Fe-Cr-Mo-Y-B-C bulk metallic glass composition on AISI 4140 steel. Surf. Coat. Technol. 202, 2623 (2008).CrossRefGoogle Scholar
Riahi, M.: Surface treatment of cast iron by adding different alloying elements to form a metallic glass structure layer using an industrial carbon dioxide laser. J. Mater. Process. Technol. 58, 3 (1996).Google Scholar
Vanysek, P.: Handbook of Chemistry and Physics, 88th ed. (CRC Press Inc, Boca Raton, 2007).Google Scholar
Kamachi Mudali, U., Baunack, S., Eckert, J., Schultz, L., and Gebert, A.: Pitting corrosion of bulk glass-forming zirconium-based alloys. J. Alloys Compd. 377, 290 (2004).CrossRefGoogle Scholar
Qin, C.L., Oak, J.J., Ohtsu, N., Asami, K., and Inoue, A.: XPS study on the surface films of a newly designed Ni-free Ti-based bulk metallic glass. Acta Mater. 55, 2057 (2007).CrossRefGoogle Scholar
Qin, C.L., Zeng, Y.Q., Louzguine, D.V., Nishiyama, N., and Inoue, A.: Corrosion resistance and XPS studies of Ni-rich Ni–Pd–P–B bulk glassy alloys. J. Alloys Compd. 504S, S172–S175 (2010).Google Scholar
Palit, G.C. and Elayaperumal, K.: Passivity and pitting of corrosion resistant pure metals Ta, Nb, Ti, Zr, Cr and Al in chloride solutions. Corros. Sci. 18, 169 (1978).Google Scholar
Hua, N., Huang, L., Wang, J., Cao, Y., He, W., Pang, S., and Zhang, T.: Corrosion behavior and in vitro biocompatibility of Zr–Al–Co–Ag bulk metallic glasses: An experimental case study. J. Non-Cryst. Solids 358, 1599 (2012).Google Scholar
Gaskell, D.R.: Introduction to the Thermodynamics of Materials, 4th ed. (Taylor and Francis, New York, 2003), p. 584.Google Scholar
Kai, W., Ren, I.F., Kao, P.C., Wang, R.F., Chuang, C.P., Freels, M.W., and Liaw, P.K.: Air‐Oxidation of a Cu45Zr45Al5Ag5 bulk metallic glass. Adv. Eng. Mater. 11, 380 (2009).CrossRefGoogle Scholar