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Copper(I) Halide Nanoparticle-dispersed Glasses Prepared by Copper Staining

Published online by Cambridge University Press:  03 March 2011

Kohei Kadono ,
Tatsuya Suetsugu ,
Takeshi Ohtani ,
Toshihiko Einishi ,
Takashi Tarumi  and
Tetsuo Yazawa
Kohei Kadono*
Affiliation:
National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan
Tatsuya Suetsugu
Affiliation:
Isuzu Glass Co., Ltd., Minami-Tsumori, Nishinari, Osaka 557-0063, Japan
Takeshi Ohtani
Affiliation:
Isuzu Glass Co., Ltd., Minami-Tsumori, Nishinari, Osaka 557-0063, Japan
Toshihiko Einishi
Affiliation:
Isuzu Glass Co., Ltd., Minami-Tsumori, Nishinari, Osaka 557-0063, Japan
Takashi Tarumi
Affiliation:
Isuzu Glass Co., Ltd., Minami-Tsumori, Nishinari, Osaka 557-0063, Japan
Tetsuo Yazawa
Affiliation:
University of Hyogo, Himeji 671-2201, Japan
*
a) Address correspondence to this author. e-mail: [email protected]
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Abstract

Copper(I) chloride and bromide nanoparticle-dispersed glasses were prepared by means of a conventional copper staining. The staining was performed by the following process: copper stain was applied on the surfaces of Cl−- or Br−-ion-containing borosilicate glasses, and the glasses were heat-treated at 510 °C for various times. Typical exciton bands observed in the absorption spectra of the glasses after the heat treatment indicated that CuCl and CuBr particles were formed in the surface region of the glasses. The average sizes of the CuCl and CuBr particles in the glasses heat-treated for 48 h were estimated at 4.8 and 2.7 nm, respectively. The nanoparticles were also characterized by x-ray diffraction and transmission electron microscopy. Depth profiles of Cu and CuBr concentration in the glass heat-treated for 48 h were measured. Copper decreased in concentration monotonously with depth, reaching up to 60 μm, while the CuBr concentration had a maximum at about 25 μm in depth.

Keywords

GlassNanoparticle
Type
Articles
Information
Journal of Materials Research , Volume 20 , Issue 9 , September 2005 , pp. 2480 - 2485
Copyright
Copyright © Materials Research Society 2005

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