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Comparative study of microstructures and mechanical properties of in situ Ti–TiB composites produced by selective laser melting, powder metallurgy, and casting technologies

Published online by Cambridge University Press:  17 June 2014

H. Attar
Affiliation:
School of Engineering, Edith Cowan University, Joondalup, Perth, Western Australia 6027, Australia; and IFW Dresden, Institute for Complex Materials, D-01171 Dresden, Germany
M. Bönisch
Affiliation:
IFW Dresden, Institute for Complex Materials, D-01171 Dresden, Germany
M. Calin
Affiliation:
IFW Dresden, Institute for Complex Materials, D-01171 Dresden, Germany
L.C. Zhang*
Affiliation:
School of Engineering, Edith Cowan University, Joondalup, Perth, Western Australia 6027, Australia
K. Zhuravleva
Affiliation:
IFW Dresden, Institute for Complex Materials, D-01171 Dresden, Germany; and TU Dresden, Institute of Materials Science, D-01062 Dresden, Germany
A. Funk
Affiliation:
IFW Dresden, Institute for Complex Materials, D-01171 Dresden, Germany; and TU Dresden, Institute of Materials Science, D-01062 Dresden, Germany
S. Scudino
Affiliation:
IFW Dresden, Institute for Complex Materials, D-01171 Dresden, Germany
C. Yang
Affiliation:
National Engineering Research Center of Near-net-shape Forming for Metallic Materials, South China University of Technology, Guangzhou 510640, China
J. Eckert
Affiliation:
IFW Dresden, Institute for Complex Materials, D-01171 Dresden, Germany; and TU Dresden, Institute of Materials Science, D-01062 Dresden, Germany
*
a)Address all correspondence to this author. e-mail: [email protected], [email protected]
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Abstract

This study presents results of selective laser melting (SLM), powder metallurgy (PM), and casting technologies applied for producing Ti–TiB composites from Ti–TiB2 powder. Diffraction patterns and microstructural investigations reveal that chemical reaction occurred between Ti and TiB2 during all the three processes, leading to the formation of Ti–TiB composites. The ultimate compressive strength of SLM-processed and cast samples are 1421 and 1434 MPa, respectively, whereas the ultimate compressive strengths of PM-processed 25%, 29%, and 36% porous samples are 510, 414, and 310 MPa, respectively. The Young's moduli of porous composite samples are 70, 45, and 23 GPa for 25%, 29%, and 36% porosity levels, respectively, and are lower than those of SLM-processed (145 GPa) and cast (142 GPa) samples. Fracture analysis of the SLM-processed and cast samples shows shear fracture and microcracks across the samples, whereas failure of porous samples occurs due to porosities and weak bonds among particles.

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Articles
Copyright
Copyright © Materials Research Society 2014 

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References

REFERENCES

Geetha, M., Singh, A.K., Asokamani, R., and Gogia, A.K.: Ti based biomaterials, the ultimate choice for orthopaedic implants – A review. Prog. Mater. Sci. 54(3), 397 (2009).CrossRefGoogle Scholar
Qin, Y., Geng, L., and Ni, D.: Dry sliding wear behavior of extruded titanium matrix composite reinforced by in situ TiB whisker and TiC particle. J. Mater. Sci. 46(14), 4980 (2011).CrossRefGoogle Scholar
Cui, Z.D., Zhu, S.L., Man, H.C., and Yang, X.J.: Microstructure and wear performance of gradient Ti/TiN metal matrix composite coating synthesized using a gas nitriding technology. Surf. Coat. Technol. 190(2), 309 (2005).CrossRefGoogle Scholar
Lu, W., Zhang, D., Zhang, X., Wu, R., Sakata, T., and Mori, H.: Microstructural characterization of TiC in in situ synthesized titanium matrix composites prepared by common casting technique. J. Alloys Compd. 327(1), 248 (2001).Google Scholar
Fromentin, J.F., Debray, K., Le Petitcorps, Y., Martin, E., and Quenisset, J.M.: Interfacial zone design in titanium-matrix composites reinforced by SiC filaments. Compos. Sci. Technol. 56(7), 767 (1996).Google Scholar
Jeong, H.W., Kim, S.J., Hyun, Y.T., and Lee, Y.T.: Densification and compressive strength of in-situ processed Ti/TiB composites by powder metallurgy. Met. Mater. Int. 8(1), 25 (2002).CrossRefGoogle Scholar
Chandran, K.S.R., Panda, K.B., and Sahay, S.S.: TiBw-reinforced Ti composites: Processing, properties, application prospects, and research needs. JOM 56(5), 42 (2004).Google Scholar
Gorsse, S., Petitcorps, Y.L., Matar, S., and Rebillat, F.: Investigation of the Young's modulus of TiB needles in situ produced in titanium matrix composite. Mater. Sci. Eng., A 340(1), 80 (2003).CrossRefGoogle Scholar
Gofrey, T.M.T., Goodwin, P.S., and Ward-Close, C.M.: Titanium particulate metal matrix composites–Reinforcement, production methods, and mechanical properties. Adv. Eng. Mater. 2(3), 85 (2000).Google Scholar
Wei, S., Zhang, Z.H., Wang, F.C., Shen, X.B., Cai, H.N., Lee, S.K., and Wang, L.: Effect of Ti content and sintering temperature on the microstructures and mechanical properties of TiB reinforced titanium composites synthesized by SPS process. Mater. Sci. Eng., A 560, 249 (2013).CrossRefGoogle Scholar
Morsi, K. and Patel, V.V.: Processing and properties of titanium–titanium boride (TiBw) matrix composites—A review. J. Mater. Sci. 42(6), 2037 (2007).Google Scholar
Tjong, S.C. and Ma, Z.Y.: Microstructural and mechanical characteristics of in situ metal matrix composites. Mater. Sci. Eng., R 29(3), 49 (2000).Google Scholar
Bolzoni, L., Esteban, P.G., Ruiz-Navas, E.M., and Gordo, E.: Mechanical behaviour of pressed and sintered titanium alloys obtained from master alloy addition powders. J. Mech. Behav. Biomed. Mater. 15, 33 (2012).CrossRefGoogle ScholarPubMed
Zhu, J., Kamiya, A., Yamada, T., Watazu, A., Shi, W., and Naganuma, K.: Effect of silicon addition on microstructure and mechanical properties of cast titanium alloys. Mater. Trans. 42(2), 336 (2001).CrossRefGoogle Scholar
Campoli, G., Borleffs, M.S., Yavari, S.A., Wauthle, R., Weinans, H., and Zadpoor, A.A.: Mechanical properties of open-cell metallic biomaterials manufactured using additive manufacturing. Mater. Des. 49, 957 (2013).CrossRefGoogle Scholar
Levy, G.N., Schindel, R., and Kruth, J.P.: Rapid manufacturing and rapid tooling with layer manufacturing (LM) technologies, state of the art and future perspectives. CIRP Ann.-Manuf. Technol. 52(2), 589 (2003).Google Scholar
Attar, H., Calin, M., Zhang, L.C., Scudino, S., and Eckert, J.: Manufacture by selective laser melting and mechanical behavior of commercially pure titanium. Mater. Sci. Eng., A 593, 170 (2014).CrossRefGoogle Scholar
Zhang, L.C., Klemm, D., Eckert, J., Hao, Y.L., and Sercombe, T.B.: Manufacture by selective laser melting and mechanical behavior of a biomedical Ti–24Nb–4Zr–8Sn alloy. Scr. Mater. 65(1), 21 (2011).Google Scholar
Zhang, L.C. and Sercombe, T.B.: Selective laser melting of low-modulus biomedical Ti-24Nb-4Zr-8Sn Alloy: Effect of laser point distance. Key Eng. Mater. 520, 226 (2012).CrossRefGoogle Scholar
Attar, H., Bönisch, M., Calin, M., Zhang, L.C., Scudino, S., and Eckert, J.: Selective laser melting of in situ titanium-titanium boride composites: Processing, microstructure and mechanical properties. Acta Mater. 76, 13 (2014).CrossRefGoogle Scholar
Gu, D., Hagedorn, Y.C., Meiners, W., Wissenbach, K., and Poprawe, R.: Nanocrystalline TiC reinforced Ti matrix bulk-form nanocomposites by selective laser melting (SLM): Densification, growth mechanism and wear behavior. Compos. Sci. Technol. 71, 1612 (2011).CrossRefGoogle Scholar
Prashanth, K.G., Scudino, S., Klauss, H.J., Surreddi, K.B., Löber, L., Wang, Z., Chaubey, A.K., Kühn, U., and Eckert, J.: Microstructure and mechanical properties of Al-12Si produced by selective laser melting: Effect of heat treatment. Mater. Sci. Eng., A 590, 153 (2014).CrossRefGoogle Scholar
Thijs, L., Kempen, K., , K.J.P.and Van Humbeeck, J.: Fine-structured aluminium products with controllable texture by selective laser melting of pre-alloyed AlSi10Mg powder. Acta Mater. 61, 1809 (2013).Google Scholar
Wang, X.J., Zhang, L.C., Fang, M.H., and Sercombe, T.B.: The effect of atmosphere on the structure and properties of a selective laser melted Al-12Si alloy. Mater. Sci. Eng., A 597, 370 (2014).Google Scholar
Feng, H., Jia, D., and Zhou, Y.: Spark plasma sintering reaction synthesized TiB reinforced titanium matrix composites. Composites Part A 36(5), 558 (2005).Google Scholar
Galvan, D., Ocelik, V., Pei, Y., Kooi, B.J., De Hosson, J.T.M., and Ramous, E.: Microstructure and properties of TiB/Ti-6Al-4V coatings produced with laser treatments. J. Mater. Eng. Perform. 13(4), 406 (2004).CrossRefGoogle Scholar
Heinl, P., Müller, L., Körner, C., Singer, R.F., and Müller, F.A.: Cellular Ti–6Al–4V structures with interconnected macro porosity for bone implants fabricated by selective electron beam melting. Acta Biomater. 4(5), 1536 (2008).CrossRefGoogle ScholarPubMed
Kobashi, M., Kuze, K., and Kanetake, N.: Cell structure control of porous titanium composite synthesized by combustion reaction. Adv. Eng. Mater. 8(9), 836 (2006).Google Scholar
Chen, Y.J., Feng, B., Zhu, Y.P., Weng, J., Wang, J.X., and Lu, X.: Fabrication of porous titanium implants with biomechanical compatibility. Mater. Lett. 63(30), 2659 (2009).CrossRefGoogle Scholar
Gu, D., Hagedorn, Y.-C., Meiners, W., Meng, G., Batista, R.J.S., Wissenbach, K., and Poprawe, R.: Densification behavior, microstructure evolution, and wear performance of selective laser melting processed commercially pure titanium. Acta Mater. 60(9), 3849 (2012).Google Scholar
Zhang, L.C., Calin, M., Paturaud, F., and Eckert, J.: Deformation-induced grain refinement in body-centered cubic Co-Fe alloys upon room temperature compression. Mater. Sci. Eng., A 527, 5796 (2010).Google Scholar
Sahay, S.S., Ravichandran, K.S., Atri, R., Chen, B., and Rubin, J.: Evolution of microstructure and phases in in situ processed Ti–TiB composites containing high volume fractions of TiB whiskers. J. Mater. Res. 14(11), 4214 (1999).Google Scholar
Huang, L.J., Yang, F.Y., Hu, H.T., Rong, X.D., Geng, L., and Wu, L.Z.: TiB whiskers reinforced high temperature titanium Ti60 alloy composites with novel network microstructure. Mater. Des. 51, 421 (2013).CrossRefGoogle Scholar
Aich, S. and Chandran, K.S.R.: TiB whisker coating on titanium surfaces by solid-state diffusion: Synthesis, microstructure, and mechanical properties. Metall. Mater. Trans. A. 33(11), 3489 (2002).CrossRefGoogle Scholar
Lu, W.J., Xiao, L., Geng, K., Qin, J.N., and Zhang, D.: Growth mechanism of in situ synthesized TiBw in titanium matrix composites prepared by common casting technique. Mater. Charact. 59(7), 912 (2008).Google Scholar
Panda, K.B. and Chandran, K.S.R.: Titanium-titanium boride (Ti-TiB) functionally graded materials through reaction sintering: Synthesis, microstructure, and properties. Metall. Mater. Trans. A 34(9), 1993 (2003).Google Scholar
Panda, K.B. and Chandran, K.S.R.: Synthesis of ductile titanium-titanium boride (Ti-TiB) composites with a beta-titanium matrix: The nature of TiB formation and composite properties. Metall. Mater. Trans. A 34(6), 1371 (2003).CrossRefGoogle Scholar
Calin, M., Gebert, A., Ghinea, A.C., Gostin, P.F., Abdi, S., Mickel, C., and Eckert, J.: Designing biocompatible Ti-based metallic glasses for implant applications. Mater. Sci. Eng., C 33(2), 875 (2013).CrossRefGoogle ScholarPubMed
He, G., Löser, W., and Eckert, J.: In situ formed Ti–Cu–Ni–Sn–Ta nanostructure-dendrite composite with large plasticity. Acta Mater. 51(17), 5223 (2003).Google Scholar
Elias, C.N., Lima, J.H.C., Valiev, R., and Meyers, M.A.: Biomedical applications of titanium and its alloys. JOM 60(3), 46 (2008).Google Scholar
Long, F.W., Jiang, Q.W., Xiao, L., and Li, X.W.: Compressive deformation behaviors of coarse- and ultrafine-grained pure titanium at different temperatures: A comparative study. Mater. Trans. 52(8), 1617 (2011).Google Scholar